DOI: 10.1246/cl.1976.135. STRUCTURAL STUDY OF OPTICAL RESOLUTION I. THE CRYSTAL STRUCTURE OF TRIS(ETHYLENEDIAMINE)COBALT(III) BROMIDE <i>d</i>-TARTRATE PENTAHYDRATE

STRUCTURAL STUDY OF OPTICAL RESOLUTION I. THE CRYSTAL STRUCTURE OF TRIS(ETHYLENEDIAMINE)COBALT(III) BROMIDE d-TARTRATE PENTAHYDRATE

10.1246/cl.1976.135

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract The crystal structure of the title compound has been determined by X-ray analysis. The absolute configuration of the complex cation is found to be Λ-δδδ. In the crystal four oxygen atoms of the tartrate anion face the three axial N–H hydrogen atoms of the complex cation and the bromide anion is placed underneath the three axial N–H hydrogen atoms of the reverse side. Thus, around the complex cation the local “[Co(en)3]Br·d-tart” block is formed.

Bibliography

Kushi, Y., Kuramoto, M., & Yoneda, H. (1976). STRUCTURAL STUDY OF OPTICAL RESOLUTION I. THE CRYSTAL STRUCTURE OF TRIS(ETHYLENEDIAMINE)COBALT(III) BROMIDE d-TARTRATE PENTAHYDRATE. Chemistry Letters, 5(2), 135â136.

Authors 3

Yoshihiko Kushi (first)
Masahiro Kuramoto (additional)
Hayami Yoneda (additional)

References 9 Referenced 9

Dates

Type	When
Created	19 years, 1 month ago (July 24, 2006, 9:56 p.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 7:01 a.m.)
Indexed	1 year, 7 months ago (Jan. 19, 2024, 7:03 p.m.)
Issued	49 years, 6 months ago (Feb. 1, 1976)
Published	49 years, 6 months ago (Feb. 1, 1976)
Published Online	19 years, 5 months ago (March 27, 2006)
Published Print	49 years, 6 months ago (Feb. 5, 1976)

Funders 0

None

BibTeX

@article{Kushi_1976, title={STRUCTURAL STUDY OF OPTICAL RESOLUTION I. THE CRYSTAL STRUCTURE OF TRIS(ETHYLENEDIAMINE)COBALT(III) BROMIDE d-TARTRATE PENTAHYDRATE}, volume={5}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1976.135}, DOI={10.1246/cl.1976.135}, number={2}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Kushi, Yoshihiko and Kuramoto, Masahiro and Yoneda, Hayami}, year={1976}, month=feb, pages={135–136} }

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