DOI: 10.1243/pime_proc_1993_207_156_02. NO<sub>x</sub> Emission Control in Oxygen-Rich Exhaust Through Selective Catalytic Reduction by Hydrocarbon

NOx Emission Control in Oxygen-Rich Exhaust Through Selective Catalytic Reduction by Hydrocarbon

10.1243/pime_proc_1993_207_156_02

Crossref journal-article

SAGE Publications

Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering (179)

Abstract

Selective catalytic reduction of nitrogen monoxide by hydrocarbon in the presence of oxygen and sulphur dioxide has very recently been found on copper ion-exchanged ZSM-5 zeolite (Cu-ZSM-5). The reaction proceeds even in the oxidizing atmosphere at temperatures as low as 573 K. Addition of oxygen to the reactant stream is necessary to achieve the selective reduction of nitrogen monoxide. The increment of concentration of hydrocarbon increased the conversion into nitrogen and expanded the active temperature region. After summarizing the new findings on Cu-ZSM-5, the present review introduces catalytic activities of various metal-ion exchanged zeolites and metal-loaded aluminas. Based on the temperature dependence of each catalyst and the change of conversion of nitrogen monoxide into nitrogen with space velocity, Cu-ZSM-5 is suggested as one of the strong candidates for catalysts applicable to lean-burn gasoline and diesel engines, though several problems such as durability to water and overheating remain to be solved.

Bibliography

Iwamoto, M., & Mizuno, N. (1993). NOx Emission Control in Oxygen-Rich Exhaust Through Selective Catalytic Reduction by Hydrocarbon. Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, 207(1), 23â33.

Authors 2

M Iwamoto (first)
N Mizuno (additional)

