Abstract
Band structure match-ups are given theoretically from X-ray photoemission spectroscopy (XPS) for the electrode interfaces between platinum electrodes and the ferroelectric thin-film materials commonly used for random access memories (DRAMs and nonvolatile FRAMs): strontium bismuth tantalate (SBT), barium strontium titanate (BST), and lead zirconate titanate (PZT). The results all agree with experimentally measured Schottky barrier heights. The electronegativity constant or S-factor (derivative of Schottky barrier height with respect to electron affinity) is found to be approximately 0.7 for these materials, not the purely ionic value of 1.0. The reduction of a factor of a million in the effective Richardson coefficient is explained. And the paradox of avalanche breakdown but decreasing breakdown fields with increasing temperature is reconciled.
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Dates
Type | When |
---|---|
Created | 22 years, 10 months ago (Oct. 1, 2002, 6:51 p.m.) |
Deposited | 2 years, 8 months ago (Dec. 14, 2022, 12:09 p.m.) |
Indexed | 32 minutes ago (Aug. 21, 2025, 4:51 a.m.) |
Issued | 26 years, 4 months ago (April 1, 1999) |
Published | 26 years, 4 months ago (April 1, 1999) |
Published Print | 26 years, 4 months ago (April 1, 1999) |
@article{Scott_1999, title={Device Physics of Ferroelectric Thin-Film Memories}, volume={38}, ISSN={1347-4065}, url={http://dx.doi.org/10.1143/jjap.38.2272}, DOI={10.1143/jjap.38.2272}, number={4S}, journal={Japanese Journal of Applied Physics}, publisher={IOP Publishing}, author={Scott, J. F.}, year={1999}, month=apr, pages={2272} }