DOI: 10.1246/cl.1981.1759. IR AND X-RAY DIFFRACTION STUDIES ON AMMONIUM SALTS OBTAINED FROM ELECTROLYTICALLY REDUCED 12-HETEROPOLYMOLYBDATE ANIONS

IR AND X-RAY DIFFRACTION STUDIES ON AMMONIUM SALTS OBTAINED FROM ELECTROLYTICALLY REDUCED 12-HETEROPOLYMOLYBDATE ANIONS

10.1246/cl.1981.1759

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract The intensities of IR bands due to the heteroatom–oxygen (P–O and Si–O) and the bridged lattice oxygen(Mo–O–Mo) in 12-heteropolymolybdate anions decreased markedly upon formation of Mo5+ without any elimination of their lattice oxygen. The significance of this finding in relation to the previously proposed mechanisms for the reduction of 12-molybdophosphoric acid and its salts is discussed.

Bibliography

Akimoto, M., & Echigoya, E. (1981). IR AND X-RAY DIFFRACTION STUDIES ON AMMONIUM SALTS OBTAINED FROM ELECTROLYTICALLY REDUCED 12-HETEROPOLYMOLYBDATE ANIONS. Chemistry Letters, 10(12), 1759â1762.

Authors 2

Masamichi Akimoto (first)
Etsuro Echigoya (additional)

References 17 Referenced 18

{'key': '2024011821133973200_r1'}
{'key': '2024011821133973200_r2'}
{'key': '2024011821133973200_r3'}
{'key': '2024011821133973200_r4'}
{'key': '2024011821133973200_r5'}
10.1016/0021-9517(68)90126-7
10.1016/0021-9517(69)90003-7
10.1016/0021-9517(73)90223-6
10.1016/0021-9517(74)90206-1
10.1039/f19797501757
{'key': '2024011821133973200_r11'}
{'key': '2024011821133973200_r12'}
10.1021/ic50052a019
{'key': '2024011821133973200_r14'}
10.1016/0584-8539(76)80121-3
{'key': '2024011821133973200_r16'}
{'key': '2024011821133973200_r17'}

Dates

Type	When
Created	19 years, 1 month ago (July 24, 2006, 10:20 p.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 4:14 p.m.)
Indexed	2 months ago (June 27, 2025, 3:45 p.m.)
Issued	43 years, 8 months ago (Dec. 1, 1981)
Published	43 years, 8 months ago (Dec. 1, 1981)
Published Online	19 years, 5 months ago (March 27, 2006)
Published Print	43 years, 8 months ago (Dec. 5, 1981)

Funders 0

None

BibTeX

@article{Akimoto_1981, title={IR AND X-RAY DIFFRACTION STUDIES ON AMMONIUM SALTS OBTAINED FROM ELECTROLYTICALLY REDUCED 12-HETEROPOLYMOLYBDATE ANIONS}, volume={10}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1981.1759}, DOI={10.1246/cl.1981.1759}, number={12}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Akimoto, Masamichi and Echigoya, Etsuro}, year={1981}, month=dec, pages={1759–1762} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        6,
        27
      ]
    ],
    "date-time": "2025-06-27T19:45:26Z",
    "timestamp": 1751053526035
  },
  "reference-count": 17,
  "publisher": "Oxford University Press (OUP)",
  "issue": "12",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1981,
            12,
            1
          ]
        ],
        "date-time": "1981-12-01T00:00:00Z",
        "timestamp": 376012800000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://academic.oup.com/pages/standard-publication-reuse-rights"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1981,
        12,
        5
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title>\n               <jats:p>The intensities of IR bands due to the heteroatom\u2013oxygen (P\u2013O and Si\u2013O) and the bridged lattice oxygen(Mo\u2013O\u2013Mo) in 12-heteropolymolybdate anions decreased markedly upon formation of Mo5+ without any elimination of their lattice oxygen. The significance of this finding in relation to the previously proposed mechanisms for the reduction of 12-molybdophosphoric acid and its salts is discussed.</jats:p>",
  "DOI": "10.1246/cl.1981.1759",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2006,
        7,
        25
      ]
    ],
    "date-time": "2006-07-25T02:20:30Z",
    "timestamp": 1153794030000
  },
  "page": "1759-1762",
  "source": "Crossref",
  "is-referenced-by-count": 18,
  "title": "IR AND X-RAY DIFFRACTION STUDIES ON AMMONIUM SALTS OBTAINED FROM ELECTROLYTICALLY REDUCED 12-HETEROPOLYMOLYBDATE ANIONS",
  "prefix": "10.1093",
  "volume": "10",
  "author": [
    {
      "given": "Masamichi",
      "family": "Akimoto",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemical Engineering, Tokyo Institute of Technology"
        }
      ]
    },
    {
      "given": "Etsuro",
      "family": "Echigoya",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemical Engineering, Tokyo Institute of Technology"
        }
      ]
    }
  ],
  "member": "286",
  "published-online": {
    "date-parts": [
      [
        2006,
        3,
        27
      ]
    ]
  },
  "reference": [
    {
      "key": "2024011821133973200_r1"
    },
    {
      "key": "2024011821133973200_r2"
    },
    {
      "key": "2024011821133973200_r3"
    },
    {
      "key": "2024011821133973200_r4"
    },
    {
      "key": "2024011821133973200_r5"
    },
    {
      "key": "2024011821133973200_r6",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0021-9517(68)90126-7"
    },
    {
      "key": "2024011821133973200_r7",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0021-9517(69)90003-7"
    },
    {
      "key": "2024011821133973200_r8",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0021-9517(73)90223-6"
    },
    {
      "key": "2024011821133973200_r9",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0021-9517(74)90206-1"
    },
    {
      "key": "2024011821133973200_r10",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/f19797501757"
    },
    {
      "key": "2024011821133973200_r11"
    },
    {
      "key": "2024011821133973200_r12"
    },
    {
      "key": "2024011821133973200_r13",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50052a019"
    },
    {
      "key": "2024011821133973200_r14"
    },
    {
      "key": "2024011821133973200_r15",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0584-8539(76)80121-3"
    },
    {
      "key": "2024011821133973200_r16"
    },
    {
      "key": "2024011821133973200_r17"
    }
  ],
  "container-title": "Chemistry Letters",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://academic.oup.com/chemlett/article-pdf/10/12/1759/56166587/cl.1981.1759.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://academic.oup.com/chemlett/article-pdf/10/12/1759/56166587/cl.1981.1759.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        1,
        18
      ]
    ],
    "date-time": "2024-01-18T21:14:00Z",
    "timestamp": 1705612440000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://academic.oup.com/chemlett/article/10/12/1759/7413706"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1981,
        12
      ]
    ]
  },
  "references-count": 17,
  "journal-issue": {
    "issue": "12",
    "published-online": {
      "date-parts": [
        [
          2006,
          3,
          27
        ]
      ]
    },
    "published-print": {
      "date-parts": [
        [
          1981,
          12,
          5
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1246/cl.1981.1759",
  "relation": {},
  "ISSN": [
    "0366-7022",
    "1348-0715"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1981,
        12
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1981,
        12
      ]
    ]
  }
}