DOI: 10.1139/v73-541. A Low Temperature Infrared Study of Hydrogen Bonding in <i>N</i>-Alkylacetamides

A Low Temperature Infrared Study of Hydrogen Bonding in N-Alkylacetamides

10.1139/v73-541

Crossref journal-article

Canadian Science Publishing

Canadian Journal of Chemistry (155)

Abstract

The infrared spectra of N-methylacetamide and two other secondary amides were measured in solution at temperatures ranging from 22 to −190 °C in both the fundamental and the overtone regions. At least two hydrogen bonded species are found as association increases with decreasing temperature. The effect of hydrogen bond formation on the anharmonicity of the NH stretching vibration and on the NH stretching – NH bending coupling constant is examined.

Bibliography

Bernard-Houplain, M.-C., & Sandorfy, C. (1973). A Low Temperature Infrared Study of Hydrogen Bonding in N-Alkylacetamides. Canadian Journal of Chemistry, 51(21), 3640â3646.

Authors 2

Marie-Claude Bernard-Houplain (first)
C. Sandorfy (additional)

References 0 Referenced 39

None

Dates

Type	When
Created	19 years, 4 months ago (May 4, 2006, 4:25 p.m.)
Deposited	2 months ago (July 2, 2025, 2:44 p.m.)
Indexed	2 months ago (July 3, 2025, 12:17 a.m.)
Issued	51 years, 10 months ago (Nov. 1, 1973)
Published	51 years, 10 months ago (Nov. 1, 1973)
Published Print	51 years, 10 months ago (Nov. 1, 1973)

Funders 0

None

BibTeX

@article{Bernard_Houplain_1973, title={A Low Temperature Infrared Study of Hydrogen Bonding in N-Alkylacetamides}, volume={51}, ISSN={1480-3291}, url={http://dx.doi.org/10.1139/v73-541}, DOI={10.1139/v73-541}, number={21}, journal={Canadian Journal of Chemistry}, publisher={Canadian Science Publishing}, author={Bernard-Houplain, Marie-Claude and Sandorfy, C.}, year={1973}, month=nov, pages={3640–3646} }

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