DOI: 10.1139/v73-209. The Pyrolysis of Trimethylthallium and Evaluation of D[(CH3)2Tl

The Pyrolysis of Trimethylthallium and Evaluation of D[(CH3)2Tl—CH3]

10.1139/v73-209

Crossref journal-article

Canadian Science Publishing

Canadian Journal of Chemistry (155)

Abstract

The pyrolysis of trimethylthallium has been studied in a mercury free toluene carrier flow system (452–536 °K, total pressure 6.7–39.3 mm, contact time 0.9–5.1 s, 5.4–90.2% decomposition). In a vessel cleaned with boiling concentrated HNO3 and coated by decomposing 0.1 g Tl(CH3)3 no heterogeneous reaction could be detected. The extent of reaction measured by product analysis (CH4, C2H6, C6H5C2H5) assuming three CH3 per Tl(CH3)3 undergoing reaction 1

Bibliography

Price, S. J., Richard, J. P., Rumfeldt, R. C., & Jacko, M. G. (1973). The Pyrolysis of Trimethylthallium and Evaluation of D[(CH3)2TlâCH3]. Canadian Journal of Chemistry, 51(9), 1397â1401.

Authors 4

S. J. Price (first)
J. P. Richard (additional)
R. C. Rumfeldt (additional)
M. G. Jacko (additional)

References 0 Referenced 13

None

Dates

Type	When
Created	19 years, 3 months ago (May 4, 2006, 4:22 p.m.)
Deposited	1 month, 4 weeks ago (July 2, 2025, 2:46 p.m.)
Indexed	1 month, 4 weeks ago (July 3, 2025, 12:17 a.m.)
Issued	52 years, 3 months ago (May 1, 1973)
Published	52 years, 3 months ago (May 1, 1973)
Published Print	52 years, 3 months ago (May 1, 1973)

Funders 0

None

BibTeX

@article{Price_1973, title={The Pyrolysis of Trimethylthallium and Evaluation of D[(CH3)2Tl—CH3]}, volume={51}, ISSN={1480-3291}, url={http://dx.doi.org/10.1139/v73-209}, DOI={10.1139/v73-209}, number={9}, journal={Canadian Journal of Chemistry}, publisher={Canadian Science Publishing}, author={Price, S. J. and Richard, J. P. and Rumfeldt, R. C. and Jacko, M. G.}, year={1973}, month=may, pages={1397–1401} }

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  "abstract": "<jats:p> The pyrolysis of trimethylthallium has been studied in a mercury free toluene carrier flow system (452\u2013536 \u00b0K, total pressure 6.7\u201339.3\u2002mm, contact time 0.9\u20135.1\u2002s, 5.4\u201390.2% decomposition). In a vessel cleaned with boiling concentrated HNO<jats:sub>3</jats:sub> and coated by decomposing 0.1\u2002g Tl(CH<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub> no heterogeneous reaction could be detected. The extent of reaction measured by product analysis (CH<jats:sub>4</jats:sub>, C<jats:sub>2</jats:sub>H<jats:sub>6</jats:sub>, C<jats:sub>6</jats:sub>H<jats:sub>5</jats:sub>C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>) assuming three CH<jats:sub>3</jats:sub> per Tl(CH<jats:sub>3</jats:sub>)<jats:sub>3</jats:sub> undergoing reaction 1 </jats:p>",
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