References 46 Referenced 104

{'volume-title': 'Catalysis and automotive pollution control', 'year': '1987', 'author': 'Crucq A.', 'key': 'bibr1-PIME_PROC_1993_207_156_02'} / Catalysis and automotive pollution control by Crucq A. (1987)
10.1007/978-1-4615-8741-5_5
10.1039/f19817701629
{'key': 'bibr4-PIME_PROC_1993_207_156_02', 'first-page': '119', 'volume-title': 'Catalysis', 'volume': '5', 'author': 'Taylor K. C.', 'year': '1982'} / Catalysis by Taylor K. C. (1982)
10.1021/j100162a053
10.1246/cl.1988.1797
{'key': 'bibr7-PIME_PROC_1993_207_156_02', 'first-page': '132', 'volume': '18', 'author': 'Uchijima T.', 'year': '1987', 'journal-title': 'Hyomen'} / Hyomen by Uchijima T. (1987)
10.1246/cl.1990.1
10.1039/C39900001094
10.1246/cl.1990.1069
10.1016/S0167-2991(08)60037-3
10.1016/0920-5861(91)80074-J
Iwamoto M. Decomposition of NO on copper ion-exchanged zeolite catalysts. Proceedings of Meeting on Catalytic technology for removal of nitrogen monoxide, Tokyo, January 1990, p. 17.
Held W., König A., Richter T., Puppe L. Catalytic NOx reduction in net oxidizing exhaust gas. SAE paper 900496, 1990. (10.4271/900496)
{'key': 'bibr15-PIME_PROC_1993_207_156_02', 'first-page': '430', 'volume': '32', 'author': 'Iwamoto M.', 'year': '1990', 'journal-title': 'Shokubai (Catalyst)'} / Shokubai (Catalyst) by Iwamoto M. (1990)
Iwamoto M., Mizuno N., Yahiro H. Selective catalytic reduction of NO by hydrocarbon in oxidizing atmosphere. Proceedings of Tenth International Congress on Catalysis, Budapest, 1992, paper 088. (10.1016/S0167-2991(08)64451-1)
10.1016/S0166-9834(00)83286-8
10.1016/0920-5861(89)85047-3 / Catal. Today by Bosch H. (1989)
{'key': 'bibr19-PIME_PROC_1993_207_156_02', 'first-page': '448', 'volume': '33', 'author': 'Sato S.', 'year': '1991', 'journal-title': 'Shokubai (Catalyst)'} / Shokubai (Catalyst) by Sato S. (1991)
Konno M., Chikahisa T., Murayama T., Iwamoto M. Catalytic reduction of NOx in actual diesel engine exhaust. SAE paper 920091, 1992. (10.4271/920091)
10.1016/0926-3373(92)80001-G
10.1007/BF00764083
Yu-u Y., Yahiro H., Mizuno N., Iwamoto M. Studies on the mechanism of selective catalytic reduction of NO on Cu-MFI zeolites with infrared spectroscopy. Proceedings of Sixty-third National Meeting of Chemical Society of Japan, Osaka, 1992, paper 2C428.
10.1039/c39920000247
{'key': 'bibr25-PIME_PROC_1993_207_156_02', 'first-page': '77', 'volume': '33', 'author': 'Inui T.', 'year': '1991', 'journal-title': 'Shokubai (Catalyst)'} / Shokubai (Catalyst) by Inui T. (1991)
10.1007/BF00770950
{'key': 'bibr27-PIME_PROC_1993_207_156_02', 'first-page': '59', 'volume': '33', 'author': 'Hamada H.', 'year': '1991', 'journal-title': 'Shokubai (Catalyst)'} / Shokubai (Catalyst) by Hamada H. (1991)
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Iwamoto M., Yahiro H., Mizuno N. Selective reduction of NO by hydrocarbon in O2 on metal ion-exchanged zeolite catalysts. Proceedings of Ninth International Conference on Zeolites, Montreal, 1992, paper B7. (10.1016/B978-1-4832-8383-8.50132-X)
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Mochida I., Fujitsu H., Yasuda N. Activation of NO on Fe-zeolite catalysts. Proceedings of Fifth Meeting of Zeolite Research Society of Japan, Nagoya, 1990, p. 22.
Kondo S., Murai H., Ishibashi K., Matsumoto S., Sekizawa K. Studies on development of catalysts for NO removal in oxidizing atmosphere of automobile exhaust (1). Proceedings of Sixty-first National Meeting of Chemical Society of Japan, Tokyo, 1991, paper 3H201.
Yokota K., Kimura M., Dai H., Sekizawa K. Studies on development of catalysts for NO removal in oxidizing atmosphere of automobile exhaust (4). Proceedings of Sixty-first National Meeting of Chemical Society of Japan, Tokyo, 1991, paper 3H204.
10.1007/BF00765065
10.1246/cl.1991.1001
Nakatsuji T., Shimizu H., Yasukawa R. Catalytic reduction of nitrogen oxides with hydrocarbons over perovskite catalysts supported on solid acid catalysts. Proceedings of First Japan-EC Joint Workshop on The frontiers of catalytic science and technology, Tokyo, 1991, p. 274.
Kikuchi E., Takegoshi G., Ishihara T., Matsuda T. Reduction of NO by CO on supported Ir catalysts. Proceedings of Sixty-eightth Meeting of Catalysis Society of Japan, Hokkaido, 1991, paper 2J18.
10.1016/S0166-9834(00)83117-6
10.1007/BF00769086

Dates

Type	When
Created	18 years, 6 months ago (Feb. 20, 2007, 12:17 p.m.)
Deposited	6 months ago (March 1, 2025, 1 a.m.)
Indexed	2 months, 1 week ago (June 27, 2025, 4:03 p.m.)
Issued	32 years, 8 months ago (Jan. 1, 1993)
Published	32 years, 8 months ago (Jan. 1, 1993)
Published Online	32 years, 8 months ago (Jan. 1, 1993)
Published Print	32 years, 8 months ago (Jan. 1, 1993)

Funders 0

None

BibTeX

@article{Iwamoto_1993, title={NOx Emission Control in Oxygen-Rich Exhaust Through Selective Catalytic Reduction by Hydrocarbon}, volume={207}, ISSN={2041-2991}, url={http://dx.doi.org/10.1243/pime_proc_1993_207_156_02}, DOI={10.1243/pime_proc_1993_207_156_02}, number={1}, journal={Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering}, publisher={SAGE Publications}, author={Iwamoto, M and Mizuno, N}, year={1993}, month=jan, pages={23–33} }

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