10.1146/annurev.physchem.57.032905.104748
Crossref journal-article
Annual Reviews
Annual Review of Physical Chemistry (22)
Abstract

▪ Abstract  In this review, we highlight the progress made in the development of 4D ultrafast electron diffraction (UED), crystallography (UEC), and microscopy (UEM) with a focus on concepts, methodologies, and prototypical applications. The joint atomic-scale resolutions in space and time, and sensitivity reached, make it possible to determine complex transient structures and assemblies in different phases. These applications include studies of isolated chemical reactions (molecular beams), interfaces, surfaces and nanocrystals, self-assembly, and 2D crystalline fatty-acid bilayers. In 4D UEM, we are now able, using timed, single-electron packets, to image nano-to-micro scale structures of materials and biological cells. Future applications of these methods are foreseen across areas of physics, chemistry, and biology.

Bibliography

Zewail, A. H. (2006). 4D ULTRAFAST ELECTRON DIFFRACTION, CRYSTALLOGRAPHY, AND MICROSCOPY. Annual Review of Physical Chemistry, 57(1), 65–103.

Authors 1
  1. Ahmed H. Zewail (first)
References 119 Referenced 478
  1. 10.1098/rsta.2004.1512
  2. Zewail AH. 2000. InLes Prix Nobel: The Nobel Prizes 1999, ed.T Frängsmyr, p.103. Stockholm: Almqvist, Wiksell
  3. 10.1098/rsta.2004.1513
  4. 10.1002/hlca.200390147
  5. {'key': 'B5', 'volume-title': 'The Chemical Bond: Structure and Dynamics', 'author': 'Zewail AH', 'year': '1992'} / The Chemical Bond: Structure and Dynamics by Zewail AH (1992)
  6. 10.1038/257028a0
  7. 10.1038/318618a0
  8. 10.1126/science.280.5360.69
  9. 10.1126/science.1077945
  10. 10.1017/S003358350000305X
  11. 10.1002/(SICI)1521-3773(20000103)39:1<257::AID-ANIE257>3.0.CO;2-3
  12. 10.1073/pnas.152333399
  13. 10.1073/pnas.0408379102
  14. 10.1073/pnas.1433099100
  15. 10.1073/pnas.0506181102
  16. 10.1073/pnas.96.11.6014
  17. 10.1002/anie.200352831
  18. 10.1021/cr020689l
  19. 10.1016/j.cplett.2004.02.011
  20. 10.1038/35085661
  21. 10.1002/1521-3773(20011203)40:23<4371::AID-ANIE4371>3.0.CO;2-I
  22. 10.1007/BF01494849
  23. 10.1103/PhysRev.30.705
  24. 10.1038/119890a0
  25. 10.1021/ja01315a103
  26. 10.1103/RevModPhys.8.231
  27. {'key': 'B25', 'volume-title': 'Stereochemical Applications of Gas-Phase Electron Diffraction', 'author': 'Hargittai I', 'year': '1988'} / Stereochemical Applications of Gas-Phase Electron Diffraction by Hargittai I (1988)
  28. {'key': 'B26', 'volume-title': 'Fifty Years of Electron Diffraction', 'author': 'Goodman P', 'year': '1981'} / Fifty Years of Electron Diffraction by Goodman P (1981)
  29. 10.1021/cr0206667
  30. 10.1103/RevModPhys.73.17
  31. 10.1103/PhysRevLett.83.336
  32. 10.1103/PhysRevLett.84.111
  33. 10.1126/science.1092489
  34. 10.1038/nature01490
  35. 10.1073/pnas.192447199
  36. 10.1063/1.471305
  37. 10.1039/dc9919100207
  38. 10.1073/pnas.88.11.5021
  39. 10.1016/0009-2614(92)85988-M
  40. 10.1038/386159a0
  41. 10.1126/science.291.5503.458
  42. 10.1073/pnas.0307302101
  43. Lobastov VA, Srinivasan R, Vigliotti F, Ruan C-Y, Feenstra JS, et al. 2004. InUltrafast Optics IV, Springer Series in Optical Sciences, ed.F Krausz, G Korn, P Corkum, IA Walmsley, 95:419. New York: Springer
  44. work was presented at the conference in Vienna (2003)
  45. 10.1073/pnas.0502607102
  46. 10.1016/S0009-2614(97)01167-6
  47. 10.1039/f29848001145
  48. 10.1007/BF00688823
  49. {'key': 'B45', 'first-page': '30', 'volume': '46', 'author': 'Mastryukov VS', 'year': '1991', 'journal-title': 'Moscow Univ. Chem. Bull.'} / Moscow Univ. Chem. Bull. by Mastryukov VS (1991)
  50. 10.1021/ja00158a071
  51. 10.1063/1.1142552
