DOI: 10.1246/bcsj.49.143. <i>N</i>-Allylprazole as a Ligand. III. The Crystal and Molecular Structure of (1-Allyl-3,5-dimethylpyrazole)copper(I) Chloride

N-Allylprazole as a Ligand. III. The Crystal and Molecular Structure of (1-Allyl-3,5-dimethylpyrazole)copper(I) Chloride

10.1246/bcsj.49.143

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract The crystal structure of (1-allyl-3,5-dimethylpyrazole) copper (I) chloride, CuCl(C8H12N2), has been determined by the three-dimensional X-ray analysis. The crystal is triclinic, space group P\bar1; a=8.442(4), b=8.873(6), c=8.112(3) Å, α=103.44(3), β=116.42(3), γ=63.37(3)° and Z=2. The structure was refined to an R value of 0.056 for 1196 collected reflections. The complex has a dimeric structure in which the copper(I) ion is surrounded quasi-tetrahedrally by two bridging chlorines, a pyrazole-nitrogen and the olefinic part of the allyl group. The C=C bond distance (1.34 Å) scarcely shows any increase upon coordination to the metal. The olefin plane is almost perpendicular to the Cu-olefin bond axis and shows no significant bendings of the olefinic atoms out of the plane.

Bibliography

Fukushima, K., Kobayashi, A., Miyamoto, T., & Sasaki, Y. (1976). N-Allylprazole as a Ligand. III. The Crystal and Molecular Structure of (1-Allyl-3,5-dimethylpyrazole)copper(I) Chloride. Bulletin of the Chemical Society of Japan, 49(1), 143â146.

Authors 4

Kazuo Fukushima (first)
Akiko Kobayashi (additional)
Takeshi Miyamoto (additional)
Yukiyoshi Sasaki (additional)

References 19 Referenced 14

10.1016/S0020-1693(00)93918-5
10.1246/bcsj.49.138
{'key': '2024011703393779100_r3'}
{'key': '2024011703393779100_r4'}
10.1351/pac197127010127
{'key': '2024011703393779100_r6'}
{'key': '2024011703393779100_r7'}
{'key': '2024011703393779100_r8'}
10.1021/ic50134a006
{'key': '2024011703393779100_r10'}
10.1021/ic50018a025
10.1021/ic50061a034
10.1021/ja00890a045
10.1021/ic50021a012
10.1021/ic50021a013
10.1016/S0022-328X(00)81759-3
10.1021/ic50096a039
10.1016/S0065-2792(08)60050-3
10.1002/cber.19620950143

Dates

Type	When
Created	19 years, 1 month ago (July 19, 2006, 10:37 p.m.)
Deposited	1 year, 7 months ago (Jan. 16, 2024, 10:39 p.m.)
Indexed	1 year, 2 months ago (June 5, 2024, 7:39 a.m.)
Issued	49 years, 7 months ago (Jan. 1, 1976)
Published	49 years, 7 months ago (Jan. 1, 1976)
Published Online	19 years, 4 months ago (April 19, 2006)
Published Print	49 years, 7 months ago (Jan. 1, 1976)

Funders 0

None

BibTeX

@article{Fukushima_1976, title={N-Allylprazole as a Ligand. III. The Crystal and Molecular Structure of (1-Allyl-3,5-dimethylpyrazole)copper(I) Chloride}, volume={49}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.49.143}, DOI={10.1246/bcsj.49.143}, number={1}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Fukushima, Kazuo and Kobayashi, Akiko and Miyamoto, Takeshi and Sasaki, Yukiyoshi}, year={1976}, month=jan, pages={143–146} }

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