Anhydrous Proton-Conducting Polymers
10.1146/annurev.matsci.33.022702.155349
Crossref journal-article
Annual Reviews
Annual Review of Materials Research (22)
Abstract

▪ Abstract  Anhydrous proton-conducting polymers usually consist of a more or less inert polymer matrix that is swollen with an appropriate proton solvent (in most cases, phosphoric acid). An outline of the different materials is provided, with a focus on PBI/H3PO4 blends that are currently most suitable for fuel cell applications. Also discussed are alternative concepts for fully polymeric materials, which establish proton conductivity as an intrinsic property using amphoteric heterocycles such as imidazole as a proton solvent. The development of some of the first polymers is described, and the fundamental relations between their material properties and conductivity are discussed. Closely related to this relatively new concept are mechanistic investigations focusing on intermolecular proton transfer and diffusion of (protonated) solvent molecules, the contributions of both transport processes to conductivity, and the dependence of these ratios on composition, charge carrier density, etc. Although the development of fully polymeric proton conductors is inseparably related to mechanistic considerations, relatively little attention has been paid to these concepts in the field of conventional membranes (hydrated ionomers, H3PO4-based materials). Consequently, their general relevance is emphasized, and according investigations are summarized to provide a more comprehensive picture of proton transport processes within proton exchange membranes.

Bibliography

Schuster, M. F. H., & Meyer, W. H. (2003). Anhydrous Proton-Conducting Polymers. Annual Review of Materials Research, 33(1), 233–261.

