DOI: 10.1246/bcsj.75.1693. A Bimetallic Magnetic System Exhibiting Reversible Ferromagnetism/Metamagnetism Modulation

A Bimetallic Magnetic System Exhibiting Reversible Ferromagnetism/Metamagnetism Modulation

10.1246/bcsj.75.1693

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract A cyanide-bridged bimetallic compound, [Ni(1,1-dmen)2]2[Fe(CN)6](BPDS)0.5·4H2O (1) (1,1-dmen = 1,1-dimethylethylenediamine, BPDS2− = biphenyl-4,4′-disulfonate), has been prepared. It has a pseudo 2-D network structure based on a Fe4Ni4 square unit with two Fe–CN–Ni–NC–Fe and two Fe–CN···H2O–Ni–NC–Fe linkages and shows a metamagnetic ordering with TC = 3.3 K. The dehydration of 1 at 150 °C has afforded [Ni(1,1-dmen)2]2[Fe(CN)6](BPDS)0.5 (1a). It has a definite 2-D network structure based on a Fe4Ni4 square unit with four Fe–CN–Ni–NC–Fe linkages and shows essentially a ferromagnetic ordering with TC = 10.7 K under weak applied field (&gt; 250 G). 1a is hygroscopic and adsorbed atmospheric moisture to afford [Ni(1,1-dmen)2]2[Fe(CN)6](BPDS)0.5·2H2O (1b), which has a pseudo 2-D network structure similar to that of 1 and shows a metamagnetic ordering with TC = 4.0 K. 1a and 1b can be interconverted by dehydration at 150 °C and hydration in open air at room temperature, producing a unique molecular magnetic system exhibiting a reversible ferromagnetism/metamagnetism modulation.

Bibliography

Usuki, N., Ohba, M., & Okawa, H. (2002). A Bimetallic Magnetic System Exhibiting Reversible Ferromagnetism/Metamagnetism Modulation. Bulletin of the Chemical Society of Japan, 75(8), 1693â1698.

Authors 3

Naoki Usuki (first)
Masaaki Ohba (additional)
Hisashi Okawa (additional)

References 18 Referenced 25

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10.1016/S0010-8545(00)00233-2
10.1002/(SICI)1521-3773(19990614)38:12<1795::AID-ANIE1795>3.0.CO;2-I
10.1006/jssc.2001.9165
10.1021/ic00021a001
10.1021/ic970719g
10.1021/ja962198m
10.1021/ic980448p
10.1021/ic9608814
{'key': '2024011921012448500_r12'}
{'key': '2024011921012448500_r13'}
{'key': '2024011921012448500_r14'}
10.1007/3-540-18058-3_3
10.1021/ja00364a021
10.1021/ja00104a046
10.1080/10587250008038268

Dates

Type	When
Created	22 years, 11 months ago (Sept. 6, 2002, 6:20 a.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 4:01 p.m.)
Indexed	1 year, 7 months ago (Jan. 20, 2024, 5:37 a.m.)
Issued	23 years, 1 month ago (Aug. 1, 2002)
Published	23 years, 1 month ago (Aug. 1, 2002)
Published Online	23 years ago (Aug. 15, 2002)
Published Print	23 years, 1 month ago (Aug. 1, 2002)

Funders 0

None

BibTeX

@article{Usuki_2002, title={A Bimetallic Magnetic System Exhibiting Reversible Ferromagnetism/Metamagnetism Modulation}, volume={75}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.75.1693}, DOI={10.1246/bcsj.75.1693}, number={8}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Usuki, Naoki and Ohba, Masaaki and Okawa, Hisashi}, year={2002}, month=aug, pages={1693–1698} }

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  "abstract": "<jats:title>Abstract</jats:title>\n               <jats:p>A cyanide-bridged bimetallic compound, [Ni(1,1-dmen)2]2[Fe(CN)6](BPDS)0.5\u00b74H2O (1) (1,1-dmen = 1,1-dimethylethylenediamine, BPDS2\u2212 = biphenyl-4,4\u2032-disulfonate), has been prepared. It has a pseudo 2-D network structure based on a Fe4Ni4 square unit with two Fe\u2013CN\u2013Ni\u2013NC\u2013Fe and two Fe\u2013CN\u00b7\u00b7\u00b7H2O\u2013Ni\u2013NC\u2013Fe linkages and shows a metamagnetic ordering with TC = 3.3 K. The dehydration of 1 at 150 \u00b0C has afforded [Ni(1,1-dmen)2]2[Fe(CN)6](BPDS)0.5 (1a). It has a definite 2-D network structure based on a Fe4Ni4 square unit with four Fe\u2013CN\u2013Ni\u2013NC\u2013Fe linkages and shows essentially a ferromagnetic ordering with TC = 10.7 K under weak applied field (&amp;gt; 250 G). 1a is hygroscopic and adsorbed atmospheric moisture to afford [Ni(1,1-dmen)2]2[Fe(CN)6](BPDS)0.5\u00b72H2O (1b), which has a pseudo 2-D network structure similar to that of 1 and shows a metamagnetic ordering with TC = 4.0 K. 1a and 1b can be interconverted by dehydration at 150 \u00b0C and hydration in open air at room temperature, producing a unique molecular magnetic system exhibiting a reversible ferromagnetism/metamagnetism modulation.</jats:p>",
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