Abstract
▪ Abstract After providing some background material to establish the interest content of this subject, we summarize the many different ways in which water can be prepared in the amorphous state, making clear that there seems to be more than one distinct amorphous state to be considered. We then give some space to structural and spectroscopic characterization of the distinct states, recognizing that whereas there seems to be unambiguously two distinct states, there may be in fact be more, the additional states mimicking the structures of the higher-density crystalline polymorphs. The low-frequency vibrational properties of the amorphous solid states are then examined in some detail because of the gathering evidence that glassy water, while difficult to form directly from the liquid like other glasses, may have some unusual and almost ideal glassy features, manifested by unusually low states of disorder. This notion is pursued in the following section dealing with thermodynamic and relaxational properties, where the uniquely low excess entropy of the vitreous state of water is confirmed by three different estimates. The fact that the most nearly ideal glass known has no properly established glass transition temperature is highlighted, using known dielectric loss data for amorphous solid water (ASW) and relevant molecular glasses. Finally, the polyamorphism of glassy water, and the kinetic aspects of transformation from one form to the other, are reviewed.
References
206
Referenced
279
10.1146/annurev.pc.34.100183.003113
- 2. Sceats MG, Rice SA. 1982. InWater: A Comprehensive Treatise, ed. F Franks, pp. 83–211. London: Plenum
10.1038/135505b0
10.1098/rspa.1935.0229
10.1126/science.11539186
10.1063/1.474468
10.1038/310393a0
10.1038/314076a0
10.1063/1.452557
10.1126/science.254.5030.406
10.1063/1.467103
10.1038/360324a0
10.1103/PhysRevE.48.4605
10.1103/PhysRevLett.73.1632
10.1063/1.1673099
10.1063/1.1669935
{'key': 'B11', 'volume-title': 'High-Pressure Research: Application to Earth and Planetary Sciences', 'author': 'Wolf GH', 'year': '1992'}
/ High-Pressure Research: Application to Earth and Planetary Sciences by Wolf GH (1992)10.1021/cr000689q
{'key': 'B12a', 'author': 'Yarger JL', 'year': '2003', 'journal-title': 'Chem. Rev.'}
/ Chem. Rev. by Yarger JL (2003)10.1088/0953-8984/15/45/R01
10.1211/002235702320266343
{'key': 'B14', 'volume-title': 'Supercooled Liquids: Advances and Novel Applications', 'author': 'Yarger JL', 'year': '1997'}
/ Supercooled Liquids: Advances and Novel Applications by Yarger JL (1997)10.1103/PhysRevLett.68.83
10.1016/S0022-3093(99)00238-0
10.1103/PhysRevB.61.5934
10.1134/1.1485264
10.1103/PhysRevLett.80.999
10.1063/1.433213
10.1016/S0022-3093(05)80795-1
10.1088/0256-307X/10/11/009
10.1103/PhysRevLett.84.4629
10.1126/science.267.5206.1924
10.1007/BF02458784
10.1063/1.1667954
10.1063/1.1696068
10.1246/bcsj.41.2591
10.1021/j150648a029
10.1038/330552a0
10.1080/13642818908211189
{'key': 'B27a', 'first-page': '7551', 'volume': '93', 'author': 'Hallbrucker A', 'year': '1989', 'journal-title': 'J. Phys. Chem.'}
/ J. Phys. Chem. by Hallbrucker A (1989)10.1021/j100014a041
10.1016/0375-9601(72)90010-2
10.1073/pnas.69.1.98
10.1007/BFb0045207
10.1063/1.437079
10.1016/0009-2614(78)85603-6
10.1063/1.438369
10.1016/S0009-2614(01)01182-4
10.1063/1.471869
10.1016/0022-3093(83)90054-6