Authors 2
  1. Martin F.H. Schuster (first)
  2. Wolfgang H. Meyer (additional)
References 94 Referenced 279
  1. {'key': 'b1', 'volume-title': 'CRC Handbook of Chemistry and Physics.', 'author': 'Lide DR', 'year': '1995'} / CRC Handbook of Chemistry and Physics. by Lide DR (1995)
  2. 10.1007/BF01039396
  3. 10.1021/j100869a018
  4. Dippel T, Kreuer KD, Lassègues JC, Rodriguez D. 1993. Solid State Ionics61(1–3):41–46 (10.1016/0167-2738(93)90332-W)
  5. 10.1021/j100793a045
  6. 10.1021/cm950192a
  7. 10.1016/S0167-2738(00)00301-5
  8. Lassègues JC. 1992. InProton Conductors: Solids, Membranes, and Gels: Materials and Devices, ed. P Colomban, pp. 311–28. New York: Cambridge Univ. Press (10.1017/CBO9780511524806.021)
  9. Lassègues JC, Grondin J, Hernandez M, Marée B. 2001. Solid State Ionics145(1–4):37–45 (10.1016/S0167-2738(01)00909-2)
  10. 10.1016/0379-6779(91)91788-C
  11. Donoso P, Gorecki W, Berthier C, Defendini F, Poinsignon C, Armand MB. 1988. Solid State Ionics28:969–74
  12. {'key': 'b12', 'first-page': '968', 'volume': '71', 'author': 'Przyluski J', 'year': '1997', 'journal-title': 'Polish J. Chem.'} / Polish J. Chem. by Przyluski J (1997)
  13. Przyluski J, Dabrowska A, Stys S, Wieczorek W. 1993. Solid State Ionics60(1–3):141–46 (10.1016/0167-2738(93)90288-E)
  14. Armand M, Gauthier M. 1989. InHigh Conductivity Solid State Ionic Conductors. Recent Trends and Applications, ed. T Takahashi, Singapore: World Scientific
  15. 10.1016/0013-4686(92)80120-B
  16. 10.1016/0167-2738(93)90357-9
  17. Bermudez VD, Sanchez JY. 1993. Solid State Ionics61(1–3):203–12 (10.1016/0167-2738(93)90355-7)
  18. Daniel MF, Desbat B, Cruege F, Trinquet O, Lassègues JC. 1988. Solid State Ionics28:637–41 (10.1016/S0167-2738(88)80116-4)
  19. 10.1016/0013-4686(92)80123-4
  20. 10.1016/0013-4686(95)00207-U
  21. 10.1002/recl.19740930612 / Rec. Trav. Chim. Pay-Bas by Bloys van Treslong CJ (1974)
  22. 10.1016/0167-2738(89)90007-6
  23. 10.1016/S0013-4686(99)00347-3
  24. Grondin J, Rodriguez D, Lassègues JC. 1995. Solid State Ionics77:70–75 (10.1016/0167-2738(94)00290-9)
  25. Rodriguez D, Jegat C, Trinquet O, Grondin J, Lassègues JC. 1993. Solid State Ionics61(1–3):193–202 (10.1016/0167-2738(93)90354-6)
  26. 10.1149/1.2044337
  27. 10.1002/app.1979.070230910
  28. {'key': 'b28', 'first-page': '2787', 'volume': '2', 'author': 'Pohl HA', 'year': '1964', 'journal-title': 'J. Polym. Sci. Polym. Chem.'} / J. Polym. Sci. Polym. Chem. by Pohl HA (1964)
  29. 10.1002/polc.5070190109
  30. Buckley A, Stuetz DE, Serad GA. 1988. InEncyclopedia of Polymer Science and Engineering, ed. HF Mark, 11:572–601. New York: Wiley & Sons. 2nd ed.
  31. {'key': 'b31', 'first-page': '83', 'volume': '1', 'author': 'Gillham JK', 'year': '1972', 'journal-title': 'Crit. Rev. Macromol. Sci.'} / Crit. Rev. Macromol. Sci. by Gillham JK (1972)
  32. {'key': 'b32', 'first-page': '93', 'volume': '4', 'author': 'Savadogo O', 'year': '2001', 'journal-title': 'J. New Mater. Electrochem. Syst.'} / J. New Mater. Electrochem. Syst. by Savadogo O (2001)
  33. {'key': 'b33', 'first-page': '47', 'volume': '1', 'author': 'Savadogo O', 'year': '1998', 'journal-title': 'J. New Mater. Electrochem. Syst.'} / J. New Mater. Electrochem. Syst. by Savadogo O (1998)
  34. 10.1016/0360-3199(96)00030-4 / Int. J. Hydrogen Energy by Barbir F
  35. Wainright JS, Wang JT, Savinell RF, Litt M, Moaddel H, Rogers C. 1995. InElectrode Materials and Processes for Energy Conversion and Storage, ed. S Srinivasan, DD Macdonald, AC Khandkar, p. 255. Pennington, NJ: Electrochem. Soc. Proc. Ser.
  36. 10.1149/1.1836626
  37. 10.1023/A:1017558523354 / J. Appl. Electrochem. by Li Q (2001)
  38. 10.1149/1.2220749 / J. Electrochem. Soc. by Zawodzinski TA (1981)
  39. 10.1149/1.2069407
  40. {'key': 'b40', 'first-page': '751', 'volume': '26', 'author': 'Wang JT', 'year': '1996', 'journal-title': 'J. Appl. Electrochem.'} / J. Appl. Electrochem. by Wang JT (1996)
  41. 10.1016/S0378-7753(99)00302-X
  42. 10.1002/apmc.1974.050400122
  43. 10.1002/pen.760321709
  44. 10.1149/1.1836621
  45. 10.1016/0032-3861(93)90618-K
  46. {'key': 'b46', 'author': 'Conley RT', 'year': '1996', 'journal-title': 'Tech. Rep.'} / Tech. Rep. by Conley RT (1996)
