DOI: 10.1246/cl.1989.1485. Catalysis by Interlayer Anions of a Synthetic Hydrotalcite-like Mineral in a Halide Exchange between Organic Halides

Catalysis by Interlayer Anions of a Synthetic Hydrotalcite-like Mineral in a Halide Exchange between Organic Halides

10.1246/cl.1989.1485

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract Exchgangeable Cl− anions in the interlayer sites of a hydrotalcite-like mineral, Mg6Al2(OH)16Cl2·4H2O, catalyzed a halide-exchange reaction between C6H5CH2Cl and C4H9Br or C4H9I in toluene or in DMF. Thus, for example, a reaction between C6H5CH2Cl (33 mmol) and C4H9Br (195 mmol) in DMF at 343 K for 20 h gave C6H5CH2Br with a 90% yield on a C6H5CH2Cl basis.

Bibliography

Suzuki, E., Okamoto, M., & Ono, Y. (1989). Catalysis by Interlayer Anions of a Synthetic Hydrotalcite-like Mineral in a Halide Exchange between Organic Halides. Chemistry Letters, 18(8), 1485â1486.

Authors 3

Eiichi Suzuki (first)
Masaki Okamoto (additional)
Yoshio Ono (additional)

References 9 Referenced 16

Dates

Type	When
Created	19 years, 3 months ago (May 8, 2006, 5:14 a.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 4:08 a.m.)
Indexed	1 year, 7 months ago (Jan. 19, 2024, 7:02 p.m.)
Issued	36 years, 1 month ago (Aug. 1, 1989)
Published	36 years, 1 month ago (Aug. 1, 1989)
Published Online	19 years, 3 months ago (May 8, 2006)
Published Print	36 years, 1 month ago (Aug. 1, 1989)

Funders 0

None

BibTeX

@article{Suzuki_1989, title={Catalysis by Interlayer Anions of a Synthetic Hydrotalcite-like Mineral in a Halide Exchange between Organic Halides}, volume={18}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1989.1485}, DOI={10.1246/cl.1989.1485}, number={8}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Suzuki, Eiichi and Okamoto, Masaki and Ono, Yoshio}, year={1989}, month=aug, pages={1485–1486} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        1,
        20
      ]
    ],
    "date-time": "2024-01-20T00:02:49Z",
    "timestamp": 1705708969503
  },
  "reference-count": 9,
  "publisher": "Oxford University Press (OUP)",
  "issue": "8",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1989,
            8,
            1
          ]
        ],
        "date-time": "1989-08-01T00:00:00Z",
        "timestamp": 617932800000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://academic.oup.com/pages/standard-publication-reuse-rights"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1989,
        8,
        1
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title>\n               <jats:p>Exchgangeable Cl\u2212 anions in the interlayer sites of a hydrotalcite-like mineral, Mg6Al2(OH)16Cl2\u00b74H2O, catalyzed a halide-exchange reaction between C6H5CH2Cl and C4H9Br or C4H9I in toluene or in DMF. Thus, for example, a reaction between C6H5CH2Cl (33 mmol) and C4H9Br (195 mmol) in DMF at 343 K for 20 h gave C6H5CH2Br with a 90% yield on a C6H5CH2Cl basis.</jats:p>",
  "DOI": "10.1246/cl.1989.1485",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2006,
        5,
        8
      ]
    ],
    "date-time": "2006-05-08T09:14:19Z",
    "timestamp": 1147079659000
  },
  "page": "1485-1486",
  "source": "Crossref",
  "is-referenced-by-count": 16,
  "title": "Catalysis by Interlayer Anions of a Synthetic Hydrotalcite-like Mineral in a Halide Exchange between Organic Halides",
  "prefix": "10.1093",
  "volume": "18",
  "author": [
    {
      "given": "Eiichi",
      "family": "Suzuki",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemical Engineering, Tokyo Institute of Technology"
        }
      ]
    },
    {
      "given": "Masaki",
      "family": "Okamoto",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemical Engineering, Tokyo Institute of Technology"
        }
      ]
    },
    {
      "given": "Yoshio",
      "family": "Ono",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemical Engineering, Tokyo Institute of Technology"
        }
      ]
    }
  ],
  "member": "286",
  "published-online": {
    "date-parts": [
      [
        2006,
        5,
        8
      ]
    ]
  },
  "reference": [
    {
      "key": "2024011909082922600_r1"
    },
    {
      "key": "2024011909082922600_r2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1346/CCMN.1975.0230508"
    },
    {
      "key": "2024011909082922600_r3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1346/CCMN.1983.0310409"
    },
    {
      "key": "2024011909082922600_r4",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0021-9517(85)90219-2"
    },
    {
      "key": "2024011909082922600_r5",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0021-9517(86)90262-9"
    },
    {
      "key": "2024011909082922600_r6",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/marc.1981.030020306"
    },
    {
      "key": "2024011909082922600_r7",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/bcsj.61.1008"
    },
    {
      "key": "2024011909082922600_r8",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00263a049"
    },
    {
      "key": "2024011909082922600_r9",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/bcsj.49.1989"
    }
  ],
  "container-title": "Chemistry Letters",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://academic.oup.com/chemlett/article-pdf/18/8/1485/55651328/cl.1989.1485.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://academic.oup.com/chemlett/article-pdf/18/8/1485/55651328/cl.1989.1485.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        1,
        19
      ]
    ],
    "date-time": "2024-01-19T09:08:40Z",
    "timestamp": 1705655320000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://academic.oup.com/chemlett/article/18/8/1485/7397313"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1989,
        8,
        1
      ]
    ]
  },
  "references-count": 9,
  "journal-issue": {
    "issue": "8",
    "published-online": {
      "date-parts": [
        [
          2006,
          5,
          8
        ]
      ]
    },
    "published-print": {
      "date-parts": [
        [
          1989,
          8,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1246/cl.1989.1485",
  "relation": {},
  "ISSN": [
    "0366-7022",
    "1348-0715"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1989,
        8
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1989,
        8,
        1
      ]
    ]
  }
}