DOI: 10.1246/cl.1992.2447. Stereoselective Alkylation of Terminal Sulphide in trans-Mo(S)2(syn-Me8[16]aneS4) by Alkyl Halides. Preparation and Crystal Structure of trans-{Mo(SR)(S)(syn-Me8[16]aneS4)}+ (R = Me, PhCH2) Containing Three Distinctive Types of Sulfur Donors

Stereoselective Alkylation of Terminal Sulphide in trans-Mo(S)2(syn-Me8[16]aneS4) by Alkyl Halides. Preparation and Crystal Structure of trans-{Mo(SR)(S)(syn-Me8[16]aneS4)}+ (R = Me, PhCH2) Containing Three Distinctive Types of Sulfur Donors

10.1246/cl.1992.2447

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract Facile monoalkylation of trans-Mo(S)2(syn-Me8[16]aneS4) with MeI and PhCH2Br proceeds stereoselectively at the terminal sulphide located on the uncongested axial site to give trans-{Mo(SR)(S)(syn-Me8[16]aneS4)}+ (R = Me, CH2Ph) containing three different types of sulfur donors; thiolato, terminal sulphido, and thioether ligands; the structure of the methyl thiolate complex was elucidated by an X-ray diffraction study.

Bibliography

Yoshida, T., Adachi, T., Matsumura, K., & Baba, K. (1992). Stereoselective Alkylation of Terminal Sulphide in trans-Mo(S)2(syn-Me8[16]aneS4) by Alkyl Halides. Preparation and Crystal Structure of trans-{Mo(SR)(S)(syn-Me8[16]aneS4)}+ (R = Me, PhCH2) Containing Three Distinctive Types of Sulfur Donors. Chemistry Letters, 21(12), 2447â2450.

Authors 4

Toshikatsu Yoshida (first)
Tomohiro Adachi (additional)
Kazuhiko Matsumura (additional)
Katsumi Baba (additional)

References 23 Referenced 7

Dates

Type	When
Created	19 years, 3 months ago (May 15, 2006, 2 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 7:26 p.m.)
Indexed	1 year, 7 months ago (Jan. 19, 2024, 12:01 a.m.)
Issued	32 years, 9 months ago (Dec. 1, 1992)
Published	32 years, 9 months ago (Dec. 1, 1992)
Published Online	19 years, 3 months ago (May 15, 2006)
Published Print	32 years, 9 months ago (Dec. 1, 1992)

Funders 0

None

BibTeX

@article{Yoshida_1992, title={Stereoselective Alkylation of Terminal Sulphide in trans-Mo(S)2(syn-Me8[16]aneS4) by Alkyl Halides. Preparation and Crystal Structure of trans-{Mo(SR)(S)(syn-Me8[16]aneS4)}+ (R = Me, PhCH2) Containing Three Distinctive Types of Sulfur Donors}, volume={21}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1992.2447}, DOI={10.1246/cl.1992.2447}, number={12}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Yoshida, Toshikatsu and Adachi, Tomohiro and Matsumura, Kazuhiko and Baba, Katsumi}, year={1992}, month=dec, pages={2447–2450} }

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