  47. 10.1016/0584-8539(68)80165-5
  48. 10.1007/978-94-011-6520-4
  49. Bouchet R, Siebert E. 1999. Solid State Ionics118(3–4):287–99 (10.1016/S0167-2738(98)00466-4)
  50. 10.1039/a906060j
  51. Wasmus S, Daunch A, Moaddel H, Rinaldi PL, Litt M, et al. 1995. Presented at 187th Electrochem. Soc. Meet. Reno. Abstr. 466
  52. Schechter A, Savinell RF. 2002. Solid State Ionics147(1–2):181–87 (10.1016/S0167-2738(02)00040-1)
  53. 10.1016/0013-4686(95)00313-4
  54. 10.1002/1521-3935(20010601)202:9<1478::AID-MACP1478>3.0.CO;2-8
  55. 10.1021/je60022a041
  56. 10.1149/1.1366621
  57. 10.1021/ma000165s
  58. 10.1016/S0013-4686(97)10031-7
  59. 10.1016/S0167-2738(01)00915-8
  60. 10.1016/S0013-4686(97)10032-9
  61. 10.1002/polb.10132.abs
  62. 10.1016/0013-4686(95)00186-I
  63. 10.1021/ma9600926
  64. 10.1149/1.1473335 / Electrochem. Solid-State Lett. by Li Q (2002)
  65. 10.1016/S0013-4686(98)00142-X
  66. 10.1149/1.1836961
  67. 10.1149/1.2054875
  68. Bozkurt A, Meyer WH. 2001. Solid State Ionics138(3–4):259–65 (10.1016/S0167-2738(00)00779-7)
  69. Bozkurt A, Ise M, Kreuer KD, Meyer WH, Wegner G. 1999. Solid State Ionics125(1–4):225–33 (10.1016/S0167-2738(99)00179-4)
  70. 10.1002/polb.1174
  71. {'key': 'b71', 'first-page': '27', 'volume': '3', 'author': 'Zaidi SMJ', 'year': '2000', 'journal-title': 'J. New Mater. Electrochem. Syst.'} / J. New Mater. Electrochem. Syst. by Zaidi SMJ (2000)
  72. 10.1016/S0013-4686(00)00774-X
  73. 10.1016/S0378-7753(01)00812-6
  74. Schuster MFH. 2002. Protonenleitung in imidazolhaltigen Materialien als Modellsysteme für wasserfreie Brennstoffzellenmembranen. PhD thesis. Univ. Mainz, Germany. 127 pp.(http://ArchiMeD.uni-mainz.de/pub/2002/0017/diss.pdf)
  75. Schuster M, Meyer WH, Wegner G, Herz HG, Ise M, et al. 2001. Solid State Ionics145(1–4):85–92 (10.1016/S0167-2738(01)00917-1)
  76. {'key': 'b76', 'author': 'Schuster MFH', 'year': '2003', 'journal-title': 'Chem. Mater.'} / Chem. Mater. by Schuster MFH (2003)
  77. 10.1021/cm990002m
  78. 10.1002/1099-1581(200008/12)11:8/12<548::AID-PAT4>3.0.CO;2-8
  79. 10.1246/cl.2000.44
  80. 10.1016/S0079-6700(00)00032-0
  81. Gagnon SD. 1985. InEncyclopedia of Polymer Science and Engineering, ed. HF Mark. 6:273–307. New York: Wiley & Sons. 2nd ed.
  82. Kreuer KD. 1999. InSolid State Ionics: Science & Technology, ed. BVR Chowdari, pp. 263–74. Singapore: World Scientific
  83. 10.1051/jcp/1968650253
  84. Kirsche K. 1994. InMethoden der organischen Chemie (Houben-Weyl), ed. E Schaumann, E8b:401. Stuttgart/New York: Thieme
  85. Kreuer KD. 1997. Solid State Ionics97(1–4):1–15 (10.1016/S0167-2738(97)00082-9)
  86. Kreuer KD. 1997. Solid State Ionics94(1–4):55–62 (10.1016/S0167-2738(96)00608-X)
  87. Meister U, Ise M, Kreuer KD, Meyer WH. 1999. Presented at 12th Int. Conf. on Solid State Ionics. Abstr. pp. 429–30
  88. Dippel T, Kreuer KD. 1991. Solid State Ionics46(1–2):3–9 (10.1016/0167-2738(91)90122-R)
  89. 10.1021/jp0259521
  90. {'key': 'b90', 'author': 'Herz HG', 'year': '2003', 'journal-title': 'Electrochim. Acta.'} / Electrochim. Acta. by Herz HG (2003)
  91. Münch W, Kreuer KD, Silvestri W, Maier J, Seifert G. 2001. Solid State Ionics145(1–4):437–43 (10.1016/S0167-2738(01)00941-9)
  92. {'key': 'b92', 'author': 'Noda A', 'year': '2003', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. by Noda A (2003)
  93. 10.1149/1.1393153
  94. 10.1016/S0013-4686(99)00349-7
Dates
Type When
Created 22 years, 1 month ago (July 2, 2003, 3:08 a.m.)
Deposited 3 years, 10 months ago (Oct. 13, 2021, 5:58 p.m.)
Indexed 2 months ago (June 24, 2025, 7:28 a.m.)
Issued 22 years ago (Aug. 1, 2003)
Published 22 years ago (Aug. 1, 2003)
Published Print 22 years ago (Aug. 1, 2003)
Funders 0

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@article{Schuster_2003, title={Anhydrous Proton-Conducting Polymers}, volume={33}, ISSN={1545-4118}, url={http://dx.doi.org/10.1146/annurev.matsci.33.022702.155349}, DOI={10.1146/annurev.matsci.33.022702.155349}, number={1}, journal={Annual Review of Materials Research}, publisher={Annual Reviews}, author={Schuster, Martin F.H. and Meyer, Wolfgang H.}, year={2003}, month=aug, pages={233–261} }