HYDROGEN IN METALS: Microstructural Aspects
10.1146/annurev.matsci.36.090804.094451
Crossref journal-article
Annual Reviews
Annual Review of Materials Research (22)
Abstract

▪ Abstract  Metal-hydrogen (M-H) systems are interesting from both a theoretical and a practical point of view. M-H systems are utilized for energy-storage systems, in sensor applications, and in catalysis. These systems are often exploited as models for studying basic material properties, especially when the size of these systems is small and nonbulk-like contributions become dominant. Surfaces, nanocrystals, vacancy- and dislocation-rich materials, thin films, multilayers, and clusters as systems of major interest are addressed in this review. We show that the hydrogen solubility of M-H systems is strongly affected by the morphology and microstructure of and the stress between regions of different hydrogen concentration. For small-sized systems, surface- or interface-related sites become important and change the overall solubility as well as the phase boundaries of M-H systems. In thin films deposited on stiff substrates, compressive stresses evolve during hydrogen loading because the films are effectively clamped to substrates. These stresses are in the GPa range and strongly depend on microstructure. Nanoparticles even change their crystallographic structure, which results in completely new phases.

Bibliography

Pundt, A., & Kirchheim, R. (2006). HYDROGEN IN METALS: Microstructural Aspects. Annual Review of Materials Research, 36(1), 555–608.

Authors 2
  1. A. Pundt (first)
  2. R. Kirchheim (additional)
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Dates
Type When
Created 19 years, 4 months ago (April 7, 2006, 9:55 a.m.)
Deposited 1 year, 6 months ago (Feb. 3, 2024, 12:02 p.m.)
Indexed 2 days, 22 hours ago (Aug. 29, 2025, 6:12 a.m.)
Issued 19 years, 1 month ago (Aug. 1, 2006)
Published 19 years, 1 month ago (Aug. 1, 2006)
Published Print 19 years, 1 month ago (Aug. 1, 2006)
Funders 0

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@article{Pundt_2006, title={HYDROGEN IN METALS: Microstructural Aspects}, volume={36}, ISSN={1545-4118}, url={http://dx.doi.org/10.1146/annurev.matsci.36.090804.094451}, DOI={10.1146/annurev.matsci.36.090804.094451}, number={1}, journal={Annual Review of Materials Research}, publisher={Annual Reviews}, author={Pundt, A. and Kirchheim, R.}, year={2006}, month=aug, pages={555–608} }