- 34. Schmitt B, Grim SRJA, Greenberg J, Klinger J. 1992. InProc. VIIIth Symp. Phys. Chem. Ice, ed. N Maeno, T Hondoh, p.344. Sapporo, Jpn: Hokkaido Univ. Press
10.1086/178220
10.1016/S0039-6028(96)00943-0
{'key': 'B37', 'first-page': '186', 'volume': '3', 'author': 'Koverda VP', 'year': '1977', 'journal-title': 'Russ. J. Phys. Chem. Glasses'}
/ Russ. J. Phys. Chem. Glasses by Koverda VP (1977)10.1063/1.460897
10.1126/science.187.4175.428
10.1063/1.432298
10.1038/19725
10.1021/jp963278f
10.1103/PhysRevLett.80.5798
{'key': 'B42', 'first-page': 'C7', 'volume': '9', 'author': 'Dubochet J', 'year': '1984', 'journal-title': 'J. Phys.'}
/ J. Phys. by Dubochet J (1984)10.1103/PhysRevB.59.3569
10.1016/S0167-7322(02)00009-0
10.1063/1.1413963
10.1103/PhysRevLett.89.205503
10.1103/PhysRevB.65.140201
10.1038/288569a0
10.1038/298715a0
10.1111/j.1365-2818.1981.tb02483.x
10.1063/1.336179
10.1111/j.1365-2818.1985.tb02656.x
{'key': 'B48b', 'first-page': '269', 'volume': '141', 'author': 'Mayer E', 'year': '1986', 'journal-title': 'J. Microsc.'}
/ J. Microsc. by Mayer E (1986)10.1063/1.1149776
10.1016/S0022-2313(02)00268-5
10.1021/jp012868x
10.1038/330552a0
10.1080/13642818908211189
10.1021/j100287a002
10.1021/jp981779q
10.1063/1.466468
10.1063/1.470140
10.1063/1.1392365
10.1111/j.1365-2818.1993.tb03393.x
{'key': 'B53a', 'first-page': '33', 'volume': '2', 'author': 'Moor H', 'year': '1968', 'journal-title': 'Micron'}
/ Micron by Moor H (1968)10.1007/978-3-642-72815-0_8
10.1103/PhysRevLett.69.2220
10.1103/PhysRevE.52.6484
10.1038/23216
10.1103/PhysRevLett.57.3062
10.1038/nature01106
10.1063/1.481481
10.1021/jp980765h
10.1039/a908699d
10.1021/j100323a005
10.1126/science.273.5271.90
10.1063/1.477512
10.1126/science.1074178
10.1016/S0921-4526(97)00749-7
10.1103/PhysRevLett.85.4100
10.1088/0953-8984/15/3/301
{'key': 'B65', 'first-page': '653', 'volume': '69', 'author': "Stal'gorova O", 'year': '1999', 'journal-title': "Pis'ma Zh. Eksp.Teor. Fiz."}
/ Pis'ma Zh. Eksp.Teor. Fiz. by Stal'gorova O (1999)10.1134/1.568077
- 65b. Lyapin AG, Brazhkin VV, Grommitskaya EL, Mukhamadiarov VV, Stal'gorova OV, Tsiok OB. 2002. See Ref.152, pp. 449–68
10.1103/PhysRevLett.88.225503
10.1046/j.1365-2818.1996.61425.x
10.1046/j.1365-2818.2002.01051.x
10.1111/j.1365-2818.1982.tb04625.x
10.1146/annurev.bb.15.060186.001321
10.1016/S0092-8674(00)80690-X
10.1073/pnas.261560398
10.1029/EO065i052p01245
10.1103/PhysRevB.63.212201
10.1111/j.1151-2916.1965.tb14713.x
{'key': 'B75a', 'first-page': '1184', 'volume': '54', 'author': 'Ermakov AE', 'year': '1981', 'journal-title': 'Fiz. Metal. Metalloved.'}
/ Fiz. Metal. Metalloved. by Ermakov AE (1981)10.1080/10587259608046023
10.1016/0304-3991(84)90095-0
10.1209/0295-5075/18/6/008
10.1016/0304-3991(85)90070-1
10.1038/344134a0
10.1038/416409a
10.1103/PhysRevLett.88.195701
{'key': 'B80', 'author': 'Giovambattista N', 'year': '2004', 'journal-title': 'Phys. Rev. Lett.'}
/ Phys. Rev. Lett. by Giovambattista N (2004)10.1016/S0009-2614(98)01392-X
- 82. Angell CA. 2001. InWater Science for Food, Health, Agriculture and Environment, ed. Z Berk, RB Leslie, PJ Lilford, S Mizrahi, pp. 1–30. Lancaster: Technomic ISOPOW 8
- 83. Deleted in proof
10.1063/1.453149
10.1063/1.453150
10.1016/0022-3093(82)90084-9
10.1016/0022-2860(90)80141-6
10.1063/1.463254
10.1016/0375-9601(91)90370-N
10.1063/1.457285
