DOI: 10.1143/jjap.43.5378. Influence of the Niobium or Fluorine Dopant Concentration on the Properties of Mn-Doped Lead Zirconate Titanate Ceramics

Influence of the Niobium or Fluorine Dopant Concentration on the Properties of Mn-Doped Lead Zirconate Titanate Ceramics

10.1143/jjap.43.5378

Crossref journal-article

IOP Publishing

Japanese Journal of Applied Physics (266)

Abstract

In this paper, we report on the effect of donor addition (Nb5+ or F-) on the electrical and piezoelectric properties and crystallographic characteristics of Mn-doped lead zirconate titanate (PZT) ceramics. Samples were prepared chemically by coprecipitation of oxalates and hydroxides. The niobium ion was incorporated in the B site whereas the fluorine ion was introduced in the anionic site. Structural analysis (XRD) and measurement of electrical properties were carried out. Electron spin resonance was used to determined the valency states of manganese in PZT ceramics. From the experimental results, the F–O substitution decreases the amount of oxygen vacancies in the Mn-doped PZT, and the valency states remain unchanged. However, a small number of oxygen vacancies may exist in PZT doped with 1 at.% manganese and 2 at.% fluorine. In the (Mn,Nb) co-doping case, the valency states vary from 4+ to 2+ and the number of oxygen vacancies is lower or even almost equal to zero. Thus the electroneutrality is achieved by lead vacancies.

Bibliography

Boucher, E., Guiffard, B., Lebrun, L., & Guyomar, D. (2004). Influence of the Niobium or Fluorine Dopant Concentration on the Properties of Mn-Doped Lead Zirconate Titanate Ceramics. Japanese Journal of Applied Physics, 43(8R), 5378.

Authors 4

Eric Boucher (first)
Benoit Guiffard (additional)
Laurent Lebrun (additional)
Daniel Guyomar (additional)

References 17 Referenced 14

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10.1088/0034-4885/61/9/002 / Rep. Prog. Phys. (1998)
10.1007/BF00550337 / J. Mater. Sci.: Mater. Electron. (1995)
10.1080/00150190208260631 / Ferroelectrics (2002)
10.1063/1.1499526 / J. Appl. Phys. (2002)
10.1016/S0025-5408(98)00189-5 / Mater. Res. Bull. (1998)
{'key': ''}
10.1002/pssa.2211220132 / Phys. Status Solidi A (1990)
10.1143/JJAP.31.3045 / Jpn. J. Appl. Phys. (1992)
10.1023/A:1004717702149 / J. Mater. Sci. (2000)
10.1143/JJAP.31.3058 / Jpn. J. Appl. Phys. (1992)
10.1002/adma.19900021004 / Adv. Mater. (1990)
10.1016/0038-1098(69)90688-7 / Solid State Commun. (1969)
10.1146/annurev.ms.14.080184.000331 / Ann. Rev. Mater. (1984)
10.1111/j.1151-2916.1991.tb07812.x / J. Am. Ceram. Soc. (1991)
10.1080/00150199408244731 / Ferroelectrics (1994)
10.1016/0022-3697(96)00020-0 / J. Phys. Chem. Solids (1996)

Dates

Type	When
Created	20 years, 6 months ago (Feb. 10, 2005, 7:05 a.m.)
Deposited	2 years, 8 months ago (Dec. 19, 2022, 12:15 p.m.)
Indexed	6 months ago (Feb. 21, 2025, 5:34 a.m.)
Issued	21 years ago (Aug. 1, 2004)
Published	21 years ago (Aug. 1, 2004)
Published Online	21 years ago (Aug. 10, 2004)
Published Print	21 years ago (Aug. 1, 2004)

Funders 0

None

BibTeX

@article{Boucher_2004, title={Influence of the Niobium or Fluorine Dopant Concentration on the Properties of Mn-Doped Lead Zirconate Titanate Ceramics}, volume={43}, ISSN={1347-4065}, url={http://dx.doi.org/10.1143/jjap.43.5378}, DOI={10.1143/jjap.43.5378}, number={8R}, journal={Japanese Journal of Applied Physics}, publisher={IOP Publishing}, author={Boucher, Eric and Guiffard, Benoit and Lebrun, Laurent and Guyomar, Daniel}, year={2004}, month=aug, pages={5378} }

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