DOI: 10.1143/jjap.33.l1338. Removal of Adsorbed Organic Molecules with Scanning Tunneling Microscope: Formate Anions on TiO<sub>2</sub>(110) Surface

Removal of Adsorbed Organic Molecules with Scanning Tunneling Microscope: Formate Anions on TiO2(110) Surface

10.1143/jjap.33.l1338

Crossref journal-article

IOP Publishing

Japanese Journal of Applied Physics (266)

Abstract

A scanning tunneling microscope (STM) operated under ultrahigh vacuum enabled us to eliminate individual formate anions ( DCOO-) adsorbed on a TiO2(110) surface. When bias voltages of +3.7 V or more were applied on the sample, the formate anions were removed under the STM tip. In contrast, much higher voltages, +5.0 V or more, were required to damage the underlying TiO2 surface. Thus we could strip off the formate anions in a desired area without damage to the substrate, to create patchworks of uncovered substrate in the monolayer of adsorbed formate anions. The threshold bias voltage for the elimination showed a small dependence on tunneling current, suggesting that the removal process is through field evaporation rather than direct excitation or thermal activation by tunneling electrons.

Bibliography

Hiroshi Onishi, H. O., & Yasuhiro Iwasawa, Y. I. (1994). Removal of Adsorbed Organic Molecules with Scanning Tunneling Microscope: Formate Anions on TiO2(110) Surface. Japanese Journal of Applied Physics, 33(9B), L1338.

Authors 2

Hiroshi Onishi Hiroshi Onishi (first)
Yasuhiro Iwasawa Yasuhiro Iwasawa (additional)

References 24 Referenced 28

10.1038/344524a0 / Nature (1990)
10.1038/352600a0 / Nature (1991)
10.1103/PhysRevLett.65.2418 / Phys. Rev. Lett. (1990)
10.1126/science.253.5016.173 / Science (1991)
10.1143/JJAP.31.4501 / Jpn. J. Appl. Phys. (1992)
10.1016/0039-6028(93)91126-A / Surf. Sci. (1993)
10.1103/PhysRevLett.70.2040 / Phys. Rev. Lett. (1993)
10.1126/science.259.5102.1724 / Science (1993)
10.1143/JJAP.33.L190 / Jpn. J. Appl. Phys. (1994)
10.1016/0169-4332(92)90489-K / Appl. Surf. Sci. (1992)
10.1126/science.255.5049.1232 / Science (1992)
10.1073/pnas.84.4.969 / Proc. Natl. Acad. Sci. USA (1987)
10.1021/la00040a015 / Langmuir (1992)
{'year': '1994', 'key': ''} (1994)
10.1006/jcat.1994.1094 / J. Catal. (1994)
10.1021/ja00075a112 / J. Am. Chem. Soc. (1993)
10.1016/0009-2614(94)00712-8 / Chem. Phys. Lett. (1994)
{'journal-title': 'Langmuir.', 'key': ''} / Langmuir.
10.1016/S0360-0564(08)60338-7 / Adv. Catal. (1963)
10.1016/0039-6028(94)91146-0 / Surf. Sci. Lett. (1994)
10.1016/0039-6028(88)90321-4 / Surf. Sci. (1988)
10.1103/PhysRev.91.793 / Phys. Rev. (1953)
10.1039/f19898502597 / J. Chem. Soc., Faraday Trans. 1, (1989)
{'year': '1983', 'key': ''} (1983)

Dates

Type	When
Created	22 years, 10 months ago (Oct. 1, 2002, 4:18 p.m.)
Deposited	2 years, 8 months ago (Dec. 7, 2022, 12:30 p.m.)
Indexed	6 months ago (Feb. 21, 2025, 5:32 a.m.)
Issued	30 years, 11 months ago (Sept. 1, 1994)
Published	30 years, 11 months ago (Sept. 1, 1994)
Published Print	30 years, 11 months ago (Sept. 1, 1994)

