DOI: 10.1180/claymin.1984.019.4.01. Ferrous-iron-bearing vermiculite-smectite series formed during alteration of chlorite to kaolinite, Otago Schist, New Zealand

Ferrous-iron-bearing vermiculite-smectite series formed during alteration of chlorite to kaolinite, Otago Schist, New Zealand

10.1180/claymin.1984.019.4.01

Crossref journal-article

Mineralogical Society

Clay Minerals (7149)

Abstract

AbstractInterlayered (<20 µm scale) vermiculite-smectite minerals were found in drill-cores from altered Otago schist basement up to 2 m from the contact with the overlying sediment. Mineral compositions defined a series from Fe2+-rich trioctahedral vermiculite to Fe2+-bearing dioctahedral smectite; in these, tetrahedral substitution of Al for Si was unusually high (up to 3·3/8 in the formula unit). The minerals formed as intermediates during the alteration of chlorite to kaolinite under non-oxidizing, possibly acid conditions. The source of the altering solutions may have been overlying lignite seams.

Bibliography

Craw, D. (1984). Ferrous-iron-bearing vermiculite-smectite series formed during alteration of chlorite to kaolinite, Otago Schist, New Zealand. Clay Minerals, 19(4), 509â520.

Authors 1

D. Craw (first)

References 31 Referenced 25

{'key': 'S0009855800009213_ref017', 'first-page': '393', 'volume-title': 'The X-ray Identification and Crystal Structures of Clay Minerals', 'author': 'McEwan', 'year': '1961'} / The X-ray Identification and Crystal Structures of Clay Minerals by McEwan (1961)
{'key': 'S0009855800009213_ref014', 'first-page': '596', 'volume-title': 'Clay Mineralogy.', 'author': 'Grim', 'year': '1968'} / Clay Mineralogy. by Grim (1968)
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10.1180/minmag.1982.045.337.09
{'key': 'S0009855800009213_ref012', 'volume-title': 'Distribution and deposition of coal-bearing Manuherikia Group, central Otago.', 'author': 'Douglas', 'year': '1984'} / Distribution and deposition of coal-bearing Manuherikia Group, central Otago. by Douglas (1984)
{'key': 'S0009855800009213_ref019', 'first-page': '1161', 'article-title': 'Experimental formation of kaolinite from montmorillonite at low temperatures', 'volume': '52', 'author': 'Poncelet', 'year': '1967', 'journal-title': 'Am. Miner.'} / Am. Miner. / Experimental formation of kaolinite from montmorillonite at low temperatures by Poncelet (1967)
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10.1346/CCMN.1982.0300604
10.1016/0040-1951(78)90038-0
{'key': 'S0009855800009213_ref001', 'first-page': '83', 'article-title': 'Die ‘Viridite’ im Tholeyit von Tholey (Saar)', 'volume': '120', 'author': 'Arikas', 'year': '1974', 'journal-title': 'Neues. Jahrb. Mineral. Abhdl.'} / Neues. Jahrb. Mineral. Abhdl. / Die ‘Viridite’ im Tholeyit von Tholey (Saar) by Arikas (1974)
{'key': 'S0009855800009213_ref027', 'first-page': 'l01', 'article-title': 'Formation of aluminous hydroxy vermiculite (intergrade) and smectite from mica under acidic conditions', 'volume': '12', 'author': 'Vincente', 'year': '1977', 'journal-title': 'Clay Miner.'} / Clay Miner. / Formation of aluminous hydroxy vermiculite (intergrade) and smectite from mica under acidic conditions by Vincente (1977)
10.1180/claymin.1982.017.3.06
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{'key': 'S0009855800009213_ref028', 'first-page': '78', 'article-title': 'Lattice expansion of kaolin minerals by treatment with potassium acetate', 'volume': '46', 'author': 'Wada', 'year': '1961', 'journal-title': 'Am. Miner.'} / Am. Miner. / Lattice expansion of kaolin minerals by treatment with potassium acetate by Wada (1961)
Blakemore L.C. , Searle P.L. & Daly B.K. (1972) Methods for chemical analysis of soils. New Zealand Soil Bureau Scientific Report 10A.
{'key': 'S0009855800009213_ref011', 'volume-title': 'Rock-forming Minerals, vol. 3 Sheet Silicates.', 'author': 'Deer', 'year': '1963'} / Rock-forming Minerals, vol. 3 Sheet Silicates. by Deer (1963)
{'key': 'S0009855800009213_ref026', 'first-page': '37', 'article-title': 'Experimental formation of kaolinite from vermiculite', 'volume': '4', 'author': 'Urabe', 'year': '1970', 'journal-title': 'Clay Sci.'} / Clay Sci. / Experimental formation of kaolinite from vermiculite by Urabe (1970)
{'key': 'S0009855800009213_ref029', 'first-page': '297', 'volume-title': 'The X-ray Identification and Crystal Structures of Clay Minerals', 'author': 'Walker', 'year': '1961'} / The X-ray Identification and Crystal Structures of Clay Minerals by Walker (1961)
{'key': 'S0009855800009213_ref030', 'first-page': '56', 'article-title': 'A new method for the determination of ferrous iron in rocks and minerals', 'volume': '9', 'author': 'Wilson', 'year': '1955', 'journal-title': 'Bull. Geol. Surv. Great Britain'} / Bull. Geol. Surv. Great Britain / A new method for the determination of ferrous iron in rocks and minerals by Wilson (1955)
{'key': 'S0009855800009213_ref024', 'first-page': '203', 'article-title': 'Kaolinite-enrichment beneath coals: a modern analog, Snuggedy Swamp, South Carolina. J', 'volume': '48', 'author': 'Staub', 'year': '1978', 'journal-title': 'Sed. Petrol.'} / Sed. Petrol. / Kaolinite-enrichment beneath coals: a modern analog, Snuggedy Swamp, South Carolina. J by Staub (1978)
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10.5575/geosoc.60.18

Dates

Type	When
Created	18 years, 8 months ago (Dec. 7, 2006, 6:02 p.m.)
Deposited	6 years, 3 months ago (May 23, 2019, 3:46 p.m.)
Indexed	1 year, 10 months ago (Oct. 30, 2023, 1:13 a.m.)
Issued	41 years ago (Sept. 1, 1984)
Published	41 years ago (Sept. 1, 1984)
Published Online	7 years, 1 month ago (July 9, 2018)
Published Print	41 years ago (Sept. 1, 1984)

Funders 0

None

BibTeX

@article{Craw_1984, title={Ferrous-iron-bearing vermiculite-smectite series formed during alteration of chlorite to kaolinite, Otago Schist, New Zealand}, volume={19}, ISSN={1471-8030}, url={http://dx.doi.org/10.1180/claymin.1984.019.4.01}, DOI={10.1180/claymin.1984.019.4.01}, number={4}, journal={Clay Minerals}, publisher={Mineralogical Society}, author={Craw, D.}, year={1984}, month=sep, pages={509–520} }

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