DOI: 10.1246/bcsj.52.437. Kinetics of the Oxidative Addition Reaction of Iodine to (Dimethyldithiocarbamato)bis(2,4,6-rimethylphenyl isocyanide)rhodium(I)

Kinetics of the Oxidative Addition Reaction of Iodine to (Dimethyldithiocarbamato)bis(2,4,6-rimethylphenyl isocyanide)rhodium(I)

10.1246/bcsj.52.437

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract The reaction of Rh(dtc)L2 (dtc=S2CN(CH3)2, L=2,4,6-(CH3)3C6H2NC) with an equimolar amount of iodine yields a trans adduct, RhI2(dtc)L2. The rate of this reaction was measured in benzene, employing a stopped flow technique under pseudo-first-order conditions with excess iodine. The result indicates that the reaction proceeds via a charge transfer complex Rh(dtc)L2·I2, which is rearranged in two consecutive zero-order reactions with respect to the I2 concentration; the rearrangement of Rh(dtc)L2·I2 to a cis adduct followed by isomerization to the trans adduct. This mechanism is supported from kinetic data for the reaction of Rh(acac)L2 (acac=CH3COCHCOCH3) with I2. It is also described that RhI(I3)(dtc)L2 and RhI(I3)(acac)L2 were obtained by reactions of Rh(dtc)L2 and Rh(acac)L2 with excess iodine, respectively.

Bibliography

Kuwae, R., Tanaka, T., & Kawakami, K. (1979). Kinetics of the Oxidative Addition Reaction of Iodine to (Dimethyldithiocarbamato)bis(2,4,6-rimethylphenyl isocyanide)rhodium(I). Bulletin of the Chemical Society of Japan, 52(2), 437â440.

Authors 3

Ryosho Kuwae (first)
Toshio Tanaka (additional)
Katsuhiko Kawakami (additional)

References 29 Referenced 14

Dates

Type	When
Created	19 years, 1 month ago (July 19, 2006, 11:13 p.m.)
Deposited	1 year, 7 months ago (Jan. 17, 2024, 7:09 a.m.)
Indexed	1 year, 7 months ago (Jan. 17, 2024, 9:58 p.m.)
Issued	46 years, 7 months ago (Feb. 1, 1979)
Published	46 years, 7 months ago (Feb. 1, 1979)
Published Online	19 years, 4 months ago (April 19, 2006)
Published Print	46 years, 7 months ago (Feb. 1, 1979)

