DOI: 10.1246/bcsj.69.3563. Supramolecular Stacks of Bis(imidazolyl)porphyrin through Metal Coordination

Supramolecular Stacks of Bis(imidazolyl)porphyrin through Metal Coordination

10.1246/bcsj.69.3563

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract cis- and trans-bis(1-methyl-2-imidazolyl)tetraethyltetramethylporphyrin Mg complexes were prepared. 1H NMR, absorption, and fluorescence spectra suggest that Mg has a high tendency toward dimer formation through coordination from imidazolyl to metal in a similar way to Zn, and accepts further the sixth coordination, which never occurred in Zn complexes. Propagation of the organization from a dimer to a trimer for trans-Mg complex starts at such a low concentration level as 10−5 M (1 M = 1 mol dm−3) and a 2 × 10−3 M solution organized the system to a 2.34 mer on average.

Bibliography

Kobuke, Y., & Miyaji, H. (1996). Supramolecular Stacks of Bis(imidazolyl)porphyrin through Metal Coordination. Bulletin of the Chemical Society of Japan, 69(12), 3563â3569.

Authors 2

Yoshiaki Kobuke (first)
Hidekazu Miyaji (additional)

References 25 Referenced 65

Dates

Type	When
Created	19 years, 2 months ago (June 29, 2006, 1:56 a.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 10:04 p.m.)
Indexed	1 year, 6 months ago (March 5, 2024, 10:05 a.m.)
Issued	28 years, 9 months ago (Dec. 1, 1996)
Published	28 years, 9 months ago (Dec. 1, 1996)
Published Online	19 years, 2 months ago (June 29, 2006)
Published Print	28 years, 9 months ago (Dec. 1, 1996)

Funders 0

None

BibTeX

@article{Kobuke_1996, title={Supramolecular Stacks of Bis(imidazolyl)porphyrin through Metal Coordination}, volume={69}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.69.3563}, DOI={10.1246/bcsj.69.3563}, number={12}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Kobuke, Yoshiaki and Miyaji, Hidekazu}, year={1996}, month=dec, pages={3563–3569} }

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