DOI: 10.1246/cl.1992.547. A Novel Type of Chiral Diphosphine Ligand, trans-2,3-Bis(diphenylphosphino)-1-methyl-1-cyclopropanecarboxylic Acid and Asymmetric Allylic Alkylation by the Use of Its Palladium Complex

A Novel Type of Chiral Diphosphine Ligand, trans-2,3-Bis(diphenylphosphino)-1-methyl-1-cyclopropanecarboxylic Acid and Asymmetric Allylic Alkylation by the Use of Its Palladium Complex

10.1246/cl.1992.547

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract Optically active trans-2,3-bis(diphenylphosphino)-1-methyl-1-cyclopropanecarboxylic acid was synthesized from trans-1,2-bis(diphenylphosphinyl)ethene via resolution of the racemic diphosphine oxide. Asymmetric allylic alkylation of 2-cyclohexenyl acetate with l-menthyl sodiodiethylphosphonoacetate was achieved in good optical yields by the use of its palladium complex.

Bibliography

Okada, Y., Minami, T., Yamamoto, T., & Ichikawa, J. (1992). A Novel Type of Chiral Diphosphine Ligand, trans-2,3-Bis(diphenylphosphino)-1-methyl-1-cyclopropanecarboxylic Acid and Asymmetric Allylic Alkylation by the Use of Its Palladium Complex. Chemistry Letters, 21(4), 547â550.

Authors 4

Yoshiharu Okada (first)
Toru Minami (additional)
Tsutomu Yamamoto (additional)
Junji Ichikawa (additional)

References 14 Referenced 26

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10.1021/ja00547a020
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10.1016/S0040-4039(00)97502-6
10.1016/S0957-4166(00)86121-2
10.1021/ja00447a064
10.1016/S0040-4039(00)83974-X
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Dates

Type	When
Created	19 years, 5 months ago (March 22, 2006, 7:58 p.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 1:50 p.m.)
Indexed	1 year ago (Aug. 21, 2024, 8:44 p.m.)
Issued	33 years, 5 months ago (April 1, 1992)
Published	33 years, 5 months ago (April 1, 1992)
Published Online	19 years, 5 months ago (March 23, 2006)
Published Print	33 years, 5 months ago (April 1, 1992)

Funders 0

None

BibTeX

@article{Okada_1992, title={A Novel Type of Chiral Diphosphine Ligand, trans-2,3-Bis(diphenylphosphino)-1-methyl-1-cyclopropanecarboxylic Acid and Asymmetric Allylic Alkylation by the Use of Its Palladium Complex}, volume={21}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1992.547}, DOI={10.1246/cl.1992.547}, number={4}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Okada, Yoshiharu and Minami, Toru and Yamamoto, Tsutomu and Ichikawa, Junji}, year={1992}, month=apr, pages={547–550} }

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