DOI: 10.1246/bcsj.77.1409. The Basicity and Catalytic Activity of Ordered Mesoporous Silicon Nitride Oxide

The Basicity and Catalytic Activity of Ordered Mesoporous Silicon Nitride Oxide

10.1246/bcsj.77.1409

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract The basicity and base catalytic properties of ordered mesoporous silicon nitride oxide (MSON) were investigated in our present contribution. It was found that the basic strength of MSON was stronger and comparable to the strength of MgO. In addition, MSON had a much higher base catalytic activity than not only amorphous silicon nitride oxide but also crystallized nitrogen-containing microporous molecular sieves used in the Knoevenagel condensation reaction of benzaldehyde and malononitrile. Furthermore, the catalysts were stable both in structure and in composition below 1123 K in an inert atmosphere. These stable, solid base catalysts may find their use in some important base catalyzed reactions.

Bibliography

Wan, K., Liu, Q., Zhang, C., & Wang, J. (2004). The Basicity and Catalytic Activity of Ordered Mesoporous Silicon Nitride Oxide. Bulletin of the Chemical Society of Japan, 77(7), 1409â1414.

Authors 4

Keshu Wan (first)
Qian Liu (additional)
Cunman Zhang (additional)
Jiacheng Wang (additional)

References 15 Referenced 26

10.1021/cr00035a005
10.1080/01614949608006465
10.1016/S1387-1811(01)00366-3
{'key': '2024012020364820800_r4'}
10.1016/0920-5861(92)80176-N
{'key': '2024012020364820800_r6'}
{'key': '2024012020364820800_r7'}
10.1006/jcat.2001.3263
10.1038/359710a0
10.1002/1521-4095(200102)13:3<192::AID-ADMA192>3.0.CO;2-M
10.1002/anie.200350978
10.1246/cl.2003.94
10.1246/cl.2003.362
{'key': '2024012020364820800_r14'}
{'key': '2024012020364820800_r15'}

Dates

Type	When
Created	21 years, 1 month ago (July 9, 2004, 2:06 a.m.)
Deposited	1 year, 7 months ago (Jan. 20, 2024, 3:37 p.m.)
Indexed	1 year, 5 months ago (March 20, 2024, 7:40 a.m.)
Issued	21 years, 2 months ago (July 1, 2004)
Published	21 years, 2 months ago (July 1, 2004)
Published Online	21 years, 1 month ago (July 9, 2004)
Published Print	21 years, 2 months ago (July 1, 2004)

Funders 0

None

BibTeX

@article{Wan_2004, title={The Basicity and Catalytic Activity of Ordered Mesoporous Silicon Nitride Oxide}, volume={77}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.77.1409}, DOI={10.1246/bcsj.77.1409}, number={7}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Wan, Keshu and Liu, Qian and Zhang, Cunman and Wang, Jiacheng}, year={2004}, month=jul, pages={1409–1414} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        3,
        20
      ]
    ],
    "date-time": "2024-03-20T11:40:00Z",
    "timestamp": 1710934800177
  },
  "reference-count": 15,
  "publisher": "Oxford University Press (OUP)",
  "issue": "7",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2004,
            7,
            1
          ]
        ],
        "date-time": "2004-07-01T00:00:00Z",
        "timestamp": 1088640000000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://academic.oup.com/pages/standard-publication-reuse-rights"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2004,
        7,
        1
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title>\n               <jats:p>The basicity and base catalytic properties of ordered mesoporous silicon nitride oxide (MSON) were investigated in our present contribution. It was found that the basic strength of MSON was stronger and comparable to the strength of MgO. In addition, MSON had a much higher base catalytic activity than not only amorphous silicon nitride oxide but also crystallized nitrogen-containing microporous molecular sieves used in the Knoevenagel condensation reaction of benzaldehyde and malononitrile. Furthermore, the catalysts were stable both in structure and in composition below 1123 K in an inert atmosphere. These stable, solid base catalysts may find their use in some important base catalyzed reactions.</jats:p>",
  "DOI": "10.1246/bcsj.77.1409",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2004,
        7,
        9
      ]
    ],
    "date-time": "2004-07-09T06:06:10Z",
    "timestamp": 1089353170000
  },
  "page": "1409-1414",
  "source": "Crossref",
  "is-referenced-by-count": 26,
  "title": "The Basicity and Catalytic Activity of Ordered Mesoporous Silicon Nitride Oxide",
  "prefix": "10.1093",
  "volume": "77",
  "author": [
    {
      "given": "Keshu",
      "family": "Wan",
      "sequence": "first",
      "affiliation": [
        {
          "name": "State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences"
        }
      ]
    },
    {
      "given": "Qian",
      "family": "Liu",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences"
        }
      ]
    },
    {
      "given": "Cunman",
      "family": "Zhang",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences"
        },
        {
          "name": "Department of Material Science and Engineering, Tongji University"
        }
      ]
    },
    {
      "given": "Jiacheng",
      "family": "Wang",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences"
        }
      ]
    }
  ],
  "member": "286",
  "published-online": {
    "date-parts": [
      [
        2004,
        7,
        9
      ]
    ]
  },
  "reference": [
    {
      "key": "2024012020364820800_r1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr00035a005"
    },
    {
      "key": "2024012020364820800_r2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/01614949608006465"
    },
    {
      "key": "2024012020364820800_r3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S1387-1811(01)00366-3"
    },
    {
      "key": "2024012020364820800_r4"
    },
    {
      "key": "2024012020364820800_r5",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0920-5861(92)80176-N"
    },
    {
      "key": "2024012020364820800_r6"
    },
    {
      "key": "2024012020364820800_r7"
    },
    {
      "key": "2024012020364820800_r8",
      "doi-asserted-by": "publisher",
      "DOI": "10.1006/jcat.2001.3263"
    },
    {
      "key": "2024012020364820800_r9",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/359710a0"
    },
    {
      "key": "2024012020364820800_r10",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/1521-4095(200102)13:3&lt;192::AID-ADMA192&gt;3.0.CO;2-M"
    },
    {
      "key": "2024012020364820800_r11",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200350978"
    },
    {
      "key": "2024012020364820800_r12",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/cl.2003.94"
    },
    {
      "key": "2024012020364820800_r13",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/cl.2003.362"
    },
    {
      "key": "2024012020364820800_r14"
    },
    {
      "key": "2024012020364820800_r15"
    }
  ],
  "container-title": "Bulletin of the Chemical Society of Japan",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://academic.oup.com/bcsj/article-pdf/77/7/1409/56264909/bcsj.77.1409.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://academic.oup.com/bcsj/article-pdf/77/7/1409/56264909/bcsj.77.1409.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        1,
        20
      ]
    ],
    "date-time": "2024-01-20T20:37:00Z",
    "timestamp": 1705783020000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://academic.oup.com/bcsj/article/77/7/1409/7340110"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2004,
        7,
        1
      ]
    ]
  },
  "references-count": 15,
  "journal-issue": {
    "issue": "7",
    "published-online": {
      "date-parts": [
        [
          2004,
          7,
          9
        ]
      ]
    },
    "published-print": {
      "date-parts": [
        [
          2004,
          7,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1246/bcsj.77.1409",
  "relation": {},
  "ISSN": [
    "0009-2673",
    "1348-0634"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        2004,
        7
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        2004,
        7,
        1
      ]
    ]
  }
}