DOI: 10.1139/v57-093. POLAROGRAPHIC BEHAVIOR OF THE VIOLOGEN INDICATORS

POLAROGRAPHIC BEHAVIOR OF THE VIOLOGEN INDICATORS

10.1139/v57-093

Crossref journal-article

Canadian Science Publishing

Canadian Journal of Chemistry (155)

Abstract

The polarographic behavior of 1,1′-dimethyl- and 1,1′-dibenzyl-4,4′-bipyridinium dichloride has been investigated over the pH range of 1 to 13. Reversible reduction waves are obtained for the first single-electron step for both compounds. The second step is electrochemically irreversible but evidence is presented to indicate that the second step is fleetingly reversible at the dropping mercury electrode for methyl viologen but not benzyl viologen. Minor waves due to adsorption of the reduced viologen on the surface of the mercury have been observed.

Bibliography

Elofson, R. M., & Edsberg, R. L. (1957). POLAROGRAPHIC BEHAVIOR OF THE VIOLOGEN INDICATORS. Canadian Journal of Chemistry, 35(7), 646â650.

Authors 2

R. M. Elofson (first)
R. L. Edsberg (additional)

References 0 Referenced 97

None

Dates

Type	When
Created	19 years, 4 months ago (May 2, 2006, 4:25 p.m.)
Deposited	2 months ago (July 2, 2025, 1:47 p.m.)
Indexed	6 hours, 15 minutes ago (Sept. 4, 2025, 10:33 a.m.)
Issued	68 years, 2 months ago (July 1, 1957)
Published	68 years, 2 months ago (July 1, 1957)
Published Print	68 years, 2 months ago (July 1, 1957)

Funders 0

None

BibTeX

@article{Elofson_1957, title={POLAROGRAPHIC BEHAVIOR OF THE VIOLOGEN INDICATORS}, volume={35}, ISSN={1480-3291}, url={http://dx.doi.org/10.1139/v57-093}, DOI={10.1139/v57-093}, number={7}, journal={Canadian Journal of Chemistry}, publisher={Canadian Science Publishing}, author={Elofson, R. M. and Edsberg, R. L.}, year={1957}, month=jul, pages={646–650} }

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  "abstract": "<jats:p> The polarographic behavior of 1,1\u2032-dimethyl- and 1,1\u2032-dibenzyl-4,4\u2032-bipyridinium dichloride has been investigated over the pH range of 1 to 13. Reversible reduction waves are obtained for the first single-electron step for both compounds. The second step is electrochemically irreversible but evidence is presented to indicate that the second step is fleetingly reversible at the dropping mercury electrode for methyl viologen but not benzyl viologen. Minor waves due to adsorption of the reduced viologen on the surface of the mercury have been observed. </jats:p>",
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