DOI: 10.1246/bcsj.47.813. Standard Potentials of Alkali Metals, Silver, and Thallium Metal/Ion Couples in <i>N</i>,<i>N</i>′-Dimethylformamide, Dimethyl Sulfoxide, and Propylene Carbonate

Standard Potentials of Alkali Metals, Silver, and Thallium Metal/Ion Couples in N,N′-Dimethylformamide, Dimethyl Sulfoxide, and Propylene Carbonate

10.1246/bcsj.47.813

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract The relative standard potentials of alkali metals, silver, and thallium metal/ion couples in N,N′-dimethylforrnamide(DMF), dimethyl sulfoxide(DMSO), and propylene carbonate (PC) were measured against an aqueous saturated calomel electrode(SGE). These standard potentials of lithium, sodium, potassium, rubidium, caesium, thallium, and silver are −3.237, −2.898, −3.116, −3.079, −3.079, −0.643, and +0.372 V vs. SGE respectively in DMSO, and −3.163, −2.830, −3.067, −3.040, −3.048, −0.559, and +0.538 V vs. SGE respectively in DMF, and −2.9064, −2.691, −3.002, −2.980, −2.986, −0.402, and +0.813 V vs. SGE respectively in PC. The thallium electrode was found to be stable enough to be used as a reference electrode in these solvents. For the purpose of examining the Debye-Hückel equation for estimating the activity coefficient, the formal potentials of the thallium electrode were measured at various ionic strengths. The Debye-Hückel equation was confirmed to be applicable in these solvents, provided a proper value was chosen for the ionic radius parameter, a, for each solvent–3.6 for DMSO, 5.0 for DMF and 0.0 for PC.

Bibliography

Matsuura, N., Umemoto, K., & Takeuchi, Z. (1974). Standard Potentials of Alkali Metals, Silver, and Thallium Metal/Ion Couples in N,Nâ²-Dimethylformamide, Dimethyl Sulfoxide, and Propylene Carbonate. Bulletin of the Chemical Society of Japan, 47(4), 813â817.

Authors 3

Niro Matsuura (first)
Kisaburo Umemoto (additional)
Zen’ichi Takeuchi (additional)

References 10 Referenced 61

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10.1021/ja01929a009
10.1021/ja02203a001
10.1021/ja02193a004
10.1021/ja02174a004
10.1246/bcsj.47.806
10.1021/ja02232a006
{'key': '2024011723230459300_r8'}
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{'key': '2024011723230459300_r10'}

Dates

Type	When
Created	19 years, 1 month ago (July 19, 2006, 10:24 p.m.)
Deposited	1 year, 7 months ago (Jan. 17, 2024, 6:38 p.m.)
Indexed	1 week, 4 days ago (Aug. 12, 2025, 6:20 p.m.)
Issued	51 years, 4 months ago (April 1, 1974)
Published	51 years, 4 months ago (April 1, 1974)
Published Online	19 years, 4 months ago (March 27, 2006)
Published Print	51 years, 4 months ago (April 1, 1974)

Funders 0

None

BibTeX

@article{Matsuura_1974, title={Standard Potentials of Alkali Metals, Silver, and Thallium Metal/Ion Couples in N,N′-Dimethylformamide, Dimethyl Sulfoxide, and Propylene Carbonate}, volume={47}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.47.813}, DOI={10.1246/bcsj.47.813}, number={4}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Matsuura, Niro and Umemoto, Kisaburo and Takeuchi, Zen’ichi}, year={1974}, month=apr, pages={813–817} }

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