DOI: 10.1246/bcsj.51.2334. Studies on Mixed Valence Complexes of Platinum and Palladium. I. Preparation and Characterization of Pt(II)–Pt(IV), Pd(II)–Pt(IV), and Pd(II)–Pd(IV) Complexes of the General Formula, [M(AA)2][M′X2(AA)2]Y4

Studies on Mixed Valence Complexes of Platinum and Palladium. I. Preparation and Characterization of Pt(II)–Pt(IV), Pd(II)–Pt(IV), and Pd(II)–Pd(IV) Complexes of the General Formula, [M(AA)2][M′X2(AA)2]Y4

10.1246/bcsj.51.2334

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract A series of deeply colored mixed valence complexes of the general formula [M(AA)2][M′X2(AA)2]Y4 were prepared and characterized, where M–M′=Pt(II)–Pt(IV), Pd(II)–Pt(IV), and Pd(II)–Pd(IV); (AA)=ethylenediamine, propylenediamine, and trimethylenediamine; X=Cl, Br, and I; Y=ClO4, BF4. The relationships between the reflection spectra and the nature of the constituents (X, (AA), Y and M–M′) of the compounds were studied. The value of \barνmax of the main absorption band in the visible region decreases in the order: Cl→Br→I, pn→tn→en, ClO4→BF4, Pd(II)–Pt(IV)→Pt(II)–Pt(IV)→Pd(II)–Pd(IV). On the basis of dichroism of the crystals, it can be predicted that the X–M′(IV)–X…M(II) atoms in these complexes are arrayed in a straight line parallel to the crystal needle.

Bibliography

Matsumoto, N., Yamashita, M., & Kida, S. (1978). Studies on Mixed Valence Complexes of Platinum and Palladium. I. Preparation and Characterization of Pt(II)âPt(IV), Pd(II)âPt(IV), and Pd(II)âPd(IV) Complexes of the General Formula, [M(AA)2][Mâ²X2(AA)2]Y4. Bulletin of the Chemical Society of Japan, 51(8), 2334â2337.

Authors 3

Naohide Matsumoto (first)
Masahiro Yamashita (additional)
Sigeo Kida (additional)

References 23 Referenced 57

Dates

Type	When
Created	19 years, 1 month ago (July 19, 2006, 11:07 p.m.)
Deposited	1 year, 7 months ago (Jan. 17, 2024, 6:08 a.m.)
Indexed	1 year, 7 months ago (Jan. 20, 2024, 3:59 p.m.)
Issued	47 years ago (Aug. 1, 1978)
Published	47 years ago (Aug. 1, 1978)
Published Online	19 years, 4 months ago (April 19, 2006)
Published Print	47 years ago (Aug. 1, 1978)

Funders 0

None

BibTeX

@article{Matsumoto_1978, title={Studies on Mixed Valence Complexes of Platinum and Palladium. I. Preparation and Characterization of Pt(II)–Pt(IV), Pd(II)–Pt(IV), and Pd(II)–Pd(IV) Complexes of the General Formula, [M(AA)2][M′X2(AA)2]Y4}, volume={51}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.51.2334}, DOI={10.1246/bcsj.51.2334}, number={8}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Matsumoto, Naohide and Yamashita, Masahiro and Kida, Sigeo}, year={1978}, month=aug, pages={2334–2337} }

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