DOI: 10.1246/bcsj.20120274. Structural Dependence of Alcoholic Sacrificial Agents on TiO2-Photocatalytic Hydrogen Evolution

Structural Dependence of Alcoholic Sacrificial Agents on TiO2-Photocatalytic Hydrogen Evolution

10.1246/bcsj.20120274

Crossref journal-article

Oxford University Press (OUP)

Bulletin of the Chemical Society of Japan (286)

Abstract

Abstract The photocatalytic H2 evolution by Pt-loaded TiO2 was examined using sacrificial agents such as 1,2-ethanediol, glycerol, erythritol, and arabitol, the carbons of which all have hydroxy groups. In these cases, almost complete decomposition of sacrificial agents into CO2 and H2O occurred. Moreover, the H2 evolution reached the maximum values estimated by their potentially electron-donating ability. On the other hand, smaller amounts of CO2 and H2 were evolved from 1,2,3-butanetriol, 1,2,4-butanetriol, and 1,2-butanediol, which had both continuous hydroxylated carbons and one or two non-hydroxy-substituted carbons, the inner continuous 2,3-butanediol, and the discontinuous 1,3- and 1,4-butanediols. In the cases of monools such as 2-butanol and 2-propanol, CO2 was not evolved at all. Thus, we found that the structure of sacrificial agents, more so than the potential electron-donating ability, is an important factor to evolve H2 efficiently.

Bibliography

Shiragami, T., Tomo, T., Matsumoto, T., & Yasuda, M. (2013). Structural Dependence of Alcoholic Sacrificial Agents on TiO2-Photocatalytic Hydrogen Evolution. Bulletin of the Chemical Society of Japan, 86(3), 382â389.

Authors 4

Tsutomu Shiragami (first)
Takayuki Tomo (additional)
Tomoko Matsumoto (additional)
Masahide Yasuda (additional)

References 20 Referenced 22

Dates

Type	When
Created	12 years, 5 months ago (March 5, 2013, 2:47 a.m.)
Deposited	1 year, 7 months ago (Jan. 20, 2024, 4:31 p.m.)
Indexed	1 month ago (July 24, 2025, 7:30 a.m.)
Issued	12 years, 5 months ago (March 1, 2013)
Published	12 years, 5 months ago (March 1, 2013)
Published Online	12 years, 5 months ago (March 5, 2013)
Published Print	12 years, 5 months ago (March 15, 2013)

