DOI: 10.1246/cl.1993.109. Solvent Effects on an Enzymatic Ester Synthesis in Supercritical Carbon Dioxide

Solvent Effects on an Enzymatic Ester Synthesis in Supercritical Carbon Dioxide

10.1246/cl.1993.109

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract The ester synthesis from oleic acid and (±)-citronellol by lipase was carried out in supercritical carbon dioxide(SC-CO2). In the near-critical region, the rate of reaction was considerably enhanced and (S)-(−)-oleic acid 3,7-dimethyl-6-octenyl ester was stereoselectively formed. The results were discussed with taking account of solvent properties of SC-CO2 and aggregation phenomenon about reacting species at high pressures.

Bibliography

Ikushima, Y., Saito, N., Yokoyama, T., Hatakeda, K., Ito, S., Arai, M., & Blanch, H. W. (1993). Solvent Effects on an Enzymatic Ester Synthesis in Supercritical Carbon Dioxide. Chemistry Letters, 22(1), 109â112.

Authors 7

Yutaka Ikushima (first)
Norio Saito (additional)
Toshirou Yokoyama (additional)
Kiyotaka Hatakeda (additional)
Shota Ito (additional)
Masahiko Arai (additional)
Harvey W Blanch (additional)

References 7 Referenced 37

Dates

Type	When
Created	19 years, 5 months ago (March 20, 2006, 12:58 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 4:20 p.m.)
Indexed	3 months ago (June 3, 2025, 12:26 a.m.)
Issued	32 years, 8 months ago (Jan. 1, 1993)
Published	32 years, 8 months ago (Jan. 1, 1993)
Published Online	19 years, 5 months ago (March 20, 2006)
Published Print	32 years, 8 months ago (Jan. 1, 1993)

Funders 0

None

BibTeX

@article{Ikushima_1993, title={Solvent Effects on an Enzymatic Ester Synthesis in Supercritical Carbon Dioxide}, volume={22}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1993.109}, DOI={10.1246/cl.1993.109}, number={1}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Ikushima, Yutaka and Saito, Norio and Yokoyama, Toshirou and Hatakeda, Kiyotaka and Ito, Shota and Arai, Masahiko and Blanch, Harvey W}, year={1993}, month=jan, pages={109–112} }

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