Abstract
Protrusions of (Ba, Sr)TiO3 (BST) crystallites were found to appear on BST film surfaces prepared by liquid source chemical vapor deposition (CVD) at a substrate temperature T s=420° C and a reactor pressure P=1.5 Torr. Such protrusions were successfully suppressed by two-step deposition, where BST films consisted of a buffer layer and a main layer; the buffer layer was a CVD-BST film about 60 Å thick annealed in N2 ambient. By this two-step deposition on Pt electrodes, the BST film properties of equivalent SiO2 thickness t eq=0.56 nm, leakage current J L=1.2×10-8 A/cm2 at +1.1 V and dielectric loss tan δ=0.011 were achieved at a total film thickness of 230 Å, along with a coverage of 80% at a trench of aspect ratio 0.65 and sufficiently low absorption current.
References
14
Referenced
57
{'key': ''}
{'key': '', 'first-page': '67', 'volume': '43', 'year': '1994', 'journal-title': 'Ceram. Trans.'}
/ Ceram. Trans. (1994){'year': '1994', 'key': ''}
(1994)10.1143/JJAP.33.5129
/ Jpn. J. Appl. Phys. (1994){'key': ''}
{'year': '1992', 'key': ''}
(1992)10.1149/1.2043883
/ J. Electrochem. Soc. (1995){'key': ''}
{'key': ''}
10.1143/JJAP.33.5167
/ Jpn. J. Appl. Phys. (1994)10.1143/JJAP.30.2193
/ Jpn. J. Appl. Phys. (1991){'key': ''}
10.1143/JJAP.30.431
/ Jpn. J. Appl. Phys. (1991)10.1143/JJAP.28.212
/ Jpn. J. Appl. Phys. (1989)
@article{Kawahara_1995, title={Surface Morphologies and Electrical Properties of (Ba, Sr)TiO3 Films Prepared by Two-Step Deposition of Liquid Source Chemical Vapor Deposition}, volume={34}, ISSN={1347-4065}, url={http://dx.doi.org/10.1143/jjap.34.5077}, DOI={10.1143/jjap.34.5077}, number={9S}, journal={Japanese Journal of Applied Physics}, publisher={IOP Publishing}, author={Kawahara, Takaaki and Yamamuka, Mikio and Yuuki, Akimasa and Kouichi Ono, Kouichi Ono}, year={1995}, month=sep, pages={5077} }