Funders 0

None

BibTeX

@article{Hiroshi_Onishi_1994, title={Removal of Adsorbed Organic Molecules with Scanning Tunneling Microscope: Formate Anions on TiO2(110) Surface}, volume={33}, ISSN={1347-4065}, url={http://dx.doi.org/10.1143/jjap.33.l1338}, DOI={10.1143/jjap.33.l1338}, number={9B}, journal={Japanese Journal of Applied Physics}, publisher={IOP Publishing}, author={Hiroshi Onishi, Hiroshi Onishi and Yasuhiro Iwasawa, Yasuhiro Iwasawa}, year={1994}, month=sep, pages={L1338} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        2,
        21
      ]
    ],
    "date-time": "2025-02-21T10:32:03Z",
    "timestamp": 1740133923104,
    "version": "3.37.3"
  },
  "reference-count": 24,
  "publisher": "IOP Publishing",
  "issue": "9B",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1994,
            9,
            1
          ]
        ],
        "date-time": "1994-09-01T00:00:00Z",
        "timestamp": 778377600000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://iopscience.iop.org/page/copyright"
    },
    {
      "start": {
        "date-parts": [
          [
            1994,
            9,
            1
          ]
        ],
        "date-time": "1994-09-01T00:00:00Z",
        "timestamp": 778377600000
      },
      "content-version": "tdm",
      "delay-in-days": 0,
      "URL": "https://iopscience.iop.org/info/page/text-and-data-mining"
    }
  ],
  "content-domain": {
    "domain": [
      "iopscience.iop.org"
    ],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1994,
        9,
        1
      ]
    ]
  },
  "abstract": "<jats:p> \n   A scanning tunneling microscope (STM) operated under ultrahigh vacuum enabled us to eliminate individual formate anions ( DCOO<jats:sup>-</jats:sup>) adsorbed on a  TiO<jats:sub>2</jats:sub>(110) surface. When bias voltages of  +3.7 V or more were applied on the sample, the formate anions were removed under the STM tip. In contrast, much higher voltages,  +5.0 V or more, were required to damage the underlying  TiO<jats:sub>2</jats:sub> surface. Thus we could strip off the formate anions in a desired area without damage to the substrate, to create patchworks of uncovered substrate in the monolayer of adsorbed formate anions. The threshold bias voltage for the elimination showed a small dependence on tunneling current, suggesting that the removal process is through field evaporation rather than direct excitation or thermal activation by tunneling electrons. \n   </jats:p>",
  "DOI": "10.1143/jjap.33.l1338",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        10,
        1
      ]
    ],
    "date-time": "2002-10-01T20:18:21Z",
    "timestamp": 1033503501000
  },
  "page": "L1338",
  "update-policy": "https://doi.org/10.1088/crossmark-policy",
  "source": "Crossref",
  "is-referenced-by-count": 28,
  "title": "Removal of Adsorbed Organic Molecules with Scanning Tunneling Microscope: Formate Anions on TiO<sub>2</sub>(110) Surface",
  "prefix": "10.35848",
  "volume": "33",
  "author": [
    {
      "given": "Hiroshi Onishi",
      "family": "Hiroshi Onishi",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Yasuhiro Iwasawa",
      "family": "Yasuhiro Iwasawa",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "266",
  "reference": [
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "524",
      "DOI": "10.1038/344524a0",
      "volume": "344",
      "year": "1990",
      "journal-title": "Nature"
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "600",
      "DOI": "10.1038/352600a0",
      "volume": "352",
      "year": "1991",
      "journal-title": "Nature"
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "2418",
      "DOI": "10.1103/PhysRevLett.65.2418",
      "volume": "65",
      "year": "1990",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "173",
      "DOI": "10.1126/science.253.5016.173",
      "volume": "253",
      "year": "1991",
      "journal-title": "Science"
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "4501",
      "DOI": "10.1143/JJAP.31.4501",
      "volume": "31",
      "year": "1992",
      "journal-title": "Jpn. J. Appl. Phys."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1056",
      "DOI": "10.1016/0039-6028(93)91126-A",
      "volume": "287/288",
      "year": "1993",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "2040",
      "DOI": "10.1103/PhysRevLett.70.2040",
      "volume": "70",
      "year": "1993",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1724",
      "DOI": "10.1126/science.259.5102.1724",
      "volume": "259",
      "year": "1993",
      "journal-title": "Science"
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "L190",
      "DOI": "10.1143/JJAP.33.L190",
      "volume": "33",
      "year": "1994",
