DOI: 10.1180/claymin.1986.021.1.01. Interlayer adsorption of macrocyclic compounds (crown-ethers and cryptands) in 2:1 phyllosilicates: I. Isotherms and kinetics

Interlayer adsorption of macrocyclic compounds (crown-ethers and cryptands) in 2:1 phyllosilicates: I. Isotherms and kinetics

10.1180/claymin.1986.021.1.01

Crossref journal-article

Mineralogical Society

Clay Minerals (7149)

Abstract

AbstractThe intercalation process of crown-ethers and cryptands into Ba2+- and Na+-montmorillonites leads to H-type adsorption isotherms according to the Giles et al. classification. The experimental monolayer capacity shows that 1:1 or 2:1 macrocyclic ligand/interlayer cation complexes can be produced. Kinetic experiments at different temperatures indicate that the intercalation is diffusion-controlled. The activation energies deduced from Arrhenius plots are 25–38 kJ mol−1.

Bibliography

Casal, B., & Ruiz-Hitzky, E. (1986). Interlayer adsorption of macrocyclic compounds (crown-ethers and cryptands) in 2:1 phyllosilicates: I. Isotherms and kinetics. Clay Minerals, 21(1), 1â7.

Authors 2

B. Casal (first)
E. Ruiz-Hitzky (additional)

References 15 Referenced 16

10.1180/claymin.1979.014.4.02
Giles C.H. , Macewan T.H. , Nakhma S.N. & Smith D. (1960) Studies in adsorption. Part. XI, A system of classification of solution adsorption isotherms and its use in diagnosis of adsorption mechanisms and in measurements of specific surface areas of solids. J. Chem. Soc. 3973–3993.
{'key': 'S0009855800012103_ref004', 'volume-title': 'Introduction a la Cinetique Heterogene.', 'author': 'Delmon', 'year': '1969'} / Introduction a la Cinetique Heterogene. by Delmon (1969)
{'key': 'S0009855800012103_ref009', 'volume-title': 'Adsorption from Solutions of Non-Electrolytes', 'author': 'Kipling', 'year': '1965'} / Adsorption from Solutions of Non-Electrolytes by Kipling (1965)
Mifsud C.A. (1975) Cinética de la reacción de cambio iónico de vermiculita con monocloruro de L-ornitina. PhD Thesis, Universidad Complutense, Madrid.
{'key': 'S0009855800012103_ref008', 'volume-title': 'Progress in Macrocyclic Chemistry (I and II).', 'author': 'Izatt', 'year': '1979'} / Progress in Macrocyclic Chemistry (I and II). by Izatt (1979)
{'key': 'S0009855800012103_ref010', 'first-page': '49', 'volume-title': 'Acc. Chem. Res.', 'volume': 'l1', 'author': 'Lehn', 'year': '1978'} / Acc. Chem. Res. by Lehn (1978)
{'key': 'S0009855800012103_ref005', 'first-page': '769', 'article-title': 'Estudio de la reacción de caolinita y N-metilformamida', 'volume': 'B65', 'author': 'Fenoll', 'year': '1969', 'journal-title': 'An. R.S. Esp. Fis. Quim.'} / An. R.S. Esp. Fis. Quim. / Estudio de la reacción de caolinita y N-metilformamida by Fenoll (1969)
{'key': 'S0009855800012103_ref003', 'first-page': '49', 'article-title': 'Estudio por espectroscopía IR y UV de la adsorción interlaminar de polieteres macrocícicos en filosilicatos', 'volume': '18', 'author': 'Casal', 'year': '1985', 'journal-title': 'Opt. Pur. y Apl.'} / Opt. Pur. y Apl. / Estudio por espectroscopía IR y UV de la adsorción interlaminar de polieteres macrocícicos en filosilicatos by Casal (1985)
10.1021/ja01002a035
Casal B. (1983) Estudio de la interacción de compuestos macrocíclicos (éteres-corona y criptandos) con filosilicatos. PhD Thesis, Universidad Complutense, Madrid.
10.1038/276596a0
{'key': 'S0009855800012103_ref014', 'first-page': '379', 'article-title': 'Numerical data for some commonly used solid-state reaction equations', 'volume': '49', 'author': 'Sharp', 'year': '1966', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. / Numerical data for some commonly used solid-state reaction equations by Sharp (1966)
{'key': 'S0009855800012103_ref015', 'volume-title': 'An Introduction to Clay Colloid Chemistry (2nd edition).', 'author': 'Vand Olphen', 'year': '1977'} / An Introduction to Clay Colloid Chemistry (2nd edition). by Vand Olphen (1977)
10.1016/0040-6031(79)85024-8

Dates

Type	When
Created	18 years, 9 months ago (Nov. 16, 2006, 5:58 a.m.)
Deposited	6 years, 3 months ago (May 22, 2019, 3:30 a.m.)
Indexed	1 year, 5 months ago (April 2, 2024, 12:34 a.m.)
Issued	39 years, 6 months ago (March 1, 1986)
Published	39 years, 6 months ago (March 1, 1986)
Published Online	7 years, 1 month ago (July 9, 2018)
Published Print	39 years, 6 months ago (March 1, 1986)

Funders 0

None

BibTeX

@article{Casal_1986, title={Interlayer adsorption of macrocyclic compounds (crown-ethers and cryptands) in 2:1 phyllosilicates: I. Isotherms and kinetics}, volume={21}, ISSN={1471-8030}, url={http://dx.doi.org/10.1180/claymin.1986.021.1.01}, DOI={10.1180/claymin.1986.021.1.01}, number={1}, journal={Clay Minerals}, publisher={Mineralogical Society}, author={Casal, B. and Ruiz-Hitzky, E.}, year={1986}, month=mar, pages={1–7} }

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