DOI: 10.1143/jjap.35.5196. Size Effect on the Phase Transition in PbTiO<sub>3</sub> Fine Particles

Size Effect on the Phase Transition in PbTiO3 Fine Particles

10.1143/jjap.35.5196

Crossref journal-article

IOP Publishing

Japanese Journal of Applied Physics (266)

Abstract

The finite size effect on the phase transition in PbTiO3 fine particles is described. Very small crystals with an average diameter of 14.2 nm were obtained by lowering the calcination temperature to 400° C. Raman scattering measurements of such fine particles were carried out to study the dependence of the phase transition temperature on the particle size. The X-ray diffraction pattern was also measured to study the tetragonality, c/a ratio. The results strongly suggest the presence of a critical size below which the ferroelectric state becomes unstable. The critical size determined by Raman measurements was 10.7 nm.

Bibliography

Ishikawa, K., Nomura, T., Nagaya Okada, N. O., & Kazumasa Takada, K. T. (1996). Size Effect on the Phase Transition in PbTiO3 Fine Particles. Japanese Journal of Applied Physics, 35(9S), 5196.

Authors 4

Kenji Ishikawa (first)
Takashi Nomura (additional)
Nagaya Okada Nagaya Okada (additional)
Kazumasa Takada Kazumasa Takada (additional)

References 13 Referenced 71

10.1143/JJAP.32.4175 / Jpn. J. Appl. Phys. (1993)
10.1088/0022-3719/4/8/016 / J. Phys. C (1971)
10.1143/JJAP.32.4179 / Jpn. J. Appl. Phys. (1993)
10.1080/00150197608241393 / Ferroelectrics (1976)
10.1143/JJAP.32.4150 / Jpn. J. Appl. Phys. (1993)
10.1103/PhysRevB.37.5852 / Phys. Rev. B (1988)
10.1143/JJAP.33.5412 / Jpn. J. Appl. Phys. (1994)
10.1143/JJAP.33.3495 / Jpn. J. Appl. Phys. (1994)
{'key': '', 'first-page': '2619', 'volume': '5', 'year': '1993', 'journal-title': 'J. Phys.: Condens. Matter'} / J. Phys.: Condens. Matter (1993)
10.1063/1.105631 / Appl. Phys. Lett. (1991)
{'key': '', 'first-page': '521', 'volume': '26', 'year': '1953', 'journal-title': 'Helv. Phys. Acta'} / Helv. Phys. Acta (1953)
10.1111/j.1151-2916.1989.tb07706.x / J. Am. Ceram. Soc. (1989)
10.1103/PhysRev.50.698 / Phys. Rev. (1994)

Dates

Type	When
Created	22 years, 10 months ago (Oct. 1, 2002, 5:03 p.m.)
Deposited	2 years, 8 months ago (Dec. 7, 2022, 1:19 p.m.)
Indexed	1 month, 4 weeks ago (June 26, 2025, 6:45 a.m.)
Issued	28 years, 11 months ago (Sept. 1, 1996)
Published	28 years, 11 months ago (Sept. 1, 1996)
Published Print	28 years, 11 months ago (Sept. 1, 1996)

Funders 0

None

BibTeX

@article{Ishikawa_1996, title={Size Effect on the Phase Transition in PbTiO3 Fine Particles}, volume={35}, ISSN={1347-4065}, url={http://dx.doi.org/10.1143/jjap.35.5196}, DOI={10.1143/jjap.35.5196}, number={9S}, journal={Japanese Journal of Applied Physics}, publisher={IOP Publishing}, author={Ishikawa, Kenji and Nomura, Takashi and Nagaya Okada, Nagaya Okada and Kazumasa Takada, Kazumasa Takada}, year={1996}, month=sep, pages={5196} }

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