10.1016/S0009-2614(98)00813-6
10.1016/S0009-2614(01)01182-4
{'issue': '4', 'key': 'B92', 'first-page': 'S11', 'volume': '5', 'author': 'Dubochet J', 'year': '1991', 'journal-title': 'Scan. Micros.'}
/ Scan. Micros. by Dubochet J (1991)10.1038/17717
10.1039/b008282l
10.1038/34622
10.1038/31840
10.1038/314076a0
10.1063/1.480555
10.1039/b108676f
10.1103/PhysRevLett.89.285502
- 101. Deleted in proof
10.1063/1.1576372
10.1038/420749a
10.1016/S0167-2789(97)00077-8
10.1139/p03-037
10.1021/jp0142841
10.1021/jp991399k
10.1038/nmat994
10.1021/j100184a056
10.1016/S1293-2558(00)01096-7
10.1016/S0022-3093(00)00222-2
10.1103/PhysRevB.4.2029
10.1007/978-3-642-81534-8_3
10.1016/0038-1098(86)90854-9
10.1209/0295-5075/11/1/008
10.1088/0953-8984/2/51/001
10.1063/1.1286035
-
114. Klug DD, Tse JS, Shpakov V, Tulk CA, Swainson I, et al. 2002. See Ref.152, pp. 391–402
(
10.1007/978-94-010-0595-1_29
) 10.1103/PhysRevLett.80.4209
10.1088/0953-8984/15/11/327
10.1103/PhysRevLett.66.636
10.1103/PhysRevLett.75.850
10.1016/0022-2860(91)85040-A
10.1038/330550a0
10.1021/la020218u
10.1016/S0167-7322(01)00136-2
{'key': 'B120', 'author': 'Maruyama S', 'year': '2004', 'journal-title': 'Phys. Rev. Lett'}
/ Phys. Rev. Lett by Maruyama S (2004)10.1038/299810a0
10.1126/science.1061757
{'key': 'B123', 'author': 'Yue Y-Z', 'year': '2004', 'journal-title': 'Nature.'}
/ Nature. by Yue Y-Z (2004)10.1016/0022-3093(94)90321-2
10.1016/S0009-2614(02)00434-7
10.1063/1.1514386
10.1016/0022-3093(84)90641-0
10.1007/BF00552399
{'key': 'B127', 'first-page': '10191', 'volume': '117', 'author': 'Wang L-M', 'year': '2002', 'journal-title': 'J. Chem Phys.'}
/ J. Chem Phys. by Wang L-M (2002)10.1063/1.1497158
10.1016/0022-3093(83)90054-6
10.1038/18601
10.1088/0953-8984/9/45/024
10.1063/1.1674335
10.1038/19042
10.1126/science.189.4206.880
10.1021/j100348a053
10.1038/35003143
{'key': 'B136', 'volume-title': 'Proc. Int. School of Physics, “Enrico Fermi” Course CXLVII', 'author': 'McMillan PF', 'year': '2002'}
/ Proc. Int. School of Physics, “Enrico Fermi” Course CXLVII by McMillan PF (2002)10.1126/science.254.5030.406
- 138. Deleted in proof
10.1016/S0167-2789(97)00077-8
10.1063/1.1696442
10.1016/0022-3093(92)90026-G
10.1103/PhysRevLett.58.1672
10.1103/PhysRevE.67.020201
10.1103/PhysRevLett.91.115504
10.1016/S0378-4371(00)00288-0
{'key': 'B146', 'first-page': '360', 'volume': '60', 'author': 'Ponyatovsky EG', 'year': '1994', 'journal-title': 'JETP Lett.'}
/ JETP Lett. by Ponyatovsky EG (1994)10.1557/PROC-455-411
10.1088/0953-8984/11/15/005
10.1063/1.480609
10.1038/35053024
10.1038/24540
10.1088/0953-8984/15/45/R01
10.1007/978-94-010-0595-1
Dates
Type | When |
---|---|
Created | 21 years, 3 months ago (April 29, 2004, 12:49 p.m.) |
Deposited | 3 years, 10 months ago (Oct. 16, 2021, 8:57 a.m.) |
Indexed | 2 weeks, 6 days ago (Aug. 6, 2025, 8:11 a.m.) |
Issued | 21 years, 2 months ago (June 1, 2004) |
Published | 21 years, 2 months ago (June 1, 2004) |
Published Print | 21 years, 2 months ago (June 1, 2004) |
@article{Angell_2004, title={AMORPHOUS WATER}, volume={55}, ISSN={1545-1593}, url={http://dx.doi.org/10.1146/annurev.physchem.55.091602.094156}, DOI={10.1146/annurev.physchem.55.091602.094156}, number={1}, journal={Annual Review of Physical Chemistry}, publisher={Annual Reviews}, author={Angell, C. Austen}, year={2004}, month=jun, pages={559–583} }