DOI: 10.1246/bcsj.55.3446. Reaction Process of Vanadium Tetrachloride with Ammonia in the Vapor Phase and Properties of the Vanadium Nitride Formed

Reaction Process of Vanadium Tetrachloride with Ammonia in the Vapor Phase and Properties of the Vanadium Nitride Formed

10.1246/bcsj.55.3446

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract The reaction products of gaseous VCl4 with ammonia were VCl4·4NH3 at 200 °C, VCl4·4NH3, VNx, and NH4Cl at 250–550 °C, and VNx and NH4Cl at 600–1000 °C. At 1100 °C, small amounts of VCl2 and HCl were formed in addition to VNx and NH4Cl. The N/V atomic ratio, x, of the VNx formed was 1.20 at 600 °C, 1.15 at 700 °C, 1.14 at 800 °C, and 1.13 at 900 and 1000 °C. The lattice constants of the VNx formed were shown. The reaction process of gaseous VCl4 with ammonia can be represented as follows: The reaction of gaseous VCl4 with ammonia first occurs to form VCl4·4NH3. Above about 215 °C, the reaction of VCl4·4NH3 with ammonia also occurs to form VNx. At 1100 °C, in addition to these reactions, the reaction of gaseous VCl4 with hydrogen formed by the thermal dissociation of ammonia occurs to form VCl2. On heating the VNx, formed by the vapor-phase reaction, at temperatures higher than 500 °C in an argon atmosphere, the value of x decreased with the increase in the heating temperature to 1.03 at 900–1000 °C.

Bibliography

Saeki, Y., Shimizu, T., Yajima, A., & Matsuzaki, R. (1982). Reaction Process of Vanadium Tetrachloride with Ammonia in the Vapor Phase and Properties of the Vanadium Nitride Formed. Bulletin of the Chemical Society of Japan, 55(11), 3446â3449.

Authors 4

Yuzo Saeki (first)
Takashi Shimizu (additional)
Akimasa Yajima (additional)
Ryoko Matsuzaki (additional)

References 11 Referenced 6

{'key': '2024011802080498900_r1'}
10.1246/bcsj.53.2843
{'key': '2024011802080498900_r3'}
10.1007/BF00510993
{'key': '2024011802080498900_r5'}
{'key': '2024011802080498900_r6'}
{'key': '2024011802080498900_r7'}
10.1016/0039-9140(61)80017-9
10.1021/ja01217a026
{'key': '2024011802080498900_r10'}
{'key': '2024011802080498900_r11'}

Dates

Type	When
Created	19 years, 1 month ago (July 25, 2006, 9:02 p.m.)
Deposited	1 year, 7 months ago (Jan. 17, 2024, 9:08 p.m.)
Indexed	1 year, 7 months ago (Jan. 20, 2024, 5:38 a.m.)
Issued	42 years, 10 months ago (Nov. 1, 1982)
Published	42 years, 10 months ago (Nov. 1, 1982)
Published Online	19 years, 2 months ago (June 27, 2006)
Published Print	42 years, 10 months ago (Nov. 1, 1982)

Funders 0

None

BibTeX

@article{Saeki_1982, title={Reaction Process of Vanadium Tetrachloride with Ammonia in the Vapor Phase and Properties of the Vanadium Nitride Formed}, volume={55}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.55.3446}, DOI={10.1246/bcsj.55.3446}, number={11}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Saeki, Yuzo and Shimizu, Takashi and Yajima, Akimasa and Matsuzaki, Ryoko}, year={1982}, month=nov, pages={3446–3449} }

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