DOI: 10.1246/bcsj.50.2643. Stereochemistry of Cobalt(III) Complexes with Thioethers. II. Geometrical Isomers, Absorption, and Circular Dichroism Spectra of Bis(terdentate-N,S,O) Complexes

Stereochemistry of Cobalt(III) Complexes with Thioethers. II. Geometrical Isomers, Absorption, and Circular Dichroism Spectra of Bis(terdentate-N,S,O) Complexes

10.1246/bcsj.50.2643

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract Two cobalt(III) complexes containing terdentate thioethers, bis[(2-aminoethylthio)acetato]cobalt(III)(1+), and bis[3-(2-aminoethylthio)propionato]cobalt(III)(1+) were prepared and separated into five and six geometrical isomers, respectively, by ion-exchange column chromatography. The isomers were identified on the basis of their electronic absorption and NMR spectra. The circular dichroism spectra of optically resolved isomers were measured and discussed in relation to the absolute configurations.

Bibliography

Yamanari, K., Hidaka, J., & Shimura, Y. (1977). Stereochemistry of Cobalt(III) Complexes with Thioethers. II. Geometrical Isomers, Absorption, and Circular Dichroism Spectra of Bis(terdentate-N,S,O) Complexes. Bulletin of the Chemical Society of Japan, 50(10), 2643â2649.

Authors 3

Kazuaki Yamanari (first)
Jinsai Hidaka (additional)
Yoichi Shimura (additional)

References 33 Referenced 15

Dates

Type	When
Created	19 years, 1 month ago (July 19, 2006, 10:56 p.m.)
Deposited	1 year, 7 months ago (Jan. 17, 2024, 2:33 a.m.)
Indexed	1 year, 7 months ago (Jan. 18, 2024, 5:21 p.m.)
Issued	47 years, 11 months ago (Oct. 1, 1977)
Published	47 years, 11 months ago (Oct. 1, 1977)
Published Online	19 years, 4 months ago (April 19, 2006)
Published Print	47 years, 11 months ago (Oct. 1, 1977)

Funders 0

None

BibTeX

@article{Yamanari_1977, title={Stereochemistry of Cobalt(III) Complexes with Thioethers. II. Geometrical Isomers, Absorption, and Circular Dichroism Spectra of Bis(terdentate-N,S,O) Complexes}, volume={50}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.50.2643}, DOI={10.1246/bcsj.50.2643}, number={10}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Yamanari, Kazuaki and Hidaka, Jinsai and Shimura, Yoichi}, year={1977}, month=oct, pages={2643–2649} }

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