DOI: 10.1246/bcsj.40.1124. Internal Rotation of Propane from the Microwave Spectrum

Internal Rotation of Propane from the Microwave Spectrum

10.1246/bcsj.40.1124

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract The microwave spectrum of propane was observed in the first-excited states of the CH3torsion. Each transition was split into a symmetric triplet; the splittings were 14–19% larger for the (−) state than for the (+) state. The top-top interaction and its effect on the rotational spectra were treated by the perturbation theory, and the results were applied to the analysis of the triplet splittings. The two barrier parameters, V3 and V3″, were thus determined to be 3325±20 and −170±30 cal/mol respectively.

Bibliography

Hirota, E., Matsumura, C., & Morino, Y. (1967). Internal Rotation of Propane from the Microwave Spectrum. Bulletin of the Chemical Society of Japan, 40(5), 1124â1130.

Authors 3

Eizi Hirota (first)
Chi Matsumura (additional)
Yonezo Morino (additional)

References 13 Referenced 55

10.1063/1.1731434
10.1063/1.1750722
{'key': '2024011821042959000_r3'}
10.1063/1.1730087
10.1063/1.1730653
10.1063/1.1730396
10.1063/1.1700973
{'key': '2024011821042959000_r8'}
10.1063/1.1731075
{'key': '2024011821042959000_r10'}
10.1063/1.1727882
10.1016/0371-1951(65)80145-X
{'key': '2024011821042959000_r13'}

Dates

Type	When
Created	19 years, 1 month ago (July 19, 2006, 9:06 p.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 4:05 p.m.)
Indexed	1 year, 5 months ago (March 4, 2024, 6:43 p.m.)
Issued	58 years, 4 months ago (May 1, 1967)
Published	58 years, 4 months ago (May 1, 1967)
Published Online	19 years, 5 months ago (March 27, 2006)
Published Print	58 years, 4 months ago (May 1, 1967)

Funders 0

None

BibTeX

@article{Hirota_1967, title={Internal Rotation of Propane from the Microwave Spectrum}, volume={40}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.40.1124}, DOI={10.1246/bcsj.40.1124}, number={5}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Hirota, Eizi and Matsumura, Chi and Morino, Yonezo}, year={1967}, month=may, pages={1124–1130} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        3,
        4
      ]
    ],
    "date-time": "2024-03-04T23:43:33Z",
    "timestamp": 1709595813050
  },
  "reference-count": 13,
  "publisher": "Oxford University Press (OUP)",
  "issue": "5",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1967,
            5,
            1
          ]
        ],
        "date-time": "1967-05-01T00:00:00Z",
        "timestamp": -84326400000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://academic.oup.com/pages/standard-publication-reuse-rights"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1967,
        5,
        1
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title>\n               <jats:p>The microwave spectrum of propane was observed in the first-excited states of the CH3torsion. Each transition was split into a symmetric triplet; the splittings were 14\u201319% larger for the (\u2212) state than for the (+) state. The top-top interaction and its effect on the rotational spectra were treated by the perturbation theory, and the results were applied to the analysis of the triplet splittings. The two barrier parameters, V3 and V3\u2033, were thus determined to be 3325\u00b120 and \u2212170\u00b130 cal/mol respectively.</jats:p>",
  "DOI": "10.1246/bcsj.40.1124",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2006,
        7,
        20
      ]
    ],
    "date-time": "2006-07-20T01:06:22Z",
    "timestamp": 1153357582000
  },
  "page": "1124-1130",
  "source": "Crossref",
  "is-referenced-by-count": 55,
  "title": "Internal Rotation of Propane from the Microwave Spectrum",
  "prefix": "10.1093",
  "volume": "40",
  "author": [
    {
      "given": "Eizi",
      "family": "Hirota",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry, Faculty of Science, The University of Tokyo"
        }
      ]
    },
    {
      "given": "Chi",
      "family": "Matsumura",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, Faculty of Science, The University of Tokyo"
        }
      ]
    },
    {
      "given": "Yonezo",
      "family": "Morino",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, Faculty of Science, The University of Tokyo"
        }
      ]
    }
  ],
  "member": "286",
  "published-online": {
    "date-parts": [
      [
        2006,
        3,
        27
      ]
    ]
  },
  "reference": [
    {
      "key": "2024011821042959000_r1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1731434"
    },
    {
      "key": "2024011821042959000_r2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1750722"
    },
    {
      "key": "2024011821042959000_r3"
    },
    {
      "key": "2024011821042959000_r4",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1730087"
    },
    {
      "key": "2024011821042959000_r5",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1730653"
    },
    {
      "key": "2024011821042959000_r6",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1730396"
    },
    {
      "key": "2024011821042959000_r7",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1700973"
    },
    {
      "key": "2024011821042959000_r8"
    },
    {
      "key": "2024011821042959000_r9",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1731075"
    },
    {
      "key": "2024011821042959000_r10"
    },
    {
      "key": "2024011821042959000_r11",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1727882"
    },
    {
      "key": "2024011821042959000_r12",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0371-1951(65)80145-X"
    },
    {
      "key": "2024011821042959000_r13"
    }
  ],
  "container-title": "Bulletin of the Chemical Society of Japan",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://academic.oup.com/bcsj/article-pdf/40/5/1124/55884625/bcsj.40.1124.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://academic.oup.com/bcsj/article-pdf/40/5/1124/55884625/bcsj.40.1124.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        1,
        18
      ]
    ],
    "date-time": "2024-01-18T21:05:50Z",
    "timestamp": 1705611950000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://academic.oup.com/bcsj/article/40/5/1124/7371245"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1967,
        5,
        1
      ]
    ]
  },
  "references-count": 13,
  "journal-issue": {
    "issue": "5",
    "published-online": {
      "date-parts": [
        [
          2006,
          3,
          27
        ]
      ]
    },
    "published-print": {
      "date-parts": [
        [
          1967,
          5,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1246/bcsj.40.1124",
  "relation": {},
  "ISSN": [
    "0009-2673",
    "1348-0634"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1967,
        5
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1967,
        5,
        1
      ]
    ]
  }
}