  52. 10.1063/1.1148991
  53. 10.1021/j100086a015
  54. 10.1021/jp010122t
  55. 10.1063/1.93316
  56. 10.1103/PhysRevLett.52.2364
  57. 10.1063/1.99063
  58. 10.1063/1.1146036
  59. 10.1063/1.1593831
  60. 10.1126/science.1090052
  61. 10.1021/j100062a011
  62. 10.1021/jp014144r
  63. 10.1021/jp004035x
  64. 10.1126/science.1107291
  65. 10.1002/cphc.200500330
  66. 10.1016/0009-2614(93)87193-7
  67. 10.1002/anie.200453983
  68. 10.1038/nmat767
  69. 10.1126/science.1094818
  70. 10.1039/b009301g
  71. 10.1107/S0021889899008870
  72. 10.1073/pnas.0504022102
  73. {'key': 'B68', 'volume-title': 'Organic Chemical Crystallography', 'author': 'Kitaigorodskii AI', 'year': '1961'} / Organic Chemical Crystallography by Kitaigorodskii AI (1961)
  74. 10.1021/ja048297e
  75. 10.1063/1.1611612
  76. 10.1016/S1076-5670(02)80024-6
  77. 10.1038/351694a0
  78. 10.1021/j100062a010
  79. Baskin JS, Zewail AH. 2005. Chem. Phys. Chem. 6:2261 (10.1002/cphc.200500331)
  80. 10.1002/anie.200301746
  81. {'key': 'B76', 'author': 'Thomas JM', 'year': '1997', 'journal-title': 'Principles and Practice of Heterogeneous Catalysis'} / Principles and Practice of Heterogeneous Catalysis by Thomas JM (1997)
  82. {'key': 'B77', 'first-page': '2279, 2298', 'volume': '78', 'author': 'Warren WS', 'year': '1983', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. by Warren WS (1983)
  83. 10.1039/b315513g
  84. 10.1002/anie.200501466
  85. 10.1021/cg050367l
  86. 10.1006/jsbi.1999.4172
  87. 10.1016/S0927-796X(99)00005-4
  88. 10.1021/ar970352j
  89. 10.1017/S1431927604040280
  90. 10.1146/annurev.physchem.56.092503.141310
  91. 10.1039/b201620f
  92. 10.1103/PhysRevLett.92.125505
  93. 10.1063/1.1459094
  94. {'key': 'B89', 'volume-title': 'Principles of Nonlinear Optical Spectroscopy', 'author': 'Mukamel S', 'year': '1995'} / Principles of Nonlinear Optical Spectroscopy by Mukamel S (1995)
  95. 10.1016/S0959-440X(00)00243-8
  96. 10.1146/annurev.physchem.54.011002.103907
  97. 10.1038/nature03429
  98. 10.1088/0953-4075/38/9/019
  99. 10.1126/science.1058561
  100. 10.1038/nature03833
  101. 10.1016/S0009-2614(98)00520-X
  102. 10.1073/pnas.96.2.338
  103. Williamson JC. 1998. Ultrafast gas-phase electron diffraction. PhD thesis. Calif. Inst. Technol., Pasadena, CA
  104. 10.1021/jp990867n
  105. 10.1021/jp013705b
  106. 10.1073/pnas.131192898
  107. 10.1002/1521-3773(20010417)40:8<1532::AID-ANIE1532>3.0.CO;2-E
  108. 10.1016/S0009-2614(01)01476-2
  109. 10.1016/S0009-2614(03)00803-0
  110. 10.1021/ja031927c
  111. 10.1021/jp0403689
  112. 10.1511/1999.4.308
  113. 10.1023/A:1009297222400
  114. 10.1088/2058-7058/14/4/23
  115. Lobastov VA, Zewail AH. 2004. U.S. Patent (pending)
  116. {'key': 'B111', 'first-page': '2185', 'volume': '2002', 'author': 'Hall N', 'year': '2002', 'journal-title': 'Chem. Commun.'} / Chem. Commun. by Hall N (2002)
  117. 10.1063/1.2140700
  118. 10.1002/cphc.200500532
  119. 10.1016/j.cplett.2005.11.088
Dates
Type When
Created 19 years, 4 months ago (April 7, 2006, 12:47 a.m.)
Deposited 3 years, 10 months ago (Oct. 16, 2021, 8:08 a.m.)
Indexed 2 weeks, 2 days ago (Aug. 6, 2025, 8:21 a.m.)
Issued 19 years, 3 months ago (May 1, 2006)
Published 19 years, 3 months ago (May 1, 2006)
Published Print 19 years, 3 months ago (May 1, 2006)
Funders 0

None

@article{Zewail_2006, title={4D ULTRAFAST ELECTRON DIFFRACTION, CRYSTALLOGRAPHY, AND MICROSCOPY}, volume={57}, ISSN={1545-1593}, url={http://dx.doi.org/10.1146/annurev.physchem.57.032905.104748}, DOI={10.1146/annurev.physchem.57.032905.104748}, number={1}, journal={Annual Review of Physical Chemistry}, publisher={Annual Reviews}, author={Zewail, Ahmed H.}, year={2006}, month=may, pages={65–103} }