DOI: 10.1139/v69-622. Oxidations involving silver. V. The oxidation of primary aliphatic amines

Oxidations involving silver. V. The oxidation of primary aliphatic amines

10.1139/v69-622

Crossref journal-article

Canadian Science Publishing

Canadian Journal of Chemistry (155)

Abstract

Primary aliphatic amines are rapidly oxidized using a silver electrode at potentials more positive than 0.6 V normal hydrogen electrode (n.h.e.) in aqueous alkali. Primary aliphatic amines with a mono-substituted α-carbon atom give the corresponding nitrile and aldehyde, α,α-disubstituted ones give the corresponding ketone, and α,α,α-trisubstituted ones give the corresponding alcohol, nitro-compound, and unsaturated hydrocarbons. Some evidence for the reaction pathway is presented. The effect of amine on the kinetic parameters for Ag2O formation is reported.

Bibliography

Hampson, N. A., Lee, J. B., Morley, J. R., & Scanlon, B. (1969). Oxidations involving silver. V. The oxidation of primary aliphatic amines. Canadian Journal of Chemistry, 47(20), 3729â3736.

Authors 4

N. A. Hampson (first)
J. B. Lee (additional)
J. R. Morley (additional)
B. Scanlon (additional)

References 0 Referenced 32

None

Dates

Type	When
Created	19 years, 4 months ago (May 4, 2006, 3:57 p.m.)
Deposited	2 months ago (July 2, 2025, 2:50 p.m.)
Indexed	2 months ago (July 3, 2025, 12:17 a.m.)
Issued	55 years, 10 months ago (Oct. 15, 1969)
Published	55 years, 10 months ago (Oct. 15, 1969)
Published Print	55 years, 10 months ago (Oct. 15, 1969)

Funders 0

None

BibTeX

@article{Hampson_1969, title={Oxidations involving silver. V. The oxidation of primary aliphatic amines}, volume={47}, ISSN={1480-3291}, url={http://dx.doi.org/10.1139/v69-622}, DOI={10.1139/v69-622}, number={20}, journal={Canadian Journal of Chemistry}, publisher={Canadian Science Publishing}, author={Hampson, N. A. and Lee, J. B. and Morley, J. R. and Scanlon, B.}, year={1969}, month=oct, pages={3729–3736} }

JSON

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