DOI: 10.1246/cl.1983.1679. 12-TUNGSTOPHOSPHATES AS DEHYDROGENATION CATALYSTS DEHYDROGENATION OF MONOMETHYLAMINE TO HYDROGENCYANIDE

12-TUNGSTOPHOSPHATES AS DEHYDROGENATION CATALYSTS DEHYDROGENATION OF MONOMETHYLAMINE TO HYDROGENCYANIDE

10.1246/cl.1983.1679

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract Monomethylamine is dehydrogenated to yield hydrogencyanide by the catalysis of 12-tungstophosphates at temperature range of 400–500 °C. Simultaneous hydrogenolysis to yield methane and ammonia was also observed. Typical solid acid catalysts, such as Al2O3 or SiO2–Al2O3 have no activity for the reaction. Catalytic activity for the dehydrogenation might be ascribed to the affinity of polyanion to hydrogen atoms.

Bibliography

Niiyama, H., Tamai, S., Saito, Y., & Echigoya, E. (1983). 12-TUNGSTOPHOSPHATES AS DEHYDROGENATION CATALYSTS DEHYDROGENATION OF MONOMETHYLAMINE TO HYDROGENCYANIDE. Chemistry Letters, 12(11), 1679â1682.

Authors 4

Hiroo Niiyama (first)
Shoji Tamai (additional)
Yoshinori Saito (additional)
Etsuro Echigoya (additional)

References 5 Referenced 0

10.1021/j100213a018
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Dates

Type	When
Created	19 years, 1 month ago (July 24, 2006, 10:36 p.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 6:48 p.m.)
Indexed	1 year, 7 months ago (Jan. 20, 2024, 1:46 a.m.)
Issued	41 years, 10 months ago (Nov. 1, 1983)
Published	41 years, 10 months ago (Nov. 1, 1983)
Published Online	19 years, 5 months ago (March 27, 2006)
Published Print	41 years, 10 months ago (Nov. 5, 1983)

Funders 0

None

BibTeX

@article{Niiyama_1983, title={12-TUNGSTOPHOSPHATES AS DEHYDROGENATION CATALYSTS DEHYDROGENATION OF MONOMETHYLAMINE TO HYDROGENCYANIDE}, volume={12}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1983.1679}, DOI={10.1246/cl.1983.1679}, number={11}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Niiyama, Hiroo and Tamai, Shoji and Saito, Yoshinori and Echigoya, Etsuro}, year={1983}, month=nov, pages={1679–1682} }

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