Abstract
Abstract X-Ray structure analysis of [Ni3S(SPh)6]2− has revealed that a central μ3-S and three Ni atoms form a trigonal pyramid, a μ-SPh ligand bridges each pair of the three Ni atoms situated at the apexes of a triangle, and each Ni is terminally coordinated by SPh, completing a trinuclear complex. The stereochemistry around Ni is tetrahedrally distorted square planar.
References
14
Referenced
7
10.1021/ic00169a010
10.1021/ja00950a049
{'key': '2024011911182942200_r3'}
{'key': '2024011911182942200_r4'}
{'key': '2024011911182942200_r5'}
10.1021/ic00212a024
10.1071/CH9860963
10.1016/S0277-5387(00)80927-4
{'key': '2024011911182942200_r9'}
10.1002/anie.198406341
10.1021/ic00168a054
10.1021/ja00474a053
{'key': '2024011911182942200_r13'}
10.1016/S0020-1693(00)91238-6
Dates
Type | When |
---|---|
Created | 19 years, 1 month ago (July 24, 2006, 10:40 p.m.) |
Deposited | 1 year, 7 months ago (Jan. 19, 2024, 6:18 a.m.) |
Indexed | 1 year, 7 months ago (Jan. 19, 2024, 7:03 p.m.) |
Issued | 37 years, 4 months ago (May 1, 1988) |
Published | 37 years, 4 months ago (May 1, 1988) |
Published Online | 19 years, 5 months ago (March 27, 2006) |
Published Print | 37 years, 3 months ago (May 5, 1988) |
@article{Matsumoto_1988, title={Preparation and Structure of a Mixed Benzenethiolatosulfido Trinuclear Nickel Complex}, volume={17}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1988.823}, DOI={10.1246/cl.1988.823}, number={5}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Matsumoto, Keiji and Nakano, Hideyuki and OOI, Shun’ichiro}, year={1988}, month=may, pages={823–826} }