Funders 0

None

BibTeX

@article{Shiragami_2013, title={Structural Dependence of Alcoholic Sacrificial Agents on TiO2-Photocatalytic Hydrogen Evolution}, volume={86}, ISSN={1348-0634}, url={http://dx.doi.org/10.1246/bcsj.20120274}, DOI={10.1246/bcsj.20120274}, number={3}, journal={Bulletin of the Chemical Society of Japan}, publisher={Oxford University Press (OUP)}, author={Shiragami, Tsutomu and Tomo, Takayuki and Matsumoto, Tomoko and Yasuda, Masahide}, year={2013}, month=mar, pages={382–389} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        24
      ]
    ],
    "date-time": "2025-07-24T11:30:11Z",
    "timestamp": 1753356611641
  },
  "reference-count": 20,
  "publisher": "Oxford University Press (OUP)",
  "issue": "3",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2013,
            3,
            1
          ]
        ],
        "date-time": "2013-03-01T00:00:00Z",
        "timestamp": 1362096000000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://academic.oup.com/pages/standard-publication-reuse-rights"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2013,
        3,
        15
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title>\n               <jats:p>The photocatalytic H2 evolution by Pt-loaded TiO2 was examined using sacrificial agents such as 1,2-ethanediol, glycerol, erythritol, and arabitol, the carbons of which all have hydroxy groups. In these cases, almost complete decomposition of sacrificial agents into CO2 and H2O occurred. Moreover, the H2 evolution reached the maximum values estimated by their potentially electron-donating ability. On the other hand, smaller amounts of CO2 and H2 were evolved from 1,2,3-butanetriol, 1,2,4-butanetriol, and 1,2-butanediol, which had both continuous hydroxylated carbons and one or two non-hydroxy-substituted carbons, the inner continuous 2,3-butanediol, and the discontinuous 1,3- and 1,4-butanediols. In the cases of monools such as 2-butanol and 2-propanol, CO2 was not evolved at all. Thus, we found that the structure of sacrificial agents, more so than the potential electron-donating ability, is an important factor to evolve H2 efficiently.</jats:p>",
  "DOI": "10.1246/bcsj.20120274",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2013,
        3,
        5
      ]
    ],
    "date-time": "2013-03-05T07:47:40Z",
    "timestamp": 1362469660000
  },
  "page": "382-389",
  "source": "Crossref",
  "is-referenced-by-count": 22,
  "title": "Structural Dependence of Alcoholic Sacrificial Agents on TiO2-Photocatalytic Hydrogen Evolution",
  "prefix": "10.1093",
  "volume": "86",
  "author": [
    {
      "given": "Tsutomu",
      "family": "Shiragami",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki"
        }
      ]
    },
    {
      "given": "Takayuki",
      "family": "Tomo",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki"
        }
      ]
    },
    {
      "given": "Tomoko",
      "family": "Matsumoto",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Center for Collaborative Research and Community Cooperation, University of Miyazaki"
        }
      ]
    },
    {
      "given": "Masahide",
      "family": "Yasuda",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki"
        }
      ]
    }
  ],
  "member": "286",
  "published-online": {
    "date-parts": [
      [
        2013,
        3,
        5
      ]
    ]
  },
  "reference": [
    {
      "key": "2024012021313555700_r1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr0501994"
    },
    {
      "key": "2024012021313555700_r2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/238037a0"
    },
    {
      "key": "2024012021313555700_r3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jphotochemrev.2011.02.003"
    },
    {
      "key": "2024012021313555700_r4",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/1010-6030(93)85052-A"
    },
    {
      "key": "2024012021313555700_r5",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0009-2614(81)80121-2"
    },
    {
      "key": "2024012021313555700_r6",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es970860o"
    },
    {
      "key": "2024012021313555700_r7",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S1389-5567(00)00002-2"
    },
    {
      "key": "2024012021313555700_r8",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ef0400619"
    },
    {
      "key": "2024012021313555700_r9",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200604274"
    },
    {
      "key": "2024012021313555700_r10",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/cl.2012.29"
    },
    {
      "key": "2024012021313555700_r11",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01650a019"
    },
    {
      "key": "2024012021313555700_r12",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jcat.2010.05.012"
    },
    {
      "key": "2024012021313555700_r13",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.cattod.2007.01.022"
    },
    {
      "key": "2024012021313555700_r14",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.apcatb.2006.05.007"
    },
    {
      "key": "2024012021313555700_r15",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.ijhydene.2009.09.019"
    },
    {
      "key": "2024012021313555700_r16",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.cattod.2008.11.009"
    },
    {
      "key": "2024012021313555700_r17",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.apcatb.2011.07.015"
    },
    {
      "key": "2024012021313555700_r18",
      "doi-asserted-by": "publisher",
      "DOI": "10.3390/catal2010056"
    },
    {
      "key": "2024012021313555700_r19",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.ijhydene.2008.07.068"
    },
    {
      "key": "2024012021313555700_r20",
      "doi-asserted-by": "publisher",
      "DOI": "10.1006/jcat.1998.2242"
    }
  ],
  "container-title": "Bulletin of the Chemical Society of Japan",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://academic.oup.com/bcsj/article-pdf/86/3/382/56275050/bcsj.20120274.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://academic.oup.com/bcsj/article-pdf/86/3/382/56275050/bcsj.20120274.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        1,
        20
      ]
    ],
    "date-time": "2024-01-20T21:31:46Z",
    "timestamp": 1705786306000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://academic.oup.com/bcsj/article/86/3/382/7344058"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2013,
        3
      ]
    ]
  },
  "references-count": 20,
  "journal-issue": {
    "issue": "3",
    "published-online": {
      "date-parts": [
        [
          2013,
          3,
          5
        ]
      ]
    },
    "published-print": {
      "date-parts": [
        [
          2013,
          3,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1246/bcsj.20120274",
  "relation": {},
  "ISSN": [
    "0009-2673",
    "1348-0634"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        2013,
        3
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        2013,
        3
      ]
    ]
  }
}