DOI: 10.1139/v59-057. CO-ORDINATION COMPOUNDS OF NICKEL(II): PART I. THE SPECTRA OF SALICYLALDIMINE DERIVATIVES OF NICKEL(II) IN SOME ORGANIC SOLVENTS

CO-ORDINATION COMPOUNDS OF NICKEL(II): PART I. THE SPECTRA OF SALICYLALDIMINE DERIVATIVES OF NICKEL(II) IN SOME ORGANIC SOLVENTS

10.1139/v59-057

Crossref journal-article

Canadian Science Publishing

Canadian Journal of Chemistry (155)

Abstract

Measurements of the ultraviolet and visible absorption spectra of bis-N-methyl-salicylaldimine nickel(II) and its 5-chloro and 5-bromo derivatives in benzene, chloroform, carbon tetrachloride, and cyclohexane solutions at temperatures between 15° and 45 °C are reported. The results confirm the occurrence of a temperature dependent equilibrium between dia- and para-magnetic forms. The nature of the paramagnetic form is discussed in terms of the recent developments of the ligand field theory. The effect on the equilibrium of substitution of chlorine or bromine in the five position of the salicylaldehyde molecule is also discussed.

Bibliography

Clark, H. C., & OâBrien, R. J. (1959). CO-ORDINATION COMPOUNDS OF NICKEL(II): PART I. THE SPECTRA OF SALICYLALDIMINE DERIVATIVES OF NICKEL(II) IN SOME ORGANIC SOLVENTS. Canadian Journal of Chemistry, 37(2), 436â443.

Authors 2

H. C. Clark (first)
R. J. O'Brien (additional)

References 14 Referenced 9

10.1021/ja01198a001 / J. Am. Chem. Soc. by FUJII S. (1947)
{'key': 'p_3/p_3_1', 'first-page': '49', 'volume': '37', 'year': '1953', 'journal-title': 'Ser. I'} / Ser. I (1953)
{'volume': '3431', 'journal-title': 'J. Chern. Soc.', 'author': 'CLARK H. C.', 'key': 'p_4/p_4_1'} / J. Chern. Soc. by CLARK H. C.
{'volume': '719', 'journal-title': 'J. Chern. Soc.', 'author': 'VENANZI L. M.', 'key': 'p_5/p_5_1'} / J. Chern. Soc. by VENANZI L. M.
{'volume': '520', 'journal-title': 'J. Chern. Soc.', 'author': 'CLARK H. C.', 'key': 'p_6/p_6_1'} / J. Chern. Soc. by CLARK H. C.
10.1021/ja01572a027 / J. Am. Chern. Soc. by PAOLETTI P. (1957)
{'key': 'p_8/p_8_1', 'first-page': '84', 'volume': '50', 'author': 'PFEIFFER P.', 'year': '1933', 'journal-title': 'Ann.'} / Ann. by PFEIFFER P. (1933)
10.1021/ja01118a057 / J. Am. Chern. Soc. by BASOLO F. (1953)
10.1021/cr60165a004 / Chem. Revs. by NYHOLM R. S. (1953)
10.1021/ja01571a094 / J. Am. Chern. Soc. by SACCOXI L. (1957)
10.1021/ja01547a024 / Am. Chem. Soc. by SACCONI L.. (1958)
10.1021/ja01204a018 / Chem. Soc. by LEMON W. J. (1947)
10.1063/1.1743485 / J. Chem. Phys. by BELFORD R. L. (1957)
10.1063/1.1744667 / J. Chem. Phys. by NOTEADDED IN PROOF (1958)

Dates

Type	When
Created	19 years, 4 months ago (May 2, 2006, 4:30 p.m.)
Deposited	2 months ago (July 2, 2025, 11:07 a.m.)
Indexed	2 months ago (July 3, 2025, 12:09 a.m.)
Issued	66 years, 7 months ago (Feb. 1, 1959)
Published	66 years, 7 months ago (Feb. 1, 1959)
Published Print	66 years, 7 months ago (Feb. 1, 1959)

Funders 0

None

BibTeX

@article{Clark_1959, title={CO-ORDINATION COMPOUNDS OF NICKEL(II): PART I. THE SPECTRA OF SALICYLALDIMINE DERIVATIVES OF NICKEL(II) IN SOME ORGANIC SOLVENTS}, volume={37}, ISSN={1480-3291}, url={http://dx.doi.org/10.1139/v59-057}, DOI={10.1139/v59-057}, number={2}, journal={Canadian Journal of Chemistry}, publisher={Canadian Science Publishing}, author={Clark, H. C. and O’Brien, R. J.}, year={1959}, month=feb, pages={436–443} }

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