DOI: 10.1246/bcsj.70.2063. Semiconductor Photocatalysis. Part 22. Visible-Light Induced Photoreduction of CO2 with CdS Nanocrystallites — Importance of the Morphology and Surface Structures Controlled through Solvation by <i>N</i>,<i>N</i>-Dimethylformamide

Semiconductor Photocatalysis. Part 22. Visible-Light Induced Photoreduction of CO2 with CdS Nanocrystallites — Importance of the Morphology and Surface Structures Controlled through Solvation by N,N-Dimethylformamide

10.1246/bcsj.70.2063

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract Carbon dioxide (CO2) is reduced to CO on hexagonal CdS nanocrystallites (mean diameter of 4 nm) prepared in N,N-dimethylformamide (DMF) under visible-light irradiation with a quantum yield of 0.098 at λ = 405 nm in the presence of TEA as an electron donor. Solvation of the surface of CdS nanocrystallites by DMF or a related amide molecules should control the crystalline growth and stabilize the favorable morphology with a size quantization-effect. The effect of Cd2+ or H2S on CO production and the emission behavior, and the effect of electron donors suggest an important role of the surface structures of CdS–DMF for photo-induced electron transfer to CO2. The scope and limitation of the photoreduction of CO2 with semiconductor nanoparticles are discussed.

Bibliography

Yanagida, S., Kanemoto, M., Ishihara, K., Wada, Y., Sakata, T., & Mori, H. (1997). Semiconductor Photocatalysis. Part 22. Visible-Light Induced Photoreduction of CO2 with CdS Nanocrystallites â Importance of the Morphology and Surface Structures Controlled through Solvation by N,N-Dimethylformamide. Bulletin of the Chemical Society of Japan, 70(9), 2063â2070.

Authors 6

Shozo Yanagida (first)
Masashi Kanemoto (additional)
Ken-ichi Ishihara (additional)
Yuji Wada (additional)
Takao Sakata (additional)
Hirotaro Mori (additional)

References 51 Referenced 28

Dates

Type	When
Created	19 years, 2 months ago (June 15, 2006, 1:21 a.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 11:02 p.m.)
Indexed	1 year, 7 months ago (Jan. 23, 2024, 4:21 a.m.)
Issued	27 years, 11 months ago (Sept. 1, 1997)
Published	27 years, 11 months ago (Sept. 1, 1997)
Published Online	19 years, 2 months ago (June 15, 2006)
Published Print	27 years, 11 months ago (Sept. 1, 1997)

Funders 0

None

BibTeX

@article{Yanagida_1997, title={Semiconductor Photocatalysis. Part 22. Visible-Light Induced Photoreduction of CO2 with CdS Nanocrystallites — Importance of the Morphology and Surface Structures Controlled through Solvation by N,N-Dimethylformamide}, volume={70}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.70.2063}, DOI={10.1246/bcsj.70.2063}, number={9}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Yanagida, Shozo and Kanemoto, Masashi and Ishihara, Ken-ichi and Wada, Yuji and Sakata, Takao and Mori, Hirotaro}, year={1997}, month=sep, pages={2063–2070} }

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