DOI: 10.1146/annurev-physchem-032210-103343. Dynamics of Nanoconfined Supercooled Liquids

Dynamics of Nanoconfined Supercooled Liquids

10.1146/annurev-physchem-032210-103343

Crossref journal-article

Annual Reviews

Annual Review of Physical Chemistry (22)

Abstract

Near their glass transition temperature Tg, supercooled liquids display dramatic changes regarding the dynamics if subject to geometrical restrictions on the scale of 2 to 200 nm. Confinement-induced shifts of Tg of 25 K have been reported, equivalent to relaxation times that differ by several orders of magnitude compared with the bulk liquid at the same temperature. Both acceleration and frustration of structural relaxations have been observed, and the effects can depend strongly on the physical and chemical properties of the interface, on soft versus hard confinement, and on the size and dimensionality of the confining topology. This review attempts to extract a unifying picture from the past 20 years of diverse observations that involve experiments, simulations, and model considerations.

Bibliography

Richert, R. (2011). Dynamics of Nanoconfined Supercooled Liquids. Annual Review of Physical Chemistry, 62(1), 65â84.

Authors 1

R. Richert (first)

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Dates

Type	When
Created	14 years, 5 months ago (March 2, 2011, 9:41 p.m.)
Deposited	3 years, 10 months ago (Oct. 16, 2021, 12:24 p.m.)
Indexed	3 weeks, 4 days ago (July 30, 2025, 8:28 p.m.)
Issued	14 years, 3 months ago (May 5, 2011)
Published	14 years, 3 months ago (May 5, 2011)
Published Print	14 years, 3 months ago (May 5, 2011)

Funders 0

None

BibTeX

@article{Richert_2011, title={Dynamics of Nanoconfined Supercooled Liquids}, volume={62}, ISSN={1545-1593}, url={http://dx.doi.org/10.1146/annurev-physchem-032210-103343}, DOI={10.1146/annurev-physchem-032210-103343}, number={1}, journal={Annual Review of Physical Chemistry}, publisher={Annual Reviews}, author={Richert, R.}, year={2011}, month=may, pages={65–84} }

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