DOI: 10.1246/cl.1988.459. Two Novel Metal-complex Host Structures Consisting of Cyanocadmate Coordination Polyhedra. Clay-like and Zeolite-like Structures

Two Novel Metal-complex Host Structures Consisting of Cyanocadmate Coordination Polyhedra. Clay-like and Zeolite-like Structures

10.1246/cl.1988.459

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract The metal-complex host of a clathrate compound [Cd3{NH(CH3)2(CH2)3NH2}(CN)7]·C6H5F has a layered structure like a clay consisting of the linkage of tetrahedral Cd(CN)4 and Cd(CN)3(NC), and octahedral Cd(NC)5[NH2(CH2)3NH(CH3)2) coordination polyhedra. The host of another clathrate [Cd3(CN)7]·{NH(CH3)2(CH2)3NH2}·(CH2ClCH2Cl) has a three-dimensional structure like a zeolite comprised of the linkage of tetrahedral Cd(CN)4 and Cd(CN)3(NC), and octahedral Cd(NC)6 coordination polyhedra; the 3-(dimethylammonio)propylamine is accommodated as a cationic guest in the cavity formed in the host structure.

Bibliography

Kitazawa, T., Nishikiori, S., Kuroda, R., & Iwamoto, T. (1988). Two Novel Metal-complex Host Structures Consisting of Cyanocadmate Coordination Polyhedra. Clay-like and Zeolite-like Structures. Chemistry Letters, 17(3), 459â462.

Authors 4

Takafumi Kitazawa (first)
Shin-ichi Nishikiori (additional)
Reiko Kuroda (additional)
Toschitake Iwamoto (additional)

References 5 Referenced 32

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10.1016/0020-1650(73)80078-9
10.1007/BF00655731

Dates

Type	When
Created	19 years, 1 month ago (July 24, 2006, 11:09 p.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 6:07 a.m.)
Indexed	1 year, 2 months ago (June 10, 2024, 7:34 p.m.)
Issued	37 years, 6 months ago (March 1, 1988)
Published	37 years, 6 months ago (March 1, 1988)
Published Online	19 years, 5 months ago (March 27, 2006)
Published Print	37 years, 5 months ago (March 5, 1988)

Funders 0

None

BibTeX

@article{Kitazawa_1988, title={Two Novel Metal-complex Host Structures Consisting of Cyanocadmate Coordination Polyhedra. Clay-like and Zeolite-like Structures}, volume={17}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1988.459}, DOI={10.1246/cl.1988.459}, number={3}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Kitazawa, Takafumi and Nishikiori, Shin-ichi and Kuroda, Reiko and Iwamoto, Toschitake}, year={1988}, month=mar, pages={459–462} }

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