DOI: 10.1246/bcsj.49.595. The Crystal and Molecular Structure of Zinc Complex of 2-Chlorobenzoic Acid. II. The Crystal and Molecular Structure of μ3-Hydroxo-tri-μ-(2-chlorobenzoato)dizinc(II) Dihydrate

The Crystal and Molecular Structure of Zinc Complex of 2-Chlorobenzoic Acid. II. The Crystal and Molecular Structure of μ3-Hydroxo-tri-μ-(2-chlorobenzoato)dizinc(II) Dihydrate

10.1246/bcsj.49.595

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract C21H12O6Cl3Zn2OH·2H2O crystallizes in the monoclinic space group P21/c: a=12.779, b=23.732, c=14.749 Å, β=147.98°, and Z=4. The structure was determined by the usual heavy atom method and refined to R=0.039. The complex forms polymeric complex chains in the crystalline state. The ligands around two independent zinc atoms form an unusual trigonal bipyramid and an octahedron, respectively; the coordination geometry apparently differs from that found in the crystal structure of bis(2-chlorobenzoato) zinc(II). The correlation between coordination geometry and catalytic action of zinc atom is also discussed.

Bibliography

Nakacho, Y., Misawa, T., Fujiwara, T., Wakahara, A., & Tomita, K. (1976). The Crystal and Molecular Structure of Zinc Complex of 2-Chlorobenzoic Acid. II. The Crystal and Molecular Structure of Î¼3-Hydroxo-tri-Î¼-(2-chlorobenzoato)dizinc(II) Dihydrate. Bulletin of the Chemical Society of Japan, 49(3), 595â599.

Authors 5

Yoshifumi Nakacho (first)
Takeshi Misawa (additional)
Takaji Fujiwara (additional)
Akio Wakahara (additional)
Ken-ichi Tomita (additional)

References 3 Referenced 15

10.1246/bcsj.49.58
{'key': '2024011703561963500_r2'}
10.1107/S0365110X65004620

Dates

Type	When
Created	19 years, 1 month ago (July 19, 2006, 10:39 p.m.)
Deposited	1 year, 7 months ago (Jan. 16, 2024, 10:56 p.m.)
Indexed	1 year, 7 months ago (Jan. 17, 2024, 12:02 a.m.)
Issued	49 years, 5 months ago (March 1, 1976)
Published	49 years, 5 months ago (March 1, 1976)
Published Online	19 years, 4 months ago (April 19, 2006)
Published Print	49 years, 5 months ago (March 1, 1976)

Funders 0

None

BibTeX

@article{Nakacho_1976, title={The Crystal and Molecular Structure of Zinc Complex of 2-Chlorobenzoic Acid. II. The Crystal and Molecular Structure of μ3-Hydroxo-tri-μ-(2-chlorobenzoato)dizinc(II) Dihydrate}, volume={49}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.49.595}, DOI={10.1246/bcsj.49.595}, number={3}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Nakacho, Yoshifumi and Misawa, Takeshi and Fujiwara, Takaji and Wakahara, Akio and Tomita, Ken-ichi}, year={1976}, month=mar, pages={595–599} }

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