DOI: 10.1149/1.1394077. Aluminum Corrosion in Lithium Batteries An Investigation Using the Electrochemical Quartz Crystal Microbalance

Aluminum Corrosion in Lithium Batteries An Investigation Using the Electrochemical Quartz Crystal Microbalance

10.1149/1.1394077

Crossref journal-article

The Electrochemical Society

Journal of The Electrochemical Society (77)

Abstract

An electrochemical quartz crystal microbalance is used in an investigation of the corrosion of aluminum in electrolytes appropriate for lithium batteries. The electrolytes are solutions of LiN ( CF 3 SO 2 ) 2 , LiC ( CF 3 SO 2 ) 3 , LiCF 3 SO 3 , LiPF 6 , LiBF 4 , and LiClO 4 , singly or in a limited number of combinations, in propylene carbonate (PC) and polyethylene glycol dimethyl ether. Aluminum that is scratched or abraded in an inert atmosphere (so that a protective surface film does not reform) undergoes significant corrosion in PC containing LiN ( CF 3 SO 2 ) 2 , LiC ( CF 3 SO 2 ) 3 , LiCF 3 SO 3 , and LiClO 4 , but forms a protective film in PC containing LiPF 6 , or LiBF 4 . A mechanism of corrosion of aluminum in LiN ( CF 3 SO 2 ) 2 / PC is proposed. © 2000 The Electrochemical Society. All rights reserved.

Bibliography

Yang, H., Kwon, K., Devine, T. M., & Evans, J. W. (2000). Aluminum Corrosion in Lithium Batteries An Investigation Using the Electrochemical Quartz Crystal Microbalance. Journal of The Electrochemical Society, 147(12), 4399â4407.

Authors 4

Haesik Yang (first)
Kyungjung Kwon (additional)
Thomas M. Devine (additional)
James W. Evans (additional)

References 0 Referenced 222

None

Dates

Type	When
Created	23 years ago (July 28, 2002, 6:22 p.m.)
Deposited	3 years, 8 months ago (Dec. 13, 2021, 8:43 a.m.)
Indexed	2 weeks ago (Aug. 7, 2025, 4:50 p.m.)
Issued	24 years, 8 months ago (Dec. 1, 2000)
Published	24 years, 8 months ago (Dec. 1, 2000)
Published Print	24 years, 8 months ago (Dec. 1, 2000)

Funders 0

None

BibTeX

@article{Yang_2000, title={Aluminum Corrosion in Lithium Batteries An Investigation Using the Electrochemical Quartz Crystal Microbalance}, volume={147}, ISSN={1945-7111}, url={http://dx.doi.org/10.1149/1.1394077}, DOI={10.1149/1.1394077}, number={12}, journal={Journal of The Electrochemical Society}, publisher={The Electrochemical Society}, author={Yang, Haesik and Kwon, Kyungjung and Devine, Thomas M. and Evans, James W.}, year={2000}, month=dec, pages={4399–4407} }

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  "abstract": "<jats:p>An electrochemical quartz crystal microbalance is used in an investigation of the corrosion of aluminum in electrolytes appropriate for lithium batteries. The electrolytes are solutions of <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML1\" overflow=\"scroll\">\n                        <mml:mi mathvariant=\"normal\">LiN</mml:mi>\n                        <mml:mo stretchy=\"false\">(</mml:mo>\n                        <mml:msub>\n                           <mml:mo>CF</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>3</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                        <mml:msub>\n                           <mml:mo>SO</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>2</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                        <mml:msub>\n                           <mml:mo stretchy=\"false\">)</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>2</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn1.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML2\" overflow=\"scroll\">\n                        <mml:mi mathvariant=\"normal\">LiC</mml:mi>\n                        <mml:mo stretchy=\"false\">(</mml:mo>\n                        <mml:msub>\n                           <mml:mo>CF</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>3</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                        <mml:msub>\n                           <mml:mo>SO</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>2</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                        <mml:msub>\n                           <mml:mo stretchy=\"false\">)</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>3</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn2.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML3\" overflow=\"scroll\">\n                        <mml:msub>\n                           <mml:mi mathvariant=\"normal\">LiCF</mml:mi>\n                           <mml:mrow>\n                              <mml:mn>3</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                        <mml:msub>\n                           <mml:mo>SO</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>3</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn3.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML4\" overflow=\"scroll\">\n                        <mml:msub>\n                           <mml:mi mathvariant=\"normal\">LiPF</mml:mi>\n                           <mml:mrow>\n                              <mml:mn>6</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn4.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML5\" overflow=\"scroll\">\n                        <mml:msub>\n                           <mml:mi mathvariant=\"normal\">LiBF</mml:mi>\n                           <mml:mrow>\n                              <mml:mn>4</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn5.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, and <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML6\" overflow=\"scroll\">\n                        <mml:msub>\n                           <mml:mi mathvariant=\"normal\">LiClO</mml:mi>\n                           <mml:mrow>\n                              <mml:mn>4</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn6.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, singly or in a limited number of combinations, in propylene carbonate (PC) and polyethylene glycol dimethyl ether. 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           <mml:mo stretchy=\"false\">)</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>2</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn7.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML8\" overflow=\"scroll\">\n                        <mml:mi mathvariant=\"normal\">LiC</mml:mi>\n                        <mml:mo stretchy=\"false\">(</mml:mo>\n                        <mml:msub>\n                           <mml:mo>CF</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>3</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                    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                <mml:mrow>\n                              <mml:mn>3</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                        <mml:msub>\n                           <mml:mo>SO</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>3</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn9.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, and <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML10\" overflow=\"scroll\">\n                        <mml:msub>\n                           <mml:mi mathvariant=\"normal\">LiClO</mml:mi>\n                           <mml:mrow>\n                              <mml:mn>4</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn10.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, but forms a protective film in PC containing <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML11\" overflow=\"scroll\">\n                        <mml:msub>\n                           <mml:mi mathvariant=\"normal\">LiPF</mml:mi>\n                           <mml:mrow>\n                              <mml:mn>6</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn11.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>, or <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML12\" overflow=\"scroll\">\n                        <mml:msub>\n                           <mml:mi mathvariant=\"normal\">LiBF</mml:mi>\n                           <mml:mrow>\n                              <mml:mn>4</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn12.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula>. A mechanism of corrosion of aluminum in <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\" id=\"ML13\" overflow=\"scroll\">\n                        <mml:mi mathvariant=\"normal\">LiN</mml:mi>\n                        <mml:mo stretchy=\"false\">(</mml:mo>\n                        <mml:msub>\n                           <mml:mo>CF</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>3</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                        <mml:msub>\n                           <mml:mo>SO</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>2</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                        <mml:msub>\n                           <mml:mo stretchy=\"false\">)</mml:mo>\n                           <mml:mrow>\n                              <mml:mn>2</mml:mn>\n                           </mml:mrow>\n                        </mml:msub>\n                        <mml:mo>/</mml:mo>\n                        <mml:mo>PC</mml:mo>\n                     </mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"jes_147_12_4399ieqn13.jpg\" xlink:type=\"simple\"/>\n                  </jats:inline-formula> is proposed. \u00a9 2000 The Electrochemical Society. All rights reserved.</jats:p>",
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