DOI: 10.1246/cl.1983.1081. THE OXYGENATION OF α-ISOPHORONE AND ITS SILYL ENOL ETHER WITH <i>t</i>-BuOOH IN THE PRESENCE OF METAL CATALYSTS

THE OXYGENATION OF α-ISOPHORONE AND ITS SILYL ENOL ETHER WITH t-BuOOH IN THE PRESENCE OF METAL CATALYSTS

10.1246/cl.1983.1081

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract Treatment of α-isophorone (1) with t-BuOOH in the presence of palladium(II) or copper(I) catalyst gives ketoisophorone (2) selectively. A similar treatment of silyl enol ether 7 derived from 1 affords 6-hydroxylisophorone 8.

Bibliography

Hosokawa, T., Inui, S., & Murahashi, S.-I. (1983). THE OXYGENATION OF Î±-ISOPHORONE AND ITS SILYL ENOL ETHER WITH t-BuOOH IN THE PRESENCE OF METAL CATALYSTS. Chemistry Letters, 12(7), 1081â1082.

Authors 3

Takahiro Hosokawa (first)
Shiro Inui (additional)
Shun-Ichi Murahashi (additional)

References 8 Referenced 23

{'key': '2024011921015956500_r1'}
10.1016/S0040-4039(00)97540-3
10.1016/S0040-4039(00)85598-7
{'key': '2024011921015956500_r4'}
{'key': '2024011921015956500_r5'}
10.1016/0304-5102(80)85008-5
{'key': '2024011921015956500_r7'}
10.1021/jo00402a030

Dates

Type	When
Created	19 years, 1 month ago (July 24, 2006, 10:44 p.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 4:02 p.m.)
Indexed	1 year ago (Aug. 8, 2024, 3:13 p.m.)
Issued	42 years, 2 months ago (July 1, 1983)
Published	42 years, 2 months ago (July 1, 1983)
Published Online	19 years, 5 months ago (March 27, 2006)
Published Print	42 years, 1 month ago (July 5, 1983)

Funders 0

None

BibTeX

@article{Hosokawa_1983, title={THE OXYGENATION OF α-ISOPHORONE AND ITS SILYL ENOL ETHER WITH t-BuOOH IN THE PRESENCE OF METAL CATALYSTS}, volume={12}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1983.1081}, DOI={10.1246/cl.1983.1081}, number={7}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Hosokawa, Takahiro and Inui, Shiro and Murahashi, Shun-Ichi}, year={1983}, month=jul, pages={1081–1082} }

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