DOI: 10.1246/cl.1991.977. Hydrogen Source in the Photochemical Cobalt–Carbon Cleavage of Hydrophobic Vitamin B12 Derivatives in Hydrophobic Microenvironments

Hydrogen Source in the Photochemical Cobalt–Carbon Cleavage of Hydrophobic Vitamin B12 Derivatives in Hydrophobic Microenvironments

10.1246/cl.1991.977

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract The photolysis of a hydrophobia vitamin B12 with a benzyl moiety at the Coβ site was carried out in a D2O solution containing single-walled vesicles, and a major product was the non-deuterated toluene. A hydrogen atom was apparently abstracted from the hydrophobic vitamin B12 or a lipid molecule, and not from bulk water.

Bibliography

Murakami, Y., Hisaeda, Y., Song, X.-M., Takasaki, K., & Ohno, T. (1991). Hydrogen Source in the Photochemical CobaltâCarbon Cleavage of Hydrophobic Vitamin B12 Derivatives in Hydrophobic Microenvironments. Chemistry Letters, 20(6), 977â980.

Authors 5

Yukito Murakami (first)
Yoshio Hisaeda (additional)
Xi-Ming Song (additional)
Kenji Takasaki (additional)
Teruhisa Ohno (additional)

References 10 Referenced 7

{'key': '2024011901574976800_r1'}
10.1246/bcsj.56.3642
10.1246/bcsj.57.2091
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{'key': '2024011901574976800_r7'}
{'key': '2024011901574976800_r8'}
10.1021/jo00132a030
10.1021/ja00324a034

Dates

Type	When
Created	19 years, 3 months ago (May 12, 2006, 7:10 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 8:57 p.m.)
Indexed	1 year, 7 months ago (Jan. 19, 2024, 12:01 a.m.)
Issued	34 years, 3 months ago (June 1, 1991)
Published	34 years, 3 months ago (June 1, 1991)
Published Online	19 years, 3 months ago (May 12, 2006)
Published Print	34 years, 3 months ago (June 1, 1991)

Funders 0

None

BibTeX

@article{Murakami_1991, title={Hydrogen Source in the Photochemical Cobalt–Carbon Cleavage of Hydrophobic Vitamin B12 Derivatives in Hydrophobic Microenvironments}, volume={20}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1991.977}, DOI={10.1246/cl.1991.977}, number={6}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Murakami, Yukito and Hisaeda, Yoshio and Song, Xi-Ming and Takasaki, Kenji and Ohno, Teruhisa}, year={1991}, month=jun, pages={977–980} }

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