DOI: 10.1142/s0218625x99000883. CASE STUDIES IN SURFACE GEOMETRY: ADSORBATE AND COADSORBATE STRUCTURES ON Ru(001), AND SOME IMPLICATIONS

CASE STUDIES IN SURFACE GEOMETRY: ADSORBATE AND COADSORBATE STRUCTURES ON Ru(001), AND SOME IMPLICATIONS

10.1142/s0218625x99000883

Crossref journal-article

World Scientific Pub Co Pte Lt

Surface Review and Letters (219)

Abstract

Using a CCD LEED system for the collection of IV data with minimal beam damage, and full dynamical as well as Tensor LEED calculations, the geometries of about 20 adsorbate and coadsorbate structures on Ru(001) have been determined over the past decade. With work by other groups, more than 30 accurate adsorbate structures are now available for this surface. The advantage of this concentrated effort directed at a single surface with equivalent methods is that comparisons of trends can be made on this basis, and that the correlation of different structures lends additional credibility to the separately determined structural parameters. This then justifies comparisons with results of first principles theoretical calculations and other conclusions. Here a short overview is given of the methods used and of the structures derived, and some methodological questions (reliability of "LEED only," and the importance of supporting evidence; reproducibility vs. accuracy; temperature effects and the influence of soft vibrations) are discussed. This data set is then used to briefly discuss some examples, including: • Influences of site selection and environment on the adsorbate structure; • Lateral interactions in coadsorbate structures; • Possible chemical contributions in rare gas adsorption; • Global and local relaxations of the Ru surface atoms and their interpretation. Comparison to theoretical results is made where possible.

Bibliography

MENZEL, D. (1999). CASE STUDIES IN SURFACE GEOMETRY: ADSORBATE AND COADSORBATE STRUCTURES ON Ru(001), AND SOME IMPLICATIONS. Surface Review and Letters, 06(05), 835â846.

Authors 1

DIETRICH MENZEL (first)

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Dates

Type	When
Created	23 years ago (July 27, 2002, 6:59 a.m.)
Deposited	6 years ago (Aug. 6, 2019, 9:55 p.m.)
Indexed	1 year, 6 months ago (Feb. 6, 2024, 12:24 a.m.)
Issued	25 years, 10 months ago (Oct. 1, 1999)
Published	25 years, 10 months ago (Oct. 1, 1999)
Published Online	13 years, 7 months ago (Jan. 25, 2012)
Published Print	25 years, 10 months ago (Oct. 1, 1999)

Funders 0

None

BibTeX

@article{MENZEL_1999, title={CASE STUDIES IN SURFACE GEOMETRY: ADSORBATE AND COADSORBATE STRUCTURES ON Ru(001), AND SOME IMPLICATIONS}, volume={06}, ISSN={1793-6667}, url={http://dx.doi.org/10.1142/s0218625x99000883}, DOI={10.1142/s0218625x99000883}, number={05}, journal={Surface Review and Letters}, publisher={World Scientific Pub Co Pte Lt}, author={MENZEL, DIETRICH}, year={1999}, month=oct, pages={835–846} }

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