DOI: 10.1143/jjap.6.1060. On the Phase Transformation of VO<sub>2</sub>

10.1143/jjap.6.1060

Crossref journal-article

IOP Publishing

Japanese Journal of Applied Physics (266)

Abstract

Phase transformation of VO2 was studied by the optical microscopy, the X-ray difraction and the electrical resistance. Growth of transformed regions from sites of nucleation was observed in micrographs. The critical temperature of the transition and the rate of the growth were dependent on the mechanical strain. Apparent growth velocities were 0.01∼1 mm./sec. at heating rates of 0.1∼6°C/min. The intermediate phase suggested by Umeda et al with NMR was identified with a phase observed by our experiment. The lattice constants are a=5.80 AA, b=4.52 AA. c=5.38 AA, α=91.55°, β=122.78°, γ\doteqdot90°. Both the impurities of Al, Fe, and Cr and the reduction were effective for the creation of the triclinic phase. The low temperature phase which is normally monoclinic was found to be triclinic for those crystals which have the wider temperature range of the intermediate phase. The intermediate phase was explained assuming a metastable structure stabilized by the Magneli defect.

Bibliography

Mitsuishi, T. (1967). On the Phase Transformation of VO2. Japanese Journal of Applied Physics, 6(9), 1060.

Authors 1

Tomokuni Mitsuishi (first)

References 22 Referenced 79

10.1002/zaac.19392420107 / Z. Anorg. u. Allg. Chem. (1939)
10.1007/BF01498342 / Naturwiss. (1939)
10.1021/ja01194a051 / J. Am. Chem. Soc. (1947)
10.1002/zaac.19643340304 / Z. Anorg. u. Allg. Chem. (1964)
10.3891/acta.chem.scand.10-0623 / Acta Chem. Scand. (1956)
10.3891/acta.chem.scand.15-0217 / Acta Chem. Scand. (1961)
10.1103/PhysRevLett.3.34 / Phys. Rev. Lett. (1959)
10.1103/PhysRev.117.1442 / Phys. Rev. (1960)
10.1143/JPSJ.18.318 / J. Phys. Soc. Jpn. (1963)
10.1143/JPSJ.19.131 / J. Phys. Soc. Jpn. (1964)
10.1143/JPSJ.19.517 / J. Phys. Soc. Jpn. (1964)
10.1063/1.1726128 / J. Chem. Phys. (1964)
10.1063/1.1696136 / J. Chem. Phys. (1965)
10.1143/JPSJ.21.1461 / J. Phys. Soc. Jpn. (1966)
10.1143/JPSJ.19.1748 / J. Phys. Soc. Jpn. (1964)
{'key': ''}
{'year': '1951', 'key': ''} (1951)
{'key': ''}
10.3891/acta.chem.scand.18-1267 / Acta Chem. Scand. (1964)
10.1103/PhysRev.135.A276 / Phys. Rev. (1964)
10.1002/pssb.19640070127 / Phys. Status Solidi (1964)
10.1080/14786436508224248 / Philos. Mag. (1965)

Dates

Type	When
Created	19 years, 9 months ago (Nov. 4, 2005, 2:23 a.m.)
Deposited	2 years, 9 months ago (Nov. 28, 2022, 6:36 a.m.)
Indexed	2 weeks, 2 days ago (Aug. 12, 2025, 5:51 p.m.)
Issued	57 years, 11 months ago (Sept. 1, 1967)
Published	57 years, 11 months ago (Sept. 1, 1967)
Published Print	57 years, 11 months ago (Sept. 1, 1967)

