DOI: 10.1246/bcsj.46.3407. Vibrational Spectra and Molecular Conformations of Dialkyl Disulfides

Vibrational Spectra and Molecular Conformations of Dialkyl Disulfides

10.1246/bcsj.46.3407

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract The infrared and Raman spectra of several dialkyl disulfides were measured and their conformations were discussed in relation with the characteristic S–S and C–S stretching vibrations. The infrared spectra in the solid state and the temperature dependence of Raman spectra were measured for ethyl methyl disulfide and diethyl disulfide. For ethyl methyl disulfide, the gauche-gauche isomer was more stable than the trans-gauche isomer by about 0.9 kcal/mol while for diethyl disulfide the gauche-gauche-gauche isomer was more stable than the trans-gauche-gauche isomer by about 0.6 kcal/mol in the liquid state. Only the gauche-gauche form for ethyl methyl disulfide and only the gauche-gauche-gauche form for diethyl disulfide were observed in the solid state.

Bibliography

Sugeta, H., Go, A., & Miyazawa, T. (1973). Vibrational Spectra and Molecular Conformations of Dialkyl Disulfides. Bulletin of the Chemical Society of Japan, 46(11), 3407â3411.

Authors 3

Hiromu Sugeta (first)
Akikatsu Go (additional)
Tatsuo Miyazawa (additional)

References 12 Referenced 176

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10.1039/TF9504600429
10.1021/ja01162a021
10.1021/ja01130a009
10.1021/ja01547a014
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10.1016/0022-2860(69)80010-4
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10.1016/0584-8539(68)80192-8
{'key': '2024011717482424200_r11'}
{'key': '2024011717482424200_r12'}

Dates

Type	When
Created	19 years, 1 month ago (July 19, 2006, 10:06 p.m.)
Deposited	1 year, 7 months ago (Jan. 17, 2024, 1:33 p.m.)
Indexed	1 month, 3 weeks ago (June 30, 2025, 6:21 p.m.)
Issued	51 years, 9 months ago (Nov. 1, 1973)
Published	51 years, 9 months ago (Nov. 1, 1973)
Published Online	19 years, 4 months ago (March 27, 2006)
Published Print	51 years, 9 months ago (Nov. 1, 1973)

Funders 0

None

BibTeX

@article{Sugeta_1973, title={Vibrational Spectra and Molecular Conformations of Dialkyl Disulfides}, volume={46}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.46.3407}, DOI={10.1246/bcsj.46.3407}, number={11}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Sugeta, Hiromu and Go, Akikatsu and Miyazawa, Tatsuo}, year={1973}, month=nov, pages={3407–3411} }

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