      "journal-title": "Jpn. J. Appl. Phys."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "643",
      "DOI": "10.1016/0169-4332(92)90489-K",
      "volume": "60/61",
      "year": "1992",
      "journal-title": "Appl. Surf. Sci."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1232",
      "DOI": "10.1126/science.255.5049.1232",
      "volume": "255",
      "year": "1992",
      "journal-title": "Science"
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "969",
      "DOI": "10.1073/pnas.84.4.969",
      "volume": "84",
      "year": "1987",
      "journal-title": "Proc. Natl. Acad. Sci. USA"
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "1096",
      "DOI": "10.1021/la00040a015",
      "volume": "8",
      "year": "1992",
      "journal-title": "Langmuir"
    },
    {
      "year": "1994",
      "key": ""
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "557",
      "DOI": "10.1006/jcat.1994.1094",
      "volume": "146",
      "year": "1994",
      "journal-title": "J. Catal."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "10460",
      "DOI": "10.1021/ja00075a112",
      "volume": "115",
      "year": "1993",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "111",
      "DOI": "10.1016/0009-2614(94)00712-8",
      "volume": "226",
      "year": "1994",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "journal-title": "Langmuir.",
      "key": ""
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "35",
      "DOI": "10.1016/S0360-0564(08)60338-7",
      "volume": "14",
      "year": "1963",
      "journal-title": "Adv. Catal."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "L783",
      "DOI": "10.1016/0039-6028(94)91146-0",
      "volume": "313",
      "year": "1994",
      "journal-title": "Surf. Sci. Lett."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "33",
      "DOI": "10.1016/0039-6028(88)90321-4",
      "volume": "193",
      "year": "1988",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "793",
      "DOI": "10.1103/PhysRev.91.793",
      "volume": "91",
      "year": "1953",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "",
      "doi-asserted-by": "publisher",
      "first-page": "2597",
      "DOI": "10.1039/f19898502597",
      "volume": "85",
      "year": "1989",
      "journal-title": "J. Chem. Soc., Faraday Trans. 1,"
    },
    {
      "year": "1983",
      "key": ""
    }
  ],
  "container-title": "Japanese Journal of Applied Physics",
  "original-title": [],
  "link": [
    {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.33.L1338",
      "content-type": "text/html",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.33.L1338/pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.33.L1338/pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.33.L1338/pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2022,
        12,
        7
      ]
    ],
    "date-time": "2022-12-07T17:30:40Z",
    "timestamp": 1670434240000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://iopscience.iop.org/article/10.1143/JJAP.33.L1338"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1994,
        9,
        1
      ]
    ]
  },
  "references-count": 24,
  "journal-issue": {
    "issue": "9B",
    "published-print": {
      "date-parts": [
        [
          1994,
          9,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1143/JJAP.33.L1338",
  "relation": {},
  "ISSN": [
    "0021-4922",
    "1347-4065"
  ],
  "subject": [],
  "container-title-short": "Jpn. J. Appl. Phys.",
  "published": {
    "date-parts": [
      [
        1994,
        9,
        1
      ]
    ]
  },
  "assertion": [
    {
      "value": "Removal of Adsorbed Organic Molecules with Scanning Tunneling Microscope: Formate Anions on TiO2(110) Surface",
      "name": "article_title",
      "label": "Article Title"
    },
    {
      "value": "Japanese Journal of Applied Physics",
      "name": "journal_title",
      "label": "Journal Title"
    },
    {
      "value": "paper",
      "name": "article_type",
      "label": "Article Type"
    },
    {
      "value": "Copyright (c) 1994 The Japan Society of Applied Physics",
      "name": "copyright_information",
      "label": "Copyright Information"
    },
    {
      "value": "1994-07-04",
      "name": "date_received",
      "label": "Date Received",
      "group": {
        "name": "publication_dates",
        "label": "Publication dates"
      }
    },
    {
      "value": "1994-08-20",
      "name": "date_accepted",
      "label": "Date Accepted",
      "group": {
        "name": "publication_dates",
        "label": "Publication dates"
      }
    },
    {
      "name": "date_epub",
      "label": "Online publication date",
      "group": {
        "name": "publication_dates",
        "label": "Publication dates"
      }
    }
  ]
}