Funders 0

None

BibTeX

@article{Mitsuishi_1967, title={On the Phase Transformation of VO2}, volume={6}, ISSN={1347-4065}, url={http://dx.doi.org/10.1143/jjap.6.1060}, DOI={10.1143/jjap.6.1060}, number={9}, journal={Japanese Journal of Applied Physics}, publisher={IOP Publishing}, author={Mitsuishi, Tomokuni}, year={1967}, month=sep, pages={1060} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        12
      ]
    ],
    "date-time": "2025-08-12T21:51:12Z",
    "timestamp": 1755035472247,
    "version": "3.37.3"
  },
  "reference-count": 22,
  "publisher": "IOP Publishing",
  "issue": "9",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1967,
            9,
            1
          ]
        ],
        "date-time": "1967-09-01T00:00:00Z",
        "timestamp": -73699200000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://iopscience.iop.org/page/copyright"
    },
    {
      "start": {
        "date-parts": [
          [
            1967,
            9,
            1
          ]
        ],
        "date-time": "1967-09-01T00:00:00Z",
        "timestamp": -73699200000
      },
      "content-version": "tdm",
      "delay-in-days": 0,
      "URL": "https://iopscience.iop.org/info/page/text-and-data-mining"
    }
  ],
  "content-domain": {
    "domain": [
      "iopscience.iop.org"
    ],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1967,
        9,
        1
      ]
    ]
  },
  "abstract": "<jats:p> \n Phase transformation of VO<jats:sub>2</jats:sub> was studied by the optical microscopy, the X-ray difraction and the electrical resistance. Growth of transformed regions from sites of nucleation was observed in micrographs. The critical temperature of the transition and the rate of the growth were dependent on the mechanical strain. Apparent growth velocities were 0.01\u223c1 mm./sec. at heating rates of 0.1\u223c6\u00b0C/min. The intermediate phase suggested by Umeda <jats:italic>et al</jats:italic> with NMR was identified with a phase observed by our experiment. The lattice constants are <jats:italic>a</jats:italic>=5.80 AA, <jats:italic>b</jats:italic>=4.52 AA. <jats:italic>c</jats:italic>=5.38 AA, \u03b1=91.5<jats:sub>5</jats:sub>\u00b0, \u03b2=122.7<jats:sub>8</jats:sub>\u00b0, \u03b3\\doteqdot90\u00b0. Both the impurities of Al, Fe, and Cr and the reduction were effective for the creation of the triclinic phase. The low temperature phase which is normally monoclinic was found to be triclinic for those crystals which have the wider temperature range of the intermediate phase. The intermediate phase was explained assuming a metastable structure stabilized by the Magneli defect. \n </jats:p>",
  "DOI": "10.1143/jjap.6.1060",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        11,
        4
      ]
    ],
    "date-time": "2005-11-04T07:23:01Z",
    "timestamp": 1131088981000
  },
  "page": "1060",
  "update-policy": "https://doi.org/10.1088/crossmark-policy",
  "source": "Crossref",
  "is-referenced-by-count": 79,
  "title": "On the Phase Transformation of VO<sub>2</sub>",
  "prefix": "10.35848",
  "volume": "6",
  "author": [
    {
      "given": "Tomokuni",
      "family": "Mitsuishi",
      "sequence": "first",
      "affiliation": []
    }
  ],
  "member": "266",
  "reference": [
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "63",
      "DOI": "10.1002/zaac.19392420107",
      "volume": "242",
      "year": "1939",
      "journal-title": "Z. Anorg. u. Allg. Chem."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "787",
      "DOI": "10.1007/BF01498342",
      "volume": "27",
      "year": "1939",
      "journal-title": "Naturwiss."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "331",
      "DOI": "10.1021/ja01194a051",
      "volume": "69",
      "year": "1947",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "142",
      "DOI": "10.1002/zaac.19643340304",
      "volume": "334",
      "year": "1964",
      "journal-title": "Z. Anorg. u. Allg. Chem."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "623",
      "DOI": "10.3891/acta.chem.scand.10-0623",
      "volume": "10",
      "year": "1956",
      "journal-title": "Acta Chem. Scand."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "217",
      "DOI": "10.3891/acta.chem.scand.15-0217",
      "volume": "15",
      "year": "1961",
      "journal-title": "Acta Chem. Scand."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "34",
      "DOI": "10.1103/PhysRevLett.3.34",
