Abstract
Abstract Tris(octaethylporphyrin)s, in which two octaethylporphyrin (OEP) rings are connected with vinylene groups at α,γ- and α,β-meso positions of the central OEP ring, were synthesized. The tris(OEP)s have similar conformational and configurational structures to the corresponding vinylene group-connected bis(OEP). Examination of both 1H NMR and electronic absorption spectra of the tris(OEP)s showed the behavior reflecting the highly symmetrical structure and the mutual interaction between the three OEP rings through the vinylene linkages.
References
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Dates
Type | When |
---|---|
Created | 19 years, 2 months ago (June 15, 2006, 1:21 a.m.) |
Deposited | 1 year, 7 months ago (Jan. 19, 2024, 11:02 p.m.) |
Indexed | 1 year, 5 months ago (March 16, 2024, 3:57 a.m.) |
Issued | 28 years, 1 month ago (Aug. 1, 1997) |
Published | 28 years, 1 month ago (Aug. 1, 1997) |
Published Online | 19 years, 2 months ago (June 15, 2006) |
Published Print | 28 years, 1 month ago (Aug. 1, 1997) |
@article{Higuchi_1997, title={Synthesis and Properties of Tris(octaethylporphyrin)s Connected with Vinylene Groups}, volume={70}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.70.1923}, DOI={10.1246/bcsj.70.1923}, number={8}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Higuchi, Hiroyuki and Shimizu, Kenji and Takeuchi, Makoto and Ojima, Juro and Sugiura, Ken-ichi and Sakata, Yoshiteru}, year={1997}, month=aug, pages={1923–1933} }