DOI: 10.1246/bcsj.47.1393. Molecular Structure of Tungsten Oxide Tetrachloride by Gas Electron Diffraction

Molecular Structure of Tungsten Oxide Tetrachloride by Gas Electron Diffraction

10.1246/bcsj.47.1393

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract The molecular structure of tungsten oxide tetrachloride was determined by the sector-microphotometer method of gas electron diffraction. The molecule was found to have a square-pyramidal structure, and the following molecular parameters were obtained by a least-squares method; rg(W–Cl)=2.281±0.003 Å, rg(W–O)=1.686±0.011 Å, and rg(Cl···Cl(s))=3.151±0.015 Å. The OWCl angle, 102.4±1.3°, is much larger than the corresponding angles found in other square-pyramidal molecules such as XeOF4 and IF5.

Bibliography

Iijima, K., & Shibata, S. (1974). Molecular Structure of Tungsten Oxide Tetrachloride by Gas Electron Diffraction. Bulletin of the Chemical Society of Japan, 47(6), 1393â1395.

Authors 2

Kinya Iijima (first)
Shuzo Shibata (additional)

References 22 Referenced 17

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10.1063/1.1734179
10.1063/1.1667964
10.1063/1.1696273
10.1016/0022-2860(71)80016-9
10.1021/ed040p295
10.1039/jr9630004672
10.1021/ic50070a020
{'key': '2024011723385866300_r9'}
10.1002/zaac.19663440306
{'key': '2024011723385866300_r11'}
10.1063/1.1841089
10.1063/1.1671226
{'key': '2024011723385866300_r14'}
{'key': '2024011723385866300_r15'}
10.1063/1.1669470
10.1246/bcsj.39.1134
10.1246/bcsj.45.1631
10.1246/bcsj.40.505
10.1107/S0365110X65001172
10.1063/1.1743999
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Dates

Type	When
Created	19 years, 1 month ago (July 19, 2006, 6:24 p.m.)
Deposited	1 year, 7 months ago (Jan. 17, 2024, 1:43 p.m.)
Indexed	1 year, 7 months ago (Jan. 17, 2024, 10 p.m.)
Issued	51 years, 3 months ago (June 1, 1974)
Published	51 years, 3 months ago (June 1, 1974)
Published Online	19 years, 5 months ago (March 27, 2006)
Published Print	51 years, 3 months ago (June 1, 1974)

Funders 0

None

BibTeX

@article{Iijima_1974, title={Molecular Structure of Tungsten Oxide Tetrachloride by Gas Electron Diffraction}, volume={47}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.47.1393}, DOI={10.1246/bcsj.47.1393}, number={6}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Iijima, Kinya and Shibata, Shuzo}, year={1974}, month=jun, pages={1393–1395} }

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