DOI: 10.1146/annurev-physchem-032210-103454. Melting and Freezing of Metal Clusters

10.1146/annurev-physchem-032210-103454

Crossref journal-article

Annual Reviews

Annual Review of Physical Chemistry (22)

Abstract

Recent developments allow heat capacities to be measured for size-selected clusters isolated in the gas phase. For clusters with tens to hundreds of atoms, the heat capacities determined as a function of temperature usually have a single peak attributed to a melting transition. The melting temperatures and latent heats show large size-dependent fluctuations. In some cases, the melting temperatures change by hundreds of degrees with the addition of a single atom. Theory has played a critical role in understanding the origin of the size-dependent fluctuations, and in understanding the properties of the liquid-like and solid-like states. In some cases, the heat capacities have extra features (an additional peak or a dip) that reveal a more complex behavior than simple melting. In this article we provide a description of the methods used to measure the heat capacities and provide an overview of the experimental and theoretical results obtained for sodium and aluminum clusters.

Bibliography

Aguado, A., & Jarrold, M. F. (2011). Melting and Freezing of Metal Clusters. Annual Review of Physical Chemistry, 62(1), 151â172.

Authors 2

Andrés Aguado (first)
Martin F. Jarrold (additional)

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Dates

Type	When
Created	14 years, 5 months ago (March 2, 2011, 9:41 p.m.)
Deposited	3 years, 10 months ago (Oct. 16, 2021, 12:23 p.m.)
Indexed	11 months ago (Sept. 16, 2024, 6:36 a.m.)
Issued	14 years, 3 months ago (May 5, 2011)
Published	14 years, 3 months ago (May 5, 2011)
Published Print	14 years, 3 months ago (May 5, 2011)

Funders 0

None

BibTeX

@article{Aguado_2011, title={Melting and Freezing of Metal Clusters}, volume={62}, ISSN={1545-1593}, url={http://dx.doi.org/10.1146/annurev-physchem-032210-103454}, DOI={10.1146/annurev-physchem-032210-103454}, number={1}, journal={Annual Review of Physical Chemistry}, publisher={Annual Reviews}, author={Aguado, Andrés and Jarrold, Martin F.}, year={2011}, month=may, pages={151–172} }

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