Funders 0

None

BibTeX

@article{Kuwae_1979, title={Kinetics of the Oxidative Addition Reaction of Iodine to (Dimethyldithiocarbamato)bis(2,4,6-rimethylphenyl isocyanide)rhodium(I)}, volume={52}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.52.437}, DOI={10.1246/bcsj.52.437}, number={2}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Kuwae, Ryosho and Tanaka, Toshio and Kawakami, Katsuhiko}, year={1979}, month=feb, pages={437–440} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        1,
        18
      ]
    ],
    "date-time": "2024-01-18T02:58:24Z",
    "timestamp": 1705546704865
  },
  "reference-count": 29,
  "publisher": "Oxford University Press (OUP)",
  "issue": "2",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1979,
            2,
            1
          ]
        ],
        "date-time": "1979-02-01T00:00:00Z",
        "timestamp": 286675200000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://academic.oup.com/pages/standard-publication-reuse-rights"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1979,
        2,
        1
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title>\n               <jats:p>The reaction of Rh(dtc)L2 (dtc=S2CN(CH3)2, L=2,4,6-(CH3)3C6H2NC) with an equimolar amount of iodine yields a trans adduct, RhI2(dtc)L2. The rate of this reaction was measured in benzene, employing a stopped flow technique under pseudo-first-order conditions with excess iodine. The result indicates that the reaction proceeds via a charge transfer complex Rh(dtc)L2\u00b7I2, which is rearranged in two consecutive zero-order reactions with respect to the I2 concentration; the rearrangement of Rh(dtc)L2\u00b7I2 to a cis adduct followed by isomerization to the trans adduct. This mechanism is supported from kinetic data for the reaction of Rh(acac)L2 (acac=CH3COCHCOCH3) with I2. It is also described that RhI(I3)(dtc)L2 and RhI(I3)(acac)L2 were obtained by reactions of Rh(dtc)L2 and Rh(acac)L2 with excess iodine, respectively.</jats:p>",
  "DOI": "10.1246/bcsj.52.437",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2006,
        7,
        20
      ]
    ],
    "date-time": "2006-07-20T03:13:59Z",
    "timestamp": 1153365239000
  },
  "page": "437-440",
  "source": "Crossref",
  "is-referenced-by-count": 14,
  "title": "Kinetics of the Oxidative Addition Reaction of Iodine to (Dimethyldithiocarbamato)bis(2,4,6-rimethylphenyl isocyanide)rhodium(I)",
  "prefix": "10.1093",
  "volume": "52",
  "author": [
    {
      "given": "Ryosho",
      "family": "Kuwae",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Applied Chemistry, Faculty of Engineering, Osaka University"
        }
      ]
    },
    {
      "given": "Toshio",
      "family": "Tanaka",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Applied Chemistry, Faculty of Engineering, Osaka University"
        }
      ]
    },
    {
      "given": "Katsuhiko",
      "family": "Kawakami",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Applied Chemistry, Faculty of Engineering, Osaka University"
        }
      ]
    }
  ],
  "member": "286",
  "published-online": {
    "date-parts": [
      [
        2006,
        4,
        19
      ]
    ]
  },
  "reference": [
    {
      "key": "2024011712030491400_r1"
    },
    {
      "key": "2024011712030491400_r2"
    },
    {
      "key": "2024011712030491400_r3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar50005a002"
    },
    {
      "key": "2024011712030491400_r4"
    },
    {
      "key": "2024011712030491400_r5",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/bcsj.50.1453"
    },
    {
      "key": "2024011712030491400_r6",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50094a007"
    },
    {
      "key": "2024011712030491400_r7"
    },
    {
      "key": "2024011712030491400_r8",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0020-1693(00)89841-2"
    },
    {
      "key": "2024011712030491400_r9",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50162a040"
    },
    {
      "key": "2024011712030491400_r10",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-328X(00)85079-2"
    },
    {
      "key": "2024011712030491400_r11"
    },
    {
      "key": "2024011712030491400_r12",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00439a078"
    },
    {
      "key": "2024011712030491400_r13",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00441a029"
    },
    {
      "key": "2024011712030491400_r14",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50172a001"
    },
    {
      "key": "2024011712030491400_r15",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0020-1693(00)95581-6"
    },
    {
      "key": "2024011712030491400_r16",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0020-1693(00)93926-4"
    },
    {
      "key": "2024011712030491400_r17"
    },
    {
      "key": "2024011712030491400_r18",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50139a027"
    },
    {
      "key": "2024011712030491400_r19",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50057a023"
    },
    {
      "key": "2024011712030491400_r20",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50145a015"
    },
    {
      "key": "2024011712030491400_r21",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0020-1693(00)86231-3"
    },
    {
      "key": "2024011712030491400_r22",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01148a504"
    },
    {
      "key": "2024011712030491400_r23",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/bcsj.48.2816"
    },
    {
      "key": "2024011712030491400_r24",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0020-1693(00)86266-0"
    },
    {
      "key": "2024011712030491400_r25"
    },
    {
      "key": "2024011712030491400_r26",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00949a062"
    },
    {
      "key": "2024011712030491400_r27"
    },
    {
      "key": "2024011712030491400_r28",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-328X(00)83832-2"
    },
    {
      "key": "2024011712030491400_r29",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00756a049"
    }
  ],
  "container-title": "Bulletin of the Chemical Society of Japan",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://academic.oup.com/bcsj/article-pdf/52/2/437/56102028/bcsj.52.437.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://academic.oup.com/bcsj/article-pdf/52/2/437/56102028/bcsj.52.437.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        1,
        17
      ]
    ],
    "date-time": "2024-01-17T12:09:28Z",
    "timestamp": 1705493368000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://academic.oup.com/bcsj/article/52/2/437/7358188"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1979,
        2,
        1
      ]
    ]
  },
  "references-count": 29,
  "journal-issue": {
    "issue": "2",
    "published-online": {
      "date-parts": [
        [
          2006,
          4,
          19
        ]
      ]
    },
    "published-print": {
      "date-parts": [
        [
          1979,
          2,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1246/bcsj.52.437",
  "relation": {},
  "ISSN": [
    "0009-2673",
    "1348-0634"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1979,
        2
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1979,
        2,
        1
      ]
    ]
  }
}