Abstract
Abstract Paramagnetic ruthenium(III) complex, [(C5Me5)RuCl2]n, is prepared by the reaction of RuCl3·H2O with C5Me5H in refluxing ethanol. Treatment of [Cp*RuCl2]n (Cp* = C5Me5) with cyclic dienes or α,ω-bis(diphenylphosphino)alkanes gives diamagnetic Ru(II) complexes, Cp*RuCl(diene) or Cp*RuCl(dipos), respectively. Cationic diene complex of ruthenium is formed by the reaction of Cp*RuCl(2,5-norbornadiene) with AgBF4.
Dates
Type | When |
---|---|
Created | 19 years, 1 month ago (July 24, 2006, 10:46 p.m.) |
Deposited | 1 year, 7 months ago (Jan. 19, 2024, 9:43 a.m.) |
Indexed | 1 day, 20 hours ago (Sept. 3, 2025, 6:47 a.m.) |
Issued | 41 years, 2 months ago (July 1, 1984) |
Published | 41 years, 2 months ago (July 1, 1984) |
Published Online | 19 years, 5 months ago (March 27, 2006) |
Published Print | 41 years, 2 months ago (July 5, 1984) |
@article{Oshima_1984, title={SYNTHESIS AND SOME REACTIONS OF DICHLORO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(III) OLIGOMER}, volume={13}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1984.1161}, DOI={10.1246/cl.1984.1161}, number={7}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Oshima, Noriaki and Suzuki, Hiroharu and Moro-Oka, Yoshihiko}, year={1984}, month=jul, pages={1161–1164} }