      "volume": "3",
      "year": "1959",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1442",
      "DOI": "10.1103/PhysRev.117.1442",
      "volume": "117",
      "year": "1960",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "318",
      "DOI": "10.1143/JPSJ.18.318",
      "volume": "18",
      "year": "1963",
      "journal-title": "J. Phys. Soc. Jpn."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "131",
      "DOI": "10.1143/JPSJ.19.131",
      "volume": "19",
      "year": "1964",
      "journal-title": "J. Phys. Soc. Jpn."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "517",
      "DOI": "10.1143/JPSJ.19.517",
      "volume": "19",
      "year": "1964",
      "journal-title": "J. Phys. Soc. Jpn."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1591",
      "DOI": "10.1063/1.1726128",
      "volume": "41",
      "year": "1964",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1458",
      "DOI": "10.1063/1.1696136",
      "volume": "42",
      "year": "1965",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1461",
      "DOI": "10.1143/JPSJ.21.1461",
      "volume": "21",
      "year": "1966",
      "journal-title": "J. Phys. Soc. Jpn."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1748",
      "DOI": "10.1143/JPSJ.19.1748",
      "volume": "19",
      "year": "1964",
      "journal-title": "J. Phys. Soc. Jpn."
    },
    {
      "key": ""
    },
    {
      "year": "1951",
      "key": ""
    },
    {
      "key": ""
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1267",
      "DOI": "10.3891/acta.chem.scand.18-1267",
      "volume": "18",
      "year": "1964",
      "journal-title": "Acta Chem. Scand."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "A276",
      "DOI": "10.1103/PhysRev.135.A276",
      "volume": "135",
      "year": "1964",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "307",
      "DOI": "10.1002/pssb.19640070127",
      "volume": "7",
      "year": "1964",
      "journal-title": "Phys. Status Solidi"
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "627",
      "DOI": "10.1080/14786436508224248",
      "volume": "11",
      "year": "1965",
      "journal-title": "Philos. Mag."
    }
  ],
  "container-title": "Japanese Journal of Applied Physics",
  "original-title": [],
  "link": [
    {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.6.1060",
      "content-type": "text/html",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.6.1060/pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.6.1060/pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.6.1060/pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2022,
        11,
        28
      ]
    ],
    "date-time": "2022-11-28T11:36:49Z",
    "timestamp": 1669635409000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.6.1060"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1967,
        9,
        1
      ]
    ]
  },
  "references-count": 22,
  "journal-issue": {
    "issue": "9",
    "published-print": {
      "date-parts": [
        [
          1967,
          9,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1143/JJAP.6.1060",
  "relation": {},
  "ISSN": [
    "0021-4922",
    "1347-4065"
  ],
  "subject": [],
  "container-title-short": "Jpn. J. Appl. Phys.",
  "published": {
    "date-parts": [
      [
        1967,
        9,
        1
      ]
    ]
  },
  "assertion": [
    {
      "value": "On the Phase Transformation of VO2",
      "name": "article_title",
      "label": "Article Title"
    },
    {
      "value": "Japanese Journal of Applied Physics",
      "name": "journal_title",
      "label": "Journal Title"
    },
    {
      "value": "paper",
      "name": "article_type",
      "label": "Article Type"
    },
    {
      "value": "Copyright (c) 1967 The Japan Society of Applied Physics",
      "name": "copyright_information",
      "label": "Copyright Information"
    },
    {
      "value": "1967-03-03",
      "name": "date_received",
      "label": "Date Received",
      "group": {
        "name": "publication_dates",
        "label": "Publication dates"
      }
    },
    {
      "name": "date_accepted",
      "label": "Date Accepted",
      "group": {
        "name": "publication_dates",
        "label": "Publication dates"
      }
    },
    {
      "name": "date_epub",
      "label": "Online publication date",
      "group": {
        "name": "publication_dates",
        "label": "Publication dates"
